S1 TITAN Alloy LE Calibrations (P/N: )

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1 S1 TITAN Alloy LE Calibrations () Low Alloy Si P S Ti V Cr Mn Fe Co Ni Cu Nb Mo W Pb Analysis range, % LLD-2 LLD-0.15 LLD-0.3 LLD LLD LLD - 8 LLD - 5 LLD - 5 LLD- 0.3 LLD - 8 LLD - 6 LLD-0.3 LLD (Fe pure) /47 21/85 18/50 53 N.A / SEC % Typical accuracy: ±% Phase /1 2/1 2/ Tool Steel Al Si P S Ti V Cr Mn Fe Co Ni Cu Zr Nb Mo Sn W Pb Analysis range, % LLD-1.5 LLD-2 LLD-0.2 LLD-0.3 LLD LLD - 2 LLD LLD - 8 LLD - 2 LLD - 2 LLD-0.04 LLD LLD - 9 LLD-0.05 LLD - 19 LLD-0.3 LLD (Fe pure) /74 21/90 16/54 73 N.A SEC % Typical accuracy: ±% Phase /1 2/1 2/ Stainless Steels Al Si P S Ti V Cr Mn Fe Co Ni Cu Zr Nb Mo Ta W Analysis range, % LLD-1.5 LLD-4 LLD-0.1 LLD LLD LLD-0.05 LLD LLD-0.6 LLD - 15 LLD (Fe pure) / N.A SEC % Typical accuracy: ±% Phase / Nickels Al Si P Ti V Cr Mn Fe Co Ni Cu Zr Nb Mo Hf Ta W Re Analysis range, % LLD-2 LLD-1.5 LLD LLD-0.6 LLD LLD - 28 LLD LLD-3 LLD (pure Ni) / / N.A SEC % Typical accuracy: ±% Phase /1 2 2/ Cobalts Al Si P S Ti V Cr Mn Fe Co Ni Cu Nb Mo W Pb Analysis range, % LLD-1.5 LLD-1.5 LLD-0.1 LLD-0.1 LLD-3.5 LLD LLD LLD-0.25 LLD- 4.0 LLD LLD-0.4 LLD (pure Co) / / N.A SEC % Typical accuracy: ±% Phase /1 2 2/ Zincs Al Ti Fe Cu Zn Pb Bi Analysis range, % LLD-30 LLD-0.15 LLD-0.5 LLD LLD-0.15 LLD-0.1 LLD (pure Zn) / N.A SEC % Typical accuracy: ±% Phase 2 2/ Coppers Al Si P S Ti Cr Mn Fe Co Ni Cu Zn As (KB1) Zr Ag Sn Pb (LB1) Bi Analysis range, % LLD-1.5 LLD-5 LLD-0.5 LLD-0.2 LLD-0.25 LLD LLD LLD- 5 LLD-0.5 LLD LLD LLD- 0.5 LLD LLD-0.05 LLD (pure Cu) /132 20/ N.A SEC % Typical accuracy: ±% Phase /1 2/ Bruker Elemental - August 27, 2014

2 S1 TITAN Alloy LE Calibrations () Al, Si Bronzes Al Si P S Ti Cr Mn Fe Co Ni Cu Zn As (KB1) Zr Ag Sn Pb (LB1) Bi Analysis range, % LLD - 12 LLD - 5 LLD-0.5 LLD-0.2 LLD-0.25 LLD LLD LLD- 5 LLD-0.5 LLD LLD LLD- 0.5 LLD LLD-0.05 LLD (pure Cu) /132 20/ N.A SEC % Typical accuracy: ±% Phase /1 2/ Light Alloys - Titaniums Al Si Ti V Cr Mn Fe Cu Zr Nb Mo Pd Sn Ta W Analysis range, % LLD -16 LLD LLD LLD - 2 LLD - 4 LLD LLD LLD -16 LLD LLD -2 LLD-1 LLD-0.5 LLD (pure Ti) N.A SEC % Typical accuracy: ±% Phase 2 2 2/ Light Alloys - Al/Mg Mg Al Si Ti V Cr Mn Fe Co (KB1) Ni Cu Zn Zr Sn Pb Bi Analysis range, % LLD-100% LLD-100% LLD-18 LLD -0.1 LLD -0.1 LLD -0.3 LLD-2 LLD LLD LLD - 5 LLD -7 LLD-0.2 LLD-0.1 LLD -0.1 LLD-0.1 LLD (1100 or pure Mg) SEC % Typical accuracy: ±% Phase Full MultiMatrix FP Mg Al Si P S Ti V Cr Mn Fe Co Ni Cu Zn As Se Y Zr Nb Analysis range, % LLD-100% LLD-100% LLD-100% LLD-5% LLD-5% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% SEC % Mo Ru Rh Pd Ag Cd In Sn Sb Hf Ta W Re Ir Pt Au Pb Bi Analysis range, % LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% SEC % % Calibration: FP based (with empirical corrections), with normalization based on BRUKER Intensity scaling when sample is smaller than mask Analysis range: Concentration range covered by reference samples in the calibration of the application. Can be extened by 15% with FP based calibrations. Empirical calibrations should only be used within the range. Lower Limit of Detection (LLD): The smallest concentration which can be detected. a) In this document LLD is specified for a given matrix in three sigma 99.7% confidence level (3 sigma); 60 second phase 1 analysis time, 180 second phase 2 analysis time b) Individual elemental LLD's improve as a function of the square root of the analysis time. Actual lower limit of detection range depends on several factors such as matrix interferences, overlapping elements, level of statistical confidence and testing time. Measurement of concentration close to the low analysis range requires typically long measurement time > 60s Standard Error of Calibration (SEC): Average error (deviation) between certified and XRF value of the samples used for the calibration expressed as an absolute value in weight %. Typical accuracy: Typical average error within the analysis range when large set of reference samples are measured. Notice that error of the individual sample may differ significantly from this value. Measurement time: 30s (2) or less than 10 sec (1) Phase: Number indicates on which measurement phase the listed LLD was determined Bruker Elemental - August 27, 2014

3 S1 TITAN Alloy Calibration: Multimatrix FP V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

4 S1 TITAN Alloy Calibration: Low Alloy V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

5 S1 TITAN Alloy Calibration: Tool Steel V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

6 S1 TITAN Alloy Calibration: Stainless Steels V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

7 S1 TITAN Alloy Calibration: Nickels V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

8 S1 TITAN Alloy Calibration: Cobalts V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

9 S1 TITAN Alloy Calibration: Zincs V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

10 S1 TITAN Alloy Calibration: Coppers V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

11 S1 TITAN Alloy Calibration: Al Si Bronzes V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

12 S1 TITAN Alloy Calibration: Light Alloys- Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

13 S1 TITAN Alloy Calibration: Light Alloys Al/Mg V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

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