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1 Jan 19, 09 9:48 Page 1/26 ACCUMULATED TABLE OF BOND VALENCE PARAMETERS Data_BOND_VALENCE_PARAMETERS_ bvparm2006.cif BVPARM.CIF _audit_conform_dict_name cif_core.dic _audit_conform_dict_version 2.2 *************************************************************** COPYRIGHT NOTICE This table may be used and distributed without fee for non profit purposes providing 1) that this copyright notice is included and 2) no fee is charged for the table and 3) details any changes made in this list by anyone other than the copyright owner are suitably noted in the _audit_update record Please consult the copyright owner regarding any other uses. The copyright is owned by I. David Brown, Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario Canada. *****************************DISCLAIMER************************ The values reported here are taken from the literature and other sources and the author does not warrant their correctness nor accept any responsibility for errors. Users are advised to consult the primary sources. *************************************************************** The parameters given in the main table are the values of Ro and B used in the equation: bond valence = exp((ro R)/B) where R is the bond length. All values are in Angstrom units. Where significantly different values have been reported in the literature, they are listed in decreasing order of reliability. Bond valence parameters for atoms whose oxidation state is given as 9 do not have an oxidation state specified in the original citation. They may apply to a particular, but unspecified, oxidation state or they may be intended to apply to all oxidation states. The ammonium ion is listed under the symbol NH. The list below is formatted and is designed to be read either as a crystallographic information file (CIF) or as a fixed format file once the text has been stripped off. 3 _audit_creation_date _audit_update_record ; Ref m deleted new ref c and d added new ref q added refs m, z and aa added corrected CIF errors correction of errors refs ag to ai added ; _audit_author_name I. David Brown _audit_author_address ; Brockhouse Institute for Materials Research McMaster University Jan 19, 09 9:48 Page 2/26 Hamilton, Ontario, Canada L8S 4M1 ; _audit_contact_author_name I. David Brown _audit_contact_author_ idbrown@mcmaster.ca loop valence_ref_id _valence_ref_reference a Brown and Altermatt, (1985), Acta Cryst. B41, (empirical) b Brese and O Keeffe, (1991), Acta Cryst. B47, (extrapolated) c Adams, 2001, Acta Cryst. B57, (includes second neighbours) d Hu et al. (1995) Inorg. Chim. Acta, 232, e I.D.Brown Private communication f Brown et al. (1984) Inorg. Chem. 23, g Palenik (1997) Inorg. Chem h Kanowitz and Palenik (1998) Inorg. Chem i Wood and Palenik (1998) Inorg. Chem j Liu and Thorp (1993) Inorg. Chem k Palenik (1997) Inorg. Chem l Shields, Raithby, Allen and Motherwell (1999) Acta Cryst.B56, m Chen, Zhou and Hu (2002) Chinese Sci. Bul. 47, n Kihlbourg (1963) Ark. Kemi ; Schroeder 1975 Acta Cryst. B31, 2294 o Allmann (1975) Monatshefte Chem. 106, 779 p Zachariesen (1978) J.Less Common Metals 62, 1 q Krivovichev and Brown (2001) Z. Krist. 216, 245 r Burns, Ewing and Hawthorne (1997) Can. Miner. 35, s Garcia Rodriguez, et al. (2000) Acta Cryst. B56, t Mahapatra et al. (1996) J. Amer.Chem. Soc. 118, u Wood and Palenik (1999) Inorg. Chem. 38, v Wood and Palenik (1999) Inorg. Chem. 38, w Wood, Abboud, Palenik and Palenik (2000) Inorg. Chem. 39, x Tytko, Mehnike and Kurad (1999) Structure and Bonding 93, 1 66 y Gundemann, et al.(1999) J. Phys. Chem. A 103, z Zocchi (2000) Solid State Sci aa Jensen, Palenik and Tiekiak (2001) Polyhedron 20, 2137 ab Roulhac and Palenik (2002) Inorg. Chem. 42, ac Holsa et al.(2002) J.Solid State Chem 165, ae Trzesowska, Kruszynski & Bartezak (2004) Acta Cryst. B60, af Locock & Burns (2004) Z.Krist. 219, ag Hu & Zhou (2004) Z. Krist ah Trzesowska, Kruszynski & Bartczak (2005) Acta Cryst. B ai Palenik (2003) Inorg. Chem. 42, loop valence_param_atom_1 _valence_param_atom_1_valence _valence_param_atom_2 _valence_param_atom_2_valence _valence_param_ro _valence_param_b _valence_param_ref_id _valence_param_details bvparm2006.cif Ac 3 O b? Ac 3 O p? Ac 3 F b? Ac 3 F p? Ac 3 Cl b? Ac 3 Cl p? Ac 3 Br p? Ag 1 O a? Ag 1 O b? Ag 1 S a? Ag 1 F b? Ag 1 Cl b? Ag 2 F e unchecked Ag 3 F e unchecked 1/13
2 Page 3/26 Ag 9 Br b? Ag 9 I b? Ag 9 Se b? Ag 9 Te b? Ag 9 N b? Ag 9 P b? Ag 9 As b? Ag 9 H b? Al 3 O e? Al 3 O o? Al 3 S e unchecked Al 3 S b? Al 3 Se b? Al 3 Te b? Al 3 F a? Al 3 Cl a? Al 3 Br b? Al 3 I b? Al 3 N b? Al 3 P b? Al 3 As b? Al 3 H b? Am 3 O b? Am 3 O p? Am 3 F b? Am 3 F p? Am 3 Cl b? Am 3 Cl p? Am 3 Br p? Am 4 O p? Am 4 O e unchecked Am 4 F p? Am 5 O p? Am 5 F p? Am 6 O p? Am 6 F p? Am 5 O e unchecked As 2 S e unchecked As 2 Se e unchecked As 3 O a? As 3 S a? As 3 Se e unchecked As 3 Te e unchecked As 3 F b? As 3 Cl b? As 3 Br e unchecked As 3 I e unchecked As 3 C b? As 5 O a? As 5 S e unchecked As 5 F a? As 5 Cl b? Au 1 Cl e unchecked Au 1 I e unchecked Au 3 O e? Au 3 O b? Au 3 S e unchecked Au 3 F e unchecked Au 3 F b? Au 3 Cl b? Au 3 Br e unchecked Au 3 I e unchecked Au 3 N e unchecked Au 5 F e unchecked Au 9 S b? Au 9 Se b? Au 9 Te b? Au 9 Br b? Au 9 I b? Page 4/26 Au 9 N b? Au 9 P b? Au 9 As b? Au 9 H b? B 3 O a? B 3 S e unchecked B 3 S b? B 3 Se b? B 3 Te b? B 3 F a? B 3 F b? B 3 Cl b? B 3 Br b? B 3 I b? B 3 N b? B 3 P b? B 3 As b? B 3 H b? B 3 B e unchecked Ba 2 O a? Ba 2 S a? Ba 2 Se b? Ba 2 Te b? Ba 2 F a? Ba 2 Cl b? Ba 2 Br b? Ba 2 I b? Ba 2 N b? Ba 2 P b? Ba 2 As b? Ba 2 H b? Be 2 O a? Be 2 S b? Be 2 Se b? Be 2 Te b? Be 2 F a? Be 2 Cl b? Be 2 Br b? Be 2 I b? Be 2 N b? Be 2 P b? Be 2 As b? Be 2 H b? Bi 3 O a? Bi 3 S a? Bi 2 Se e unchecked Bi 3 F b? Bi 3 Cl b? Bi 3 Cl e unchecked Bi 3 Br e unchecked Bi 3 I e unchecked Bi 3 N e unchecked Bi 5 O b? Bi 5 F b? Bi 5 Cl b? Bi 9 Br b? Bi 9 I b? Bi 9 S b? Bi 9 Se b? Bi 9 Te b? Bi 9 N b? Bi 9 P b? Bi 9 As b? Bi 9 H b? Bk 3 O b? Bk 3 O p? Bk 3 F b? Bk 3 F p? Bk 3 Cl e unchecked 2/13
3 Page 5/26 Bk 3 Cl b? Bk 3 Cl p? Bk 3 Br p? Bk 4 O p? Bk 4 F p? Br 3 O e unchecked Br 3 F e unchecked Br 5 O e unchecked Br 5 F e unchecked Br 7 O b? Br 7 F b? Br 7 Cl b? C 2 O e unchecked C 2 Cl e unchecked C 4 O a? C 4 O o? C 4 C e? C 4 S e unchecked C 4 F b? C 4 F e unchecked C 4 Cl b? C 4 Br e unchecked C 4 N a? C 9 Se b? C 9 I b? C 9 Br b? C 9 S b? C 9 Te b? C 9 N b? C 9 P b? C 9 As b? C 9 H b? Ca 2 O a? Ca 2 O o? Ca 2 S b? Ca 2 Se b? Ca 2 Te b? Ca 2 F a? Ca 2 Cl b? Ca 2 Br e unchecked Ca 2 Br b? Ca 2 I b? Ca 2 N b? Ca 2 P b? Ca 2 As b? Ca 2 H b? Cd 2 O a? Cd 2 S a? Cd 2 Se b? Cd 2 Te b? Cd 2 F b? Cd 2 Cl a? Cd 2 Cl b? Cd 2 Br b? Cd 2 I b? Cd 2 I e unchecked Cd 2 N b? Cd 2 P b? Cd 2 As b? Cd 2 H b? Ce 3 O b? Ce 3 O ab in trans metal complexes Ce 3 O ae in trans metal complexes Ce 3 S e unchecked Ce 3 F b? Ce 3 F p? Ce 3 Cl b? Ce 3 Cl p? Ce 3 Br e? Page 6/26 Ce 3 Br p? Ce 3 I p? Ce 4 O b? Ce 4 O ab in organic compounds Ce 4 S e unchecked Ce 4 F b? Ce 4 F p? Ce 9 Cl b? Ce 9 Br b? Ce 9 I b? Ce 9 S b? Ce 9 Se b? Ce 9 Te b? Ce 9 N ah? Ce 9 N b? Ce 9 P b? Ce 9 As b? Ce 9 H b? Cf 3 O b? Cf 3 F b? Cf 3 F p? Cf 3 Cl b? Cf 3 Cl p? Cf 3 Br p? Cf 4 O p? Cf 4 F p? Cl 3 O e unchecked Cl 3 F e unchecked Cl 5 O e unchecked Cl 7 O a? Cl 7 F b? Cl 7 Cl b? Cf 3 Cl b? Cm 3 O b? Cm 3 O p? Cm 3 F b? Cm 3 F p? Cm 3 Cl b? Cm 3 Cl p? Cm 4 O p? Cm 4 F p? Co 1 H e unchecked Co 2 O a? Co 2 O i from transition metal complexes Co 2 S e unchecked Co 2 F b? Co 2 Cl a? Co 2 Cl b? Co 2 N e unchecked Co 3 O i from transition metal complexes Co 3 O b? Co 3 S e unchecked Co 3 F b? Co 3 Cl b? Co 3 N e unchecked Co 3 C b? Co 4 O e unchecked Co 4 F e unchecked Co 9 O o? Co 9 Br b? Co 9 I b? Co 9 S b? Co 9 Se b? Co 9 Te b? Co 9 N b? Co 9 P b? Co 9 As b? Co 9 H b? Cr 2 O b? 3/13
4 Page 7/26 Cr 2 F b? Cr 2 F e unchecked Cr 2 Cl b? Cr 2 Br e unchecked Cr 2 I e unchecked Cr 2 N e unchecked Cr 3 O a? Cr 3 O w from transition metal complexes Cr 3 S e unchecked Cr 3 F a? Cr 3 F b? Cr 3 Cl b? Cr 3 Br e unchecked Cr 3 N e unchecked Cr 4 O e unchecked Cr 4 F e unchecked Cr 5 O w from transition metal complexes Cr 5 O e unchecked Cr 6 O a? Cr 6 F b? Cr 6 Cl b? Cr 9 O o? Cr 9 O w from transition metal complexes Cr 9 Br b? Cr 9 I b? Cr 9 S b? Cr 9 Se b? Cr 9 Te b? Cr 9 N b? Cr 9 P b? Cr 9 As b? Cr 9 H b? Cs 1 O a? Cs 1 O c 7 A cut off Cs 1 S b? Cs 1 S c 7 A cut off Cs 1 S e unchecked Cs 1 Se b? Cs 1 Se c 7 A cut off Cs 1 Te b? Cs 1 Te c 8 A cut off Cs 1 F b? Cs 1 F c 7 A cut off Cs 1 F e unchecked Cs 1 Cl a? Cs 1 Cl c 7 A cut off Cs 1 Br b? Cs 1 Br c 7 A cut off Cs 1 I b? Cs 1 I c 8 A cut off Cs 1 I e unchecked Cs 1 N e unchecked Cs 1 N b? Cs 1 P b? Cs 1 As b? Cs 1 H b? Cu 1 O e unchecked Cu 1 O l from transition metal complexes Cu 1 S a? Cu 1 S l from transition metal complexes Cu 1 Se l from transition metal complexes Cu 1 F b? Cu 1 Cl l from transition metal complexes Cu 1 Cl e unchecked Cu 1 Br e unchecked Cu 1 I a? Cu 1 I l from transition metal complexes Cu 1 N l 3 coordinate N Cu 1 N l 2 coordinate N Page 8/26 Cu 1 N l 4 coordinate N Cu 1 P l from transition metal complexes Cu 1 As l from transition metal complexes Cu 1 C l from transition metal complexes Cu 2 O a? Cu 2 O j from transition metal complexes Cu 2 O l from transition metal complexes Cu 2 S a? Cu 2 S j from transition metal complexes Cu 2 S l from transition metal complexes Cu 2 S b? Cu 2 Se b? Cu 2 Se l? Cu 2 Te b? Cu 2 F a? Cu 2 Cl b? Cu 2 Br b? Cu 2 Br l from transition metal complexes Cu 2 I b? Cu 2 I l from transition metal complexes Cu 2 N j from transition metal complexes Cu 2 N l from transition metal complexes Cu 2 N b? Cu 2 N l 2 coordinate N Cu 2 N l 3 coordinate N Cu 2 N l 4 coordinate N Cu 2 P b? Cu 2 P l from transition metal complexes Cu 2 As b? Cu 2 C l from transition metal complexes Cu 2 H b? Cu 3 O t? Cu 3 O e unchecked Cu 3 F e unchecked Cu 3 Cl l from transition metal complexes Cu 3 N l from transition metal complexes Cu 3 N t? Cu 3 C l from transition metal complexes Dy 2 O e unchecked Dy 3 O a? Dy 3 O ae from transition metal complexes Dy 3 F b? Dy 3 F p? Dy 3 Cl b? Dy 3 Cl p? Dy 3 Br p? Dy 3 I p? Dy 9 Br b? Dy 9 I b? Dy 9 S b? Dy 9 Se b? Dy 9 Te b? Dy 9 N ah? Dy 9 N b? Dy 9 P b? Dy 9 As b? Dy 9 H b? Er 2 O e unchecked Er 2 S e unchecked Er 3 O a? Er 3 O b? Er 3 O ae from transition metal complexes Er 3 S e unchecked Er 3 Se e unchecked Er 3 F a? Er 3 F p? Er 3 Cl b? Er 3 Cl p? Er 3 Br p? 4/13
5 Page 9/26 Er 3 I p? Er 9 Br b? Er 9 I b? Er 9 S b? Er 9 Se b? Er 9 Te b? Er 9 N ah? Er 9 N b? Er 9 P b? Er 9 As b? Er 9 H b? Es 3 O p? Eu 2 O b? Eu 2 S a? Eu 2 F b? Eu 2 Cl b? Eu 2 Br e unchecked Eu 2 I e unchecked Eu 2 N e unchecked Eu 3 O a? Eu 3 O ae from transition metal complexes Eu 3 S e unchecked Eu 3 F b? Eu 3 F p? Eu 3 Cl e unchecked Eu 3 Cl p? Eu 3 Br p? Eu 3 I p? Eu 9 Br b? Eu 9 I b? Eu 9 S b? Eu 9 Se b? Eu 9 Te b? Eu 9 N ah? Eu 9 N b? Eu 9 P b? Eu 9 As b? Eu 9 H b? Fe 2 O a? Fe 2 O h? Fe 2 O j? Fe 2 S e unchecked Fe 2 S j from transition metal complexes Fe 2 F b? Fe 2 Cl b? Fe 2 Cl e unchecked Fe 2 Br e unchecked Fe 2 I e? Fe 2 N j from transition metal complexes Fe 3 O a? Fe 3 O h from transition metal complexes Fe 3 O j from transition metal complexes Fe 3 S a? Fe 3 S j? Fe 3 F a? Fe 3 Cl b? Fe 3 Cl e unchecked Fe 3 N j from transition metal complexes Fe 3 C a? Fe 4 S e unchecked Fe 6 O e unchecked Fe 9 O ag for all oxidation states Fe 9 O o? Fe 9 Br b? Fe 9 I b? Fe 9 S b? Fe 9 Se b? Fe 9 Te b? Fe 9 N b? Page 10/26 Fe 9 P b? Fe 9 As b? Fe 9 H b? Ga 1 Se e unchecked Ga 3 O a? Ga 3 S a? Ga 3 F b? Ga 3 F e unchecked Ga 3 Cl b? Ga 3 Br e? Ga 3 I e unchecked Ga 9 Br b? Ga 9 I b? Ga 9 S b? Ga 9 Se b? Ga 9 Te b? Ga 9 N b? Ga 9 P b? Ga 9 As b? Ga 9 H b? Gd 2 O e unchecked Gd 2 F e unchecked Gd 3 O b? Gd 3 O ae from transition metal complexes Gd 3 S e unchecked Gd 3 F b? Gd 3 F p? Gd 3 Cl b? Gd 3 Cl p? Gd 3 Cl e unchecked Gd 3 Br p? Gd 3 I p? Gd 9 Br b? Gd 9 I b? Gd 9 S b? Gd 9 Se b? Gd 9 Te b? Gd 9 N ah? Gd 9 N b? Gd 9 N e? Gd 9 P b? Gd 9 As b? Gd 9 H b? Ge 4 O a? Ge 4 S a? Ge 4 Se e unchecked Ge 4 F b? Ge 4 Cl b? Ge 9 Br b? Ge 9 I b? Ge 9 S b? Ge 9 Se b? Ge 9 Te b? Ge 9 N b? Ge 9 P b? Ge 9 As b? Ge 9 H b? H 1 O e 1.05<O H<1.70 A, best general value H 1 O e O H < 1.05 A H 1 O e 1.70 A < O H Hf 3 F e unchecked Hf 4 O b? Hf 4 F b? Hf 4 F p? Hf 4 Cl e unchecked Hf 4 Cl b? Hf 9 Br b? Hf 9 S b? Hf 9 Se b? 5/13
6 Page 11/26 Hf 9 Te b? Hf 9 I b? Hf 9 N b? Hf 9 P b? Hf 9 As b? Hf 9 H b? Hg 1 O b? Hg 1 F b? Hg 1 Cl b? Hg 2 O a? Hg 2 O b? Hg 2 S a? Hg 2 F e unchecked Hg 2 F b? Hg 2 Cl e? Hg 2 Cl b? Hg 2 Br e unchecked Hg 2 I e unchecked Hg 9 Br b? Hg 9 I b? Hg 9 S b? Hg 9 Se b? Hg 9 Te b? Hg 9 N b? Hg 9 P b? Hg 9 As b? Hg 9 H b? Hg 2 Hg f? Ho 3 O a? Ho 3 O ae from transition metal complexes Ho 3 S e unchecked Ho 3 F b? Ho 3 F p? Ho 3 Cl b? Ho 3 Cl p? Ho 3 Br p? Ho 3 I p? Ho 9 Br b? Ho 9 I b? Ho 9 S b? Ho 9 Se b? Ho 9 Te b? Ho 9 N ah? Ho 9 N b? Ho 9 P b? Ho 9 As b? Ho 9 H b? I 0 I e unchecked I 1 F e unchecked I 1 Cl e unchecked I 3 O e unchecked I 3 F b? I 3 Cl e unchecked I 5 O a? I 5 F e unchecked I 5 F b? I 5 Cl b? I 7 O b? I 7 F b? I 7 Cl b? In 1 Cl e unchecked In 3 O a? In 3 S a? In 3 F a? In 3 Cl b? In 3 Br e unchecked In 3 I e unchecked In 3 Co e unchecked In 3 Mn e unchecked Page 12/26 In 9 Br b? In 9 I b? In 9 S b? In 9 Se b? In 9 Te b? In 9 N b? In 9 P b? In 9 As b? In 9 H b? Ir 4 O e unchecked Ir 4 F e unchecked Ir 5 O b? Ir 5 O e unchecked Ir 5 F b? Ir 5 Cl b? Ir 9 S b? Ir 9 Se b? Ir 9 Te b? Ir 9 Br b? Ir 9 I b? Ir 9 N b? Ir 9 P b? Ir 9 As b? Ir 9 H b? K 1 O a? K 1 O u? K 1 O c 6 A cut off K 1 O o? K 1 S b? K 1 S c 7 A cut off K 1 S e unchecked K 1 Se b? K 1 Se c 7 A cut off K 1 Te b? K 1 Te c 7 A cut off K 1 F a? K 1 F c 6 A cut off K 1 Cl a? K 1 Cl c 6 A cut off K 1 Br b? K 1 Br c 7 A cut off K 1 I b? K 1 I c 7 A cut off K 1 I e unchecked K 1 N b? K 1 N e unchecked K 1 P b? K 1 As b? K 1 H b? Kr 2 F e? La 3 O a? La 3 O ac? La 3 O ae from transition metal complexes La 3 S a? La 3 Se b? La 3 Te b? La 3 F p? La 3 F e unchecked La 3 Cl b? La 3 Cl e unchecked La 3 Cl p? La 3 Br b? La 3 Br p? La 3 I b? La 3 I p? La 3 N ah? La 3 N b? La 3 P b? La 3 As b? 6/13
7 Page 13/26 La 3 H b? Li 1 O a? Li 1 O c 6 A cut off Li 1 O o? Li 1 S b? Li 1 S c 6 A cut off Li 1 Se b? Li 1 Se c 7 A cut off Li 1 Te b? Li 1 Te c 7 A cut off Li 1 F a? Li 1 F c 6 A cut off Li 1 Cl b? Li 1 Cl c 6 A cut off Li 1 Cl e unchecked Li 1 Br b? Li 1 Br c 7 A cut off Li 1 I b? Li 1 I c 7 A cut off Li 1 N b? Lu 3 O b? Lu 3 O ae from transition metal complex Lu 3 S b? Lu 3 Se b? Lu 3 Te b? Lu 3 F b? Lu 3 F p? Lu 3 Cl b? Lu 3 Cl p? Lu 3 Br b? Lu 3 Br p? Lu 3 I b? Lu 3 I p? Lu 3 N ah? Lu 3 N b? Lu 3 P b? Lu 3 As b? Lu 3 H b? Mg 2 O a? Mg 2 O o? Mg 2 S b? Mg 2 Se b? Mg 2 Te b? Mg 2 F a? Mg 2 Cl b? Mg 2 Br b? Mg 2 I b? Mg 2 N b? Mg 2 P b? Mg 2 As b? Mg 2 H b? Mn 2 O a? Mn 2 O j? Mn 2 S e unchecked Mn 2 F a? Mn 2 Cl a? Mn 2 Br e unchecked Mn 2 I e unchecked Mn 2 N j from transition metal complexes Mn 2 N e unchecked Mn 3 O a? Mn 3 O j from transition metal complexes Mn 3 F b? Mn 3 Cl b? Mn 3 N j from transition metal complexes Mn 4 O a? Mn 4 O j from transition metal complexes Mn 4 F b? Mn 4 F e unchecked Page 14/26 Mn 4 Cl b? Mn 4 N j from transition metal complexes Mn 6 O e? Mn 7 O e unchecked Mn 7 O b? Mn 7 F b? Mn 7 Cl b? Mn 9 O g from transition metal complexes Mn 9 Br b? Mn 9 I b? Mn 9 S b? Mn 9 Se b? Mn 9 Te b? Mn 9 N b? Mn 9 P b? Mn 9 As b? Mn 9 H b? Mo 3 O m? Mo 3 F e unchecked Mo 3 Cl e unchecked Mo 3 Br e unchecked Mo 3 N e unchecked Mo 4 O j from transition metal complexes Mo 4 O m? Mo 4 S j from transition metal complexes Mo 4 F e unchecked Mo 4 Cl e unchecked Mo 4 N j from transition metal complexes Mo 5 O j from transition metal complexes Mo 5 O m? Mo 5 S j from transition metal complexes Mo 5 Cl e unchecked Mo 5 N j from transition metal complexes Mo 6 O a? Mo 6 O x? Mo 6 O n? Mo 6 O m? Mo 6 S j from transition metal complexes Mo 6 F b? Mo 6 Cl b? Mo 6 N j from transition metal complexes Mo 9 O z applies to all oxidation states Mo 9 Br b? Mo 9 I b? Mo 9 S b? Mo 9 Se b? Mo 9 Te b? Mo 9 N b? Mo 9 P b? Mo 9 As b? Mo 9 H b? N 3 O a? N 3 S e unchecked N 3 F b? N 3 Cl b? N 3 N e unchecked N 5 O a? N 5 O o? N 5 F b? N 5 Cl b? Na 1 O a? Na 1 O v? Na 1 O c 6 A cut off Na 1 O o? Na 1 S a? Na 1 S b? Na 1 S c 6 A cut off Na 1 Se b? Na 1 Se c 7 A cut off 7/13
8 Page 15/26 Na 1 Te b? Na 1 Te c 7 A cut off Na 1 F a? Na 1 F c 6 A cut off Na 1 Cl b? Na 1 Cl c 6 A cut off Na 1 Cl e unchecked Na 1 Br b? Na 1 Br c 7 A cut off Na 1 I b? Na 1 I c 7 A cut off Na 1 N b? Na 1 N e unchecked Na 1 P b? Na 1 As b? Na 1 H b? Nb 3 O e unchecked Nb 3 F e unchecked Nb 3 Cl e unchecked Nb 3 Br e unchecked Nb 4 O e unchecked Nb 4 F e unchecked Nb 4 Cl e unchecked Nb 4 Br e unchecked Nb 5 O a? Nb 5 O x? Nb 5 F b? Nb 5 Cl b? Nb 5 I e unchecked Nb 5 N e unchecked Nb 9 Br b? Nb 9 I b? Nb 9 S b? Nb 9 Se b? Nb 9 Te b? Nb 9 N b? Nb 9 P b? Nb 9 As b? Nb 9 H b? Nd 2 O e unchecked Nd 2 S e unchecked Nd 3 O a? Nd 3 O b? Nd 3 O ae from transition metal complexes Nd 3 S b? Nd 3 Se b? Nd 3 Te b? Nd 3 F b? Nd 3 F p? Nd 3 Cl b? Nd 3 Cl p? Nd 3 Br b? Nd 3 Br p? Nd 3 I b? Nd 3 I p? Nd 3 N ah? Nd 3 N b? NH 1 O s? NH 1 F s? NH 1 Cl s? Ni 2 O a? Ni 2 O j from transition metal complexes Ni 2 S e unchecked Ni 2 S j from transition metal complexes Ni 2 F a? Ni 2 Cl b? Ni 2 Br e unchecked Ni 2 I e unchecked Ni 2 N e unchecked Page 16/26 Ni 2 N j from transition metal complexes Ni 3 O e? Ni 3 S j from transition metal complexes Ni 3 F e unchecked Ni 3 N j from transition metal complexes Ni 4 O e unchecked Ni 4 F e unchecked Ni 9 Br b? Ni 9 I b? Ni 9 S b? Ni 9 Se b? Ni 9 Te b? Ni 9 N b? Ni 9 P b? Ni 9 As b? Ni 9 H b? Np 3 F p? Np 3 Cl p? Np 3 Br p? Np 3 I p? Np 4 O e unchecked Np 4 O p? Np 4 F e unchecked Np 4 F p? Np 4 Cl p? Np 5 O p? Np 5 F p? Np 5 Cl p? Np 6 O p? Np 6 F p? Np 7 O p? O 2 O e unchecked Os 4 O b? Os 4 S e unchecked Os 4 F b? Os 4 Cl b? Os 4 Br e unchecked Os 5 F e unchecked Os 6 O a? Os 6 F e unchecked Os 8 O e unchecked P 3 O e unchecked P 3 S e unchecked P 3 Se e unchecked P 3 F e unchecked P 4 O e unchecked P 4 S e unchecked P 4 F e unchecked P 5 O a? P 5 O b? P 5 S a? P 5 F e unchecked P 5 Cl e? P 5 Br e unchecked P 5 N a? P 9 Br b? P 9 I b? P 9 S b? P 9 Se b? P 9 Te b? P 9 N b? P 9 P b? P 9 As b? P 9 H b? P 5 P e unchecked Pa 4 O p? Pa 4 F p? Pa 4 Cl p? Pa 4 Br p? 8/13
9 Page 17/26 Pa 5 O e unchecked Pa 5 O p? Pa 5 F e unchecked Pa 5 F p? Pa 5 Cl p? Pa 5 Br p? Pb 2 O q? Pb 2 O a? Pb 2 S a? Pb 2 Se e unchecked Pb 2 F b? Pb 2 Cl b? Pb 2 Br e unchecked Pb 2 I e unchecked Pb 2 N e unchecked Pb 4 O a? Pb 4 F b? Pb 4 Cl b? Pb 4 Cl e unchecked Pb 4 Br e unchecked Pb 9 Br b? Pb 9 I b? Pb 9 S b? Pb 9 Se b? Pb 9 Te b? Pb 9 N b? Pb 9 P b? Pb 9 As b? Pb 9 H b? Pd 2 O b? Pd 2 S e unchecked Pd 2 F b? Pd 2 Cl b? Pd 2 Br e unchecked Pd 2 I e unchecked Pd 2 N e unchecked Pd 2 C e unchecked Pd 4 S e unchecked Pd 4 F e unchecked Pd 9 Br b? Pd 9 I b? Pd 9 S b? Pd 9 Se b? Pd 9 Te b? Pd 9 N b? Pd 9 P b? Pd 9 As b? Pd 9 H b? Pm 3 F p? Pm 3 Cl p? Pm 3 Br p? Pm 3 Cl p? Po 4 O e unchecked Po 4 F e unchecked Pr 3 O a? Pr 3 O ae from transition metal complexes Pr 3 S b? Pr 3 Se b? Pr 3 Te b? Pr 3 F b? Pr 3 F p? Pr 3 Cl b? Pr 3 Cl p? Pr 3 Br b? Pr 3 Br p? Pr 3 I b? Pr 3 I p? Pr 3 N ah? Pr 3 N b? Page 18/26 Pr 3 P b? Pr 3 As b? Pr 3 H b? Pt 2 O b? Pt 2 O e unchecked Pt 2 S e unchecked Pt 2 F b? Pt 2 Cl b? Pt 2 Br e unchecked Pt 2 C a? Pt 2 N e unchecked Pt 3 O e unchecked Pt 3 Cl e unchecked Pt 3 Br e unchecked Pt 4 O a? Pt 4 F b? Pt 4 F e unchecked Pt 4 Cl b? Pt 4 Cl e unchecked Pt 4 Br e unchecked Pt 9 Br b? Pt 9 I b? Pt 9 S b? Pt 9 Se b? Pt 9 Te b? Pt 9 N b? Pt 9 P b? Pt 9 As b? Pt 9 H b? Pu 3 O b? Pu 3 O p? Pu 3 F b? Pu 3 F p? Pu 3 Cl b? Pu 3 Cl p? Pu 3 Br p? Pu 3 I p? Pu 4 O p? Pu 4 F p? Pu 4 Cl p? Pu 5 O e? Pu 5 O p? Pu 5 F p? Pu 6 O p? Pu 6 F p? Pu 7 O p? Rb 1 O a? Rb 1 O c 7 A cut off Rb 1 S b? Rb 1 S c 7 A cut off Rb 1 S e unchecked Rb 1 Se b? Rb 1 Se c 7 A cut off Rb 1 Te b? Rb 1 Te c 8 A cut off Rb 1 F b? Rb 1 F c 6 A cut off Rb 1 F e unchecked Rb 1 Cl a? Rb 1 Cl c 7 A cut off Rb 1 Br b? Rb 1 Br c 7 A cut off Rb 1 Br e unchecked Rb 1 I b? Rb 1 I c 7 A cut off Rb 1 I e unchecked Rb 1 N e unchecked Rb 1 N b? Rb 1 P b? 9/13
10 Page 19/26 Rb 1 As b? Rb 1 H b? Re 1 Cl e unchecked Re 3 O e unchecked Re 3 Cl e unchecked Re 4 F e unchecked Re 4 Cl e unchecked Re 4 Br e unchecked Re 5 O e? Re 5 Cl e unchecked Re 6 F e unchecked Re 7 O e unchecked Re 7 F b? Re 7 Cl b? Re 9 Br b? Re 9 I b? Re 9 S b? Re 9 Se b? Re 9 Te b? Re 9 N b? Re 9 P b? Re 9 As b? Re 9 H b? Rh 3 O b? Rh 3 F b? Rh 3 Cl e unchecked Rh 3 Cl b? Rh 3 Br e unchecked Rh 3 N e unchecked Rh 4 F e unchecked Rh 5 F e unchecked Rh 9 Br b? Rh 9 I b? Rh 9 S b? Rh 9 Se b? Rh 9 Te b? Rh 9 N b? Rh 9 P b? Rh 9 As b? Rh 9 H b? Ru 2 Se e unchecked Ru 2 F e unchecked Ru 3 O o? Ru 3 S e unchecked Ru 3 F e unchecked Ru 3 Cl e unchecked Ru 3 N e unchecked Ru 4 O b? Ru 4 S e unchecked Ru 4 F b? Ru 4 Cl b? Ru 5 O o? Ru 5 F e unchecked Ru 5 Cl e unchecked Ru 6 O e unchecked Ru 7 O e unchecked Ru 9 Br b? Ru 9 I b? Ru 9 S b? Ru 9 Se b? Ru 9 Te b? Ru 9 N b? Ru 9 P b? Ru 9 As b? Ru 9 H b? S 2 O e unchecked S 2 S e unchecked S 2 N a? S 2 N a? Page 20/26 S 2 S e unchecked S 4 O a? S 4 F b? S 4 Cl b? S 4 N a? S 6 O a? S 6 F b? S 6 Cl b? S 6 N e unchecked S 9 Br b? S 9 I b? S 9 S b? S 9 Se b? S 9 Te b? S 9 N b? S 9 P b? S 9 As b? S 9 H b? Sb 3 O a? Sb 3 S a? Sb 3 Se e unchecked Sb 3 F a? Sb 3 F b? Sb 3 Cl b? Sb 3 Br e unchecked Sb 3 I e unchecked Sb 3 N d? Sb 5 O a? Sb 5 F a? Sb 5 Cl b? Sb 5 Br e unchecked Sb 5 N e unchecked Sb 9 S b? Sb 9 Se b? Sb 9 Te b? Sb 9 Br b? Sb 9 I b? Sb 9 N b? Sb 9 P b? Sb 9 As b? Sb 9 H b? Sc 3 O a? Sc 3 O o? Sc 3 S a? Sc 3 Se b? Sc 3 Te b? Sc 3 F b? Sc 3 Cl e unchecked Sc 3 Cl b? Sc 3 Br b? Sc 3 I b? Sc 3 N b? Sc 3 P b? Sc 3 As b? Sc 3 H b? Se 2 S e unchecked Se 2 Se e unchecked Se 4 O a? Se 4 F b? Se 4 Cl b? Se 4 Br e unchecked Se 6 O a? Se 6 F b? Se 6 Cl b? Se 6 N e unchecked Se 9 Br b? Se 9 I b? Se 9 S b? Se 9 Se b? 10/13
11 Page 21/26 Se 9 Te b? Se 9 P b? Se 9 As b? Se 9 H b? Si 4 O b? Si 4 O a? Si 4 S a? Si 4 Se b? Si 4 Te b? Si 4 F b? Si 4 Cl b? Si 4 Br b? Si 4 I b? Si 4 C a? Si 4 N a? Si 4 N b? Si 4 P b? Si 4 As b? Si 4 H b? Sm 2 O ai? Sm 3 O b? Sm 3 O ae from transition metal complexes Sm 3 O ai from transition metal complexes Sm 3 S b? Sm 3 Se b? Sm 3 Te b? Sm 3 F p? Sm 3 F e unchecked Sm 3 Cl b? Sm 3 Cl p? Sm 3 Br b? Sm 3 Br p? Sm 3 I b? Sm 3 I p? Sm 3 N ah? Sm 3 N b? Sm 3 P b? Sm 3 As b? Sm 3 H b? Sn 2 O b? Sn 2 S e unchecked Sn 2 F a? Sn 2 Cl e unchecked Sn 3 Cl b? Sn 2 Br d unchecked Sn 2 I e unchecked Sn 2 N e unchecked Sn 4 O a? Sn 4 S a? Sn 4 Se e unchecked Sn 4 F a? Sn 4 Cl a? Sn 4 Br e unchecked Sn 4 N e unchecked Sn 9 Br b? Sn 9 I b? Sn 9 S aa? Sn 9 S b? Sn 9 Se b? Sn 9 Te b? Sn 9 N aa? Sn 9 N b? Sn 9 P b? Sn 9 As b? Sn 9 H b? Sr 2 O a? Sr 2 S b? Sr 2 S e unchecked Sr 2 Se b? Page 22/26 Sr 2 Te b? Sr 2 Te e unchecked Sr 2 F b? Sr 2 Cl b? Sr 2 Br b? Sr 2 I b? Sr 2 N b? Sr 2 P b? Sr 2 As b? Sr 2 H b? Ta 4 O e unchecked Ta 5 O a? Ta 5 S e unchecked Ta 5 F b? Ta 5 Cl b? Ta 9 Br b? Ta 9 I b? Ta 9 S b? Ta 9 Se b? Ta 9 Te b? Ta 9 N b? Ta 9 P b? Ta 9 As b? Ta 9 H b? Tb 3 O a? Tb 3 O b? Tb 3 O ae from transition metal complexes Tb 3 S b? Tb 3 Se b? Tb 3 Te b? Tb 3 F b? Tb 3 F p? Tb 3 Cl b? Tb 3 Cl p? Tb 3 Br b? Tb 3 Br p? Tb 3 I b? Tb 3 I p? Tb 3 N ah? Tb 3 N b? Tb 3 P b? Tb 3 As b? Tb 3 H b? Tc 4 F p? Tc 4 Cl e unchecked Tc 7 O e unchecked Te 4 O a? Te 4 S e unchecked Te 4 F b? Te 4 Cl b? Te 4 Br e unchecked Te 4 I e unchecked Te 6 O a? Te 6 F b? Te 6 Cl b? Te 9 Br b? Te 9 I b? Te 9 S b? Te 9 Se b? Te 9 Te b? Te 9 N b? Te 9 P b? Te 9 As b? Te 9 H b? Th 4 O b? Th 4 O p? Th 4 S b? Th 4 Se b? Th 4 Te b? 11/13
12 Page 23/26 Th 4 F a? Th 4 F p? Th 4 Cl b? Th 4 Cl p? Th 4 Br b? Th 4 Br p? Th 4 I b? Th 4 I p? Th 4 I e unchecked Th 4 N b? Th 4 P b? Th 4 As b? Th 4 H b? Ti 2 F e unchecked Ti 2 Cl e unchecked Ti 2 Br e unchecked Ti 3 O b? Ti 3 S e unchecked Ti 3 F b? Ti 3 Cl e unchecked Ti 3 Cl b? Ti 3 I e unchecked Ti 4 O a? Ti 4 O o? Ti 4 S e unchecked Ti 4 F b? Ti 4 Cl b? Ti 4 Br e unchecked Ti 9 O k from transition metal complexes Ti 9 Cl k from transition metal complexes Ti 9 Br b? Ti 9 I b? Ti 9 S b? Ti 9 Se b? Ti 9 Te b? Ti 9 N b? Ti 9 N k from transition metal complexes Ti 9 P b? Ti 9 As b? Ti 9 H b? Tl 1 O a? Tl 1 O b? Tl 1 O af inorganic and organic compounds Tl 1 S a? Tl 1 F b? Tl 1 Cl b? Tl 1 Cl e unchecked Tl 1 Br e unchecked Tl 1 I a? Tl 3 O b? Tl 3 F b? Tl 3 Cl b? Tl 3 Br e unchecked Tl 9 Br b? Tl 9 I b? Tl 9 S b? Tl 9 Se b? Tl 9 Te b? Tl 9 N b? Tl 9 P b? Tl 9 As b? Tl 9 H b? Tm 3 O b? Tm 3 O ae from transition metal complexes Tm 3 O e unchecked Tm 3 S b? Tm 3 Se b? Tm 3 Te b? Tm 3 F b? Page 24/26 Tm 3 F p? Tm 3 F e unchecked Tm 3 Cl b? Tm 3 Cl p? Tm 3 Br b? Tm 3 Br p? Tm 3 I b? Tm 3 I p? Tm 3 N b? Tm 3 P b? Tm 3 As b? Tm 3 H b? U 2 O e unchecked U 3 S e unchecked U 3 F p? U 3 F e unchecked U 3 Cl p? U 3 Br p? U 3 I p? U 4 O b? U 4 O p? U 4 S e unchecked U 4 F a? U 4 F b? U 4 F p? U 4 Cl p? U 4 Br p? U 4 Br e unchecked U 4 I e unchecked U 4 N e unchecked U 5 O b? U 5 O p? U 5 F b? U 5 F p? U 5 Cl b? U 5 Cl p? U 5 Br e unchecked U 6 O r? U 6 O a? U 6 O p? U 6 F p? U 6 Cl p? U 6 N e unchecked U 9 Br b? U 9 I b? U 9 S b? U 9 Se b? U 9 Te b? U 9 N b? U 9 P b? U 9 As b? U 9 H b? V 1 O e unchecked V 1 Cl e unchecked V 2 O e unchecked V 2 S e unchecked V 2 F e unchecked V 2 Cl e unchecked V 3 O a? V 3 O j from transition metal complexes V 3 S e unchecked V 3 S j? V 3 F b? V 3 Cl b? V 3 Br e unchecked V 3 N j from transition metal complexes V 3 N e unchecked V 4 O a? V 4 O j from transition metal complexes 12/13
13 Page 25/26 V 4 O j vanadyl bond only V 4 S j from transition metal complexes V 4 S j vanadyl bond only V 4 S e unchecked V 4 F b? V 4 Cl b? V 4 N j from transition metal complexes V 5 O a? V 5 O x? V 5 S e unchecked V 5 F e unchecked V 5 Cl b? V 9 O ag All oxidation states V 9 O o? V 9 Br b? V 9 I b? V 9 S b? V 9 Se b? V 9 Te b? V 9 N b? V 9 P b? V 9 As b? V 9 H b? W 5 O e unchecked W 6 O a? W 6 O x? W 6 O b? W 6 F b? W 6 Cl b? W 9 Br b? W 9 I b? W 9 S b? W 9 Se b? W 9 Te b? W 9 N b? W 9 P b? W 9 As b? W 9 H b? Xe 2 O e unchecked Xe 2 F e unchecked Xe 4 F e unchecked Xe 6 O e unchecked Xe 6 F e unchecked Xe 8 O e unchecked Y 3 O a? Y 3 O b? Y 3 S b? Y 3 Se b? Y 3 Te b? Y 3 F b? Y 3 F e unchecked Y 3 Cl b? Y 3 Br b? Y 3 I b? Y 3 N b? Y 3 P b? Y 3 As b? Y 3 H b? Yb 3 O a? Yb 3 O b? Yb 3 O ae from transition metal complexes Yb 3 S b? Yb 3 Se b? Yb 3 Te b? Yb 3 F b? Yb 3 F p? Yb 3 F e unchecked Yb 3 Cl b? Yb 3 Cl p? Page 26/26 Yb 3 Br b? Yb 3 Br p? Yb 3 I b? Yb 3 I p? Yb 3 N ah? Yb 3 N b? Yb 3 P b? Yb 3 As b? Yb 3 H b? Zn 2 O a? Zn 2 O o? Zn 2 S b? Zn 2 Se b? Zn 2 Te b? Zn 2 F b? Zn 2 F e unchecked Zn 2 Cl b? Zn 2 Br b? Zn 2 I b? Zn 2 N e unchecked Zn 2 P b? Zn 2 As b? Zn 2 H b? Zr 2 O e unchecked Zr 2 F e unchecked Zr 2 Cl e unchecked Zr 4 O a? Zr 4 O b? Zr 4 S b? Zr 4 Se b? Zr 4 Te b? Zr 4 F a? Zr 4 F b? Zr 4 Cl b? Zr 4 Br b? Zr 4 I b? Zr 4 N b? Zr 4 N e unchecked Zr 4 P b? Zr 4 As b? Zr 4 H b? EOF EOF EOF EOF EOF EOF EOF EOF 13/13
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