Kleiner als Nano: Chips aus dem Reagenzglas
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1 Kleiner als Nano: Chips aus dem Reagenzglas Ferdinand Evers Institute of Nanotechnology and Institut für Theorie der Kondensierten Materie Karlsruhe Institute of Technology
2 Chips aus dem Reagenzglas: I. Motivation
3 CMOS-Halbleiter Technologie
4 CMOS-Halbleiter Technologie
5 CMOS-Halbleiter Technologie
6 CMOS-Halbleiter Technologie
7 CMOS-Halbleiter Technologie
8 CMOS-Halbleiter Technologie
9 Chips aus dem Reagenzglas: II. Ideen und Konzepte
10 Formale/Minimale Aufgaben / 42
11 Formale/Minimale Aufgaben Eingabe Information kodieren einlesen & speichern / 42
12 Formale/Minimale Aufgaben Eingabe Information kodieren einlesen & speichern Rechenwerk Information ver- / be- arbeiten / 42
13 Formale/Minimale Aufgaben Eingabe Information kodieren einlesen & speichern Rechenwerk Information ver- / be- arbeiten / Ausgabe Resultate speichern/ausgeben 42
14 II.1 Molekuele speichern Beispiele binaerer, mechanischer Speicherelemente
15 II.1 Molekuele speichern Beispiele binaerer, mechanischer Speicherelemente H2-Phtalocyanine (H2Pc) (STM) N C H
16 II.1 Molekuele speichern Beispiele binaerer, mechanischer Speicherelemente H2-Phtalocyanine (H2Pc) (STM) Sn-Phtalocyanine (SnPc) (STM) N C H
17 II.1 Molekuele speichern Beispiele binaerer, mechanischer Speicherelemente H2-Phtalocyanine (H2Pc) (STM) Sn-Phtalocyanine (SnPc) (STM) N C H Azobenzene (Light)
18 II.1 Molekuele speichern Beispiele binaerer, elektronischer Speicherelemente Magnetische Speicher Ruben group, KIT, Angwandte Chemie 2009 weitere: - elektrische Ladung - elektrisches Dipolmoment - Quadrupolmoment - etc.
19 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: STM (Frueherer Vortrag von Regine Hoffmann-Vogel)
20 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: STM Wulfhekel group, (Frueherer Vortrag von Regine Hoffmann-Vogel) KIT, 2009
21 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: STM Wulfhekel group, (Frueherer Vortrag von Regine Hoffmann-Vogel) KIT, 2009
22 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: STM Wulfhekel group, (Frueherer Vortrag von Regine Hoffmann-Vogel) KIT, 2009
23 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: STM Wulfhekel group, (Frueherer Vortrag von Regine Hoffmann-Vogel) KIT, 2009
24 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: Bruchkontakte H. Weber, von Loehneysen group, INT (2003)
25 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: Bruchkontakte H. Weber, von Loehneysen group, INT (2003)
26 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: Bruchkontakte H. Weber, von Loehneysen group, INT (2003)
27 II.2 Manipulation einzelner Molekuele Strategien zum Kontaktieren: Bruchkontakte
28 II.4 Molekulare Netzwerke 2D und 3D Architekturen
29 II.4 Molekulare Netzwerke 2D und 3D Architekturen Woell group, KIT Nature Nanotechnolgy 2009
30 II.4 Molekulare Netzwerke 2D und 3D Architekturen Yaghi group, Northwestern University, Science 2009 Woell group, KIT Nature Nanotechnolgy 2009
31 II.4 Molekulare Netzwerke 2D und 3D Architekturen Yaghi group, Northwestern University, Science 2009 Woell group, KIT Nature Nanotechnolgy 2009 Kitagawa, CREST Japan, Nature Materials 2010
32 II.4 Molekulare Netzwerke 2D und 3D Architekturen Yaghi group, Northwestern University, Science 2009 Woell group, KIT Nature Nanotechnolgy 2009 Kitagawa, CREST Japan, Nature Materials 2010
33 Chips aus dem Reagenzglas: III. Physikalische Effekte in Theorie und Experiment
34 III.1 H2-Pc Speicher STM experiment, Repp et al., IBM-lab Zurich, Science 2007 scanning tunneling microscope (STM)
35 III.1 H2-Pc Speicher STM experiment, Repp et al., IBM-lab Zurich, Science 2007 scanning tunneling microscope (STM)
36 III.1 H2-Pc Speicher Einfuehrung in die Wellenmechanik: Beispiel Wasser Wellenzustand fuer Wasser mit periodisch angeordneten Inseln -mehrere Muster sind moeglich, je nach Frequenz der auf- und ab- Bewegung Quantenmechanik der Elektronen Impuls = h/wellenlaenge (p h/λ) (h: Planck sches Wirkungsquantum) -die Muster sind zaehlbar, d.h. nur eine gewisse diskrete Anzahl an Frequenzen und Wellenlaengen kann auftreten. z. B.: Energie = p 2 /2m (h/λ) 2 / 2m (m: Elektronenmasse; λ: Wellenlaenge)
37 III.1 H2-Pc Speicher Quantenmechanische Wellenzustaende der Elektronen hoechstes besetztes Orbital (HOMO) niedrigstes unbesetztes Orbital (LUMO)
38 III.1 H2-Pc Speicher Quantenmechanische Wellenzustaende der Elektronen hoechstes besetztes Orbital (HOMO) in der Energieluecke niedrigstes unbesetztes Orbital (LUMO)
39 III.2 Molekularer Schalter Tour molecule
40 III.2 Molekulare Bistabilitaet Loertscher, Ciszek, Tour, IBM-lab Zurich, SMALL 06
41 III.2 Molekulare Bistabilitaet Loertscher, Ciszek, Tour, IBM-lab Zurich, SMALL 06
42 III.2 Molekularer Schalter Loertscher, Ciszek, Tour, Riel, SMALL 06
43 III.2 Molekularer Schalter Loertscher, Ciszek, Tour, Riel, SMALL 06
44 III.2 Molekularer Schalter Control experiment
45 III.2 Molekularer Schalter Control experiment
46 III.2 Molekularer Schalter Control experiment
47 III.2 Molekularer Schalter Control experiment
48 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
49 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
50 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
51 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
52 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
53 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
54 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
55 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
56 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science 2008.
57 III.2 Molekularer Schalter Competing theoretical proposals: Polaron A. Nitzan, M. Ratner, Science Aufladung ist instabil
58 III.2 Molekularer Schalter Competing theoretical proposals: two axis rotation
59 III.2 Molekularer Schalter Competing theoretical proposals: two axis rotation Meded, Arnold, Bagrets, FE, SMALL '09
60 III.2 Molekularer Schalter Competing theoretical proposals: two axis rotation Meded, Arnold, Bagrets, FE, SMALL '09
61 III.2 Molekularer Schalter Kink deformation and out of plane dipole moment
62 III.2 Molekularer Schalter Kink deformation and out of plane dipole moment
63 III.2 Molekularer Schalter Kink deformation and out of plane dipole moment
64 III.2 Molekularer Schalter Kink deformation and out of plane dipole moment annihilating dipole moments within the plane! No force!!
65 III.2 Molekularer Schalter Kink deformation and out of plane dipole moment annihilating dipole moments within the plane! No force!!
66 III.2 Molekularer Schalter Kink deformation and out of plane dipole moment nonvanishing dipole moments out of the plane!! Bias voltage exerts force! annihilating dipole moments within the plane! No force!!
67 III.2 Molekularer Schalter -- Theorie Theorie und Simulation animation: Christian Seiler, KIT
68 III.2 Molekularer Schalter Theorie und Simulation: Resultate
69 III.2 Molekularer Schalter Theorie und Simulation: Resultate experiment
70 III.2 Molekularer Schalter Theorie und Simulation: Resultate experiment theory
71 III.2 Molekularer Schalter -- Theorie Theorie und Simulation: Methoden Δ
72 III.2 Molekularer Schalter -- Theorie Theorie und Simulation: Methoden Δ Manpower: ca. 2 Jahre Postdoc Computerzeit: ca h standard CPU Gesamte Projektlaufzeit: ca. 3 Jahre
73 KIT (links nach rechts, vorne) Stephan Bernadotte Hideaki Obuse Alexei Bagrets Michiel van Setten Soumya Bera & Velimir Meded Arindam Dasgupta Christian Seiler Collaborators: K. Fink, M. Ruben, F. KIT... and many international partners
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