/J-/~-'//3. Table Of Contents 1/ -,Q 3-1,:':5. /Y/b3U'7 _!,!13. ANALYSIS: =P ~~~~ \6.IL METHOD NO.: 2()2t~

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1 / Table Of Contents ANALYSS: =P \6.L METHOD NO.: 2()2t ARDL Report(s) #: ((25 Lo;]; le51tz3 MATRX: L i OJ u.. PAGE Organic Package Review Checklist... Case Narrative and/or Nonconformance Reports... Sample Receipt nformation... Field Sample Results... QC Summary Forms... Sample Preparation nformation... Standard Preparation nformation... Analytical Run Data... Example Calculation... Miscellaneous Additional Data... Package Preparation Analytical Review Final Review QA Review 1/ -Q 3-1:':5 /Y/b3U'7 i /l-4-h -- _!!13 /J-/-'//3 Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 1 of 594

2 Organic Package Review Checklist Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 2 of 594

3 ORGANC PACKAGE REVEW CHECKLST METHOD: 8 K ( p Case Narrative and/or Nonconformance Reports Case Narrative / Analyst Comment Sheets.... Nonconformance / Noncompliance Reports (if applicable).... Sample Receipt nformation Copies of Original Chain-of-Custody Forms..... Cooler Receipt Form and Airbills.... Phone Messages (f applicable)..... Field Sample Results nitial Date fjrl tjfr QC Summary Forms Surrogate Summary if applicable... j Pr Spike Blank and/or MS Summary... Blank Results & Blank Summary if applicable... STD Area Summary if applicable......!; A Sample Preparation nformation (if applicable) Total Solids Determination (f applicable)... Extraction Log (f applicable)... Extraction Notebook Pages (f applicable)... Spiking Solutions Notebook Pages... MS/MSD's... Surrogate/lSTDs...:... Spiking Solutions Certificates Of Analyses... MS/MSD's... Surrogates/STDs... Certificates of Analysis (Vendor).....;j - Standard Preparation nformation nstrument Logs/Analysis Notebook Pages.... Certificates of Analysis (Vendor).... PJ$C.!ld3Jp fj1l vj{)31 1. J kljojj).j j Analytical Run Number 1 Calibration nformation.... a;- Tune Data.... nitial Calibration.... Continuing Calibration.... nstrument Logs/Analysis Notebook Pages.... Blank/Sample/Field QC Data.... i-+-- Analytical Run Number 2 (if required) Calibration nformation.... Tune Data.... nitial Calibration.... Continuing Calibration.... nstrument Logs/Analysis Notebook Pages..... Blank/Sample/Field QC Data... 1-"'. Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 3 of 594

4 ORGANC PACKAGE REVEW CHECKLST (Continued) METHOD: Z (!)?r ( B Analyti:ir:n:ti..i Tune Data.... nitial Calibration.... Continuing Calibration.... nstrument Logs/Analysis Notebook Pages.... Blank/Sample/Field QC Data.... Analytical Run Number 4 (if required) Calibration nformation.... Tune Data.... nitial Calibration.... Continuing Calibration.... nstrument Logs/Analysis Notebook Pages.... Blank/Sample/Field QC Data.... Analytical Run Number 5 (if required) Calibration nformation.... Tune Data.... nitial Calibration.... Continuing Calibration.... nstrument Logs/Analysis Notebook Pages... :.... Blank/Sample/Field QC Data.... Analytical Run Number 6 (if required) Calibration nformation.... Tune Data.... nitial Calibration.... Continuing Calibration.... nstrument Logs/Analysis Notebook Pages.... Blank/Sample/Field QC Data.... Example Calculation Example Calculation Sheet.... Miscellaneous Additional Data (if applicable).... have checked this package for completeness and verify the following: 1. Pencils whiteout whiteout tape and dark highlighters were not used. 2. All notebook pages are signed. 3. All corrections contain the original data "struck through" with initials and date. 4. All comments found throughout the data are defined as required. 5. All pages are legible. 6. Manual integrations if applicable are printed out and include an explanation with signature of the analyst and date. nitial Date /J-- -l---- NA = Not Applicable Package Completeness Checked BylDate: o:t..----t:..----f--+-'--) Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 4 of 594

5 Case Narrative and/or Nonconformance Reports Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 5 of 594

ORGANC ANALYSS CASE NARRATVE Corps of Engineers - ERDC Vicksburg Date: 11/26/13 ARDL Report No.: 65626563 Lab Name: ARDL nc.

D No. Collected Date Extracted Analsis Reguested 6562-1 MAK1 L/2L/26L 9/27/213 11/18/13 OCP 6562-2 MAK7L 9/16/213 11/18/13 OCP 6562-3 MAK9L 9/16/213 11 /18/13 OCP 6562-4 MAK1L(comp) 9/16/213 11/18/13

6 ORGANC ANALYSS CASE NARRATVE Corps of Engineers - ERDC Vicksburg Date: 11/26/13 ARDL Report No.: Lab Name: ARDL nc. Project Name: MAKAU MLTARY RESERVATON OAHU (LMU) Samples Received at ARDL: 11/7/213 Lab Sample Date D No. D No. Collected Date Extracted Analsis Reguested MAK1 L/2L/26L 9/27/213 11/18/13 OCP MAK7L 9/16/213 11/18/13 OCP MAK9L 9/16/ /18/13 OCP MAK1L(comp) 9/16/213 11/18/13 OCP MAK11L 9/16/213 11/18/13 OCP MAK13L 9/18/213 11/18/13 OCP MAK16L/21L/27L 9/27/213 11/18/13 OCP MAK22L 9/27/213 11/18/13 OCP MAK23L 9/27/213 11/18/13 OCP MAK24L/25L 9/27/213 11/18/13 OCP MAK25L 9/27/213 11/18/13 OCP MAK47L 1/15/213 11/18/13 OCP MAK29L 1/11/213 11/19/13 OCP MAK3L 1/11/213 11/19/13 OCP MAK33L 1/11/ /19/13 OCP MAK34L 1/11/213 11/19/13 OCP MAK38L 1/11/213 11/19/13 OCP MAK41L 1/11/213 11/19/13 OCP MAK42L 1/11/213 11/19/13 OCP MAK43L 1/11/213 11/19/13 OCP MAK44L 1/15/213 11/19/13 OCP MAK45L 1/15/213 11/19/13 OCP MAK46L 1/15/213 11/19/13 OCP MAK49L 1/15/213 11/19/13 OCP ORGANOCHLORNE PESTCDES FRACTON - METHOD 8818 Twenty five (25) tissue (limu) samples were received by ARDL nc. on November for OCP analysis. One sample MB-SO-LMUOOO-TEST was provided for evaluation of test methods only. An abbreviated target list was requested for these analyses. Due to sample matrix 5. grams of sample were extracted. Method detection and reporting limits have been adjusted accordingly. All samples were put through the Gel Permeation Cleanup procedure. NTAL CALBRATON The initial calibration was performed using a minimum of five (5) calibration points and met all criteria. CONTNUNG CALBRATON Continuing calibration was performed after the analysis of 1 O samples or less. All calibration criteria were met. SURROGATES These samples were spiked with surrogate at a level of 4 ug/kg. All samples met surrogate recovery criteria. NTERNAL STANDARD Not applicable. Page 1 of 2 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 6 of 594

7 ORGANC ANALYSS CASE NARRATVE Corps of Engineers - ERDC Vicksburg Date: 11/26/13 ARDL Report No.: Lab Name: ARDL nc. Project Name: MAKAU MLTARY RESERVATON OAHU (LlMU) Samples Received at ARDL: 11/7/213 The LCS samples were spiked at a concentration of 4 ug/kg. The LCS samples met recovery ranges. MATRX SPKE/MATRX SPKE DUPLCATE The MS/MSD analyses were performed on samples MAK47L and MAK49L. The MS/MSD samples were spiked at a concentration of 4ug/Kg. Due to matrix effects the MS/MSD analyses exhibited recoveries for several analytes outside the supplied recovery ranges. The following table lists recoveries outside limits: Samples Analyte % Recovery Recovery Limits MAK47LMS delta-bhc 141% 48% -118% MAK47LMSD delta-bhc 13% 48% -118% MAK49LMS delta-bhc 173% 48% -118% MAK49LMSD delta-bhc 142% 48% - 118% MAK49LMS beta-bhc 142% 5% -111% MAK49LMSD Heptachlor 51% 52% -114% The MS/MSD analyses on sample MAK49L exhibited % RPDs for Heptachlor pp'-ddt and beta-bhc of 32% 39% and 37% respectively which are above the 25% RPD limit. As the blanks spike blanks and MS/MSD samples met surrogate recovery criteria there is no adverse effect on the data. METHOD BLANKS No target analytes were detected in the method blank above the method limit. ORGANC DATA REPORTNG QUALFERS The following organic data reporting qualifiers are used as required. ND- J - P - ndicates compound was analyzed for but not detected. The sample quantitation limit must be corrected for dilution and for percent moisture. ndicates an estimated value. This flag is used when estimating a concentration of a compound that meets identification criteria but the result is less than the quantitation or reporting limit but greater than the method detection limit. This flag is used for any two column confirmation methodology when there is greater than 4% difference for detected concentrations between the two columns. The primary column value is reported on the Form 1 and flagged with a "P". B - This flag is used when the analyte is found above the reporting limit in the blank as well as the sample. t indicates possible/probable blank contamination and warns the data user to take appropriate ivl action. Release of the data contained in this package has been authorized by th;;)hnical rvice. age7;\1lis designee as verified by the following signature. uy Dean S. Dickerson Technical Services Manager Page 2 of 2 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 7 of 594

8 Sample Receipt nformation Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 8 of 594

9 P.O. Box Aviation Drive Mount Vernon llinois Phone (618) Fax (618) CHAN OF CUSTODY RECORD ARDL nc ARDl nc PRESERVATON 'roject (/) (/) -... c Q) \RDL Makau Military Reservation Oahu Hawaii Project c 2l 3AMPLERS (Signature) C co Remarks or Sample Specify ::a Location Chemicals ill added and (/).. 1 (L final ph if E.J:l '1=l: - SAMPLE NUMBER DATE TME... co :::N > known C'O C") C") C'O.- '- Q) (/) co N Q) co > co 4- (/) 18m C9 (Lco ill (f) MAKOO1Lj2Lj26L 9/9-27/13 varies x 1 x x x x Limu x MAKOO7L 9/16/ x 1 x x x x Limu x MAKOO9L 9116/ x 1 x x x x Limu x MAK1L (comp) 9/16/213 varies x 1 x x x x Limu x MAKOllL 9/16/ x 1 x x x x Limu x MAK13L 9/18/ x 1 x x x x Limu x MAK16Lj21Lj27L 9/23-27/13 varies x 1 x x x x Limu x MAK22L 9/27/ x 1 x x x x Limu x MAK23L 9/27/ x 1 x x x x Limu x MAK24Lj25L 9/27/ x 1 x x x x Limu x MAK25L 9/27/ x 1 x x x x Limu x MAK29L 1/11/ x 1 x x x x Limu x MAK3L 1/11/ x 1 x x x x Limu x MAK33L 1/11/ x 1 x x x x Limu x MAK34L 1/11/ x 1 x x x x Limu x MAK38L 1/11/ x 1 x x x x Limu x MAK41L 1/11/ x 1 x x x x Limu x MAK42L 1/11/ x 1 x x x x Limu x MAK43L 1/11/ x 1 x x x x Limu x MAK44L 1115/ x 1 x x x X ': Limu x MAK45L 1/15/ x 1 x x x x Limu x MAK46L 1/15/ x 1 x x x x Limu x MAK47L 1/15/ x 1 x x x x Limu x MAK49L 1/15/ x 1 x x x x Limu x R'Sig""re) Date Time Relinquished by: (Signature) REMARKS SPECAL NSTRUCTONS: q lol") bosu Relinquished by: (Signature) Date Time Relinquished by: (Signature) Test samples - please process this group before or witr the accompanying project samples. Date Time Shipping Ticket No. Please send level 4 hardcopy report and excel edd to: Dean Dickerson ca ARDL nc. 4 Aviation Drive Mount Vernon L bo_ (Signa ure CJ d r ff/; (JCJSO - it?:;7v 'lis questons to ddickerson@ardlinc.com. ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 9 of 594 [/

10 P.O. Box Aviation Drive Mount Vernon llinois Phone_(618) Fax (618) ARD L n C!Project (f) (/) () 1:: co "- o ([) gs co N ARDL Makau Military Reservation Oahu Hawaii projectl. g m '- C<) SAMPLERS (Signature) <):: > "+- co: -- co U) \ CD co (J) TME l 'l*... UJO (J) -MA-Ki1el"3'C -lest g/-3..-iQ.Qe-1 -x=l 1 -K--'-X--X-. SAMPLE NUMBER DATE M&Se=HE:E6e J-=-=r-est-l-8f.292G-1-=rB4-H--X=--1-_. _l--x--l-x-- MB-SO-UMUOOO-test 8/29/ X 1 1 X X 'X X 1-7rl- x. -i-ri-p-biam 1-9f:! Date Time Relinquished by: (ignature) it!gh fc.:. Date Time Relinquished by: (9ignature) Relinquished by: (Signature) /1 Rinquished by: (Signature) Date Time Shipping Ticket No.. f( 7;:'31'93 CHAN OF CUSTODY RECORD ARDl nc PRESERVATON Remarks or Sample Location o UJ o Specify Chemicals added and final ph if known eea-etctlmbe-r.-cl.t:-tn n Umu ---*- -.2L X REMARKS SPECAL NSTRUCTONS: Test samples - please process this group before or with the accompanying project samples. Please send level 4 hardcopy report and excel edd to: Dean Dickerson ca ARDL nc. 4 Aviation Drive Mount Vernon L questonstoddickerson@ardlinc.com. ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 1 of 594 Received for Laboratory by: (Si g na)!4. -P /f J!hcC4/YL '--'"t

11 ARDL#: COOLER RECEPT REPORT ARDL NC. Cooler # Project:!l/aKo/J.1f}Jid" d.jw. Date Received: LJ! Pi Number of Coolers in Shipmet: _----<-1 ilj :t13 :. ::::::o::::'::;:: ::::'::).:':::::'.:":L(lg::':r:)T?! NO ;:::&()/(:1 J( 7 t<. K;=ii=:- _ f YES enter carrier name and airbill number here: 9'32S / JJ % f % 331.p Were custody seals on outside of cooler?...@ NO How many and where?. +"o:nj: SeaDate:/Oa-:sseaName: \ t+ Were custody seals unbroken and intact at the date and time of NO Did you screen samples for radioactivity using a Geiger :> NO 1/ Were custody papers sealed in a plastic bag and NO 6. Were custody papers filled out properly (ink signed NO N/A 7. Were custody papers signed in appropriate place by ARDL NO N/A 8. Was project identifiable from custody papers? f YES enter project name at the top of this NO N/A 9. Was a separate container provided for measuring temperature? YES NO Cooler Temp. - 3/ Y C B. LOG-N PHASE: D'"mpl" we" logg'd-o: '--13 (Slg"") JA )\ 1. Describe type of packing in cooler: A' Q" kk1o o Were all bottles sealed in separate plastic bags?... QW NO N/A 12. Did all bottles arrive unbroken and were labels in good NO 13. Were bottle labels complete?... :... (:(W NO 14. Did all bottle labels agree with custody NO 15. Were correct containers used for the tests indicated?... NO 16. Was ph correct on preserved water samples?... YES NO c:!jjs) N/A 17. Was a sufficient amount of sample sent for tests indicated?... NO 18. Were bubbles absent in VOA samples? f NO list by sample #: YES NO 19. Was the ARDL project coordinator notified of any deficiencies?... YES NO Comments and/or Corrective Action: Fraction Sample Transfer Fraction r-ttl Area # Area # Freezerc. By.hw On! / -b<-:f -- By On (By: Signature) Date: M:ADMN\FORMS\COOLER RECEPT REPORT.doc Rev. 5/717 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 11 of 594

12 Field Sample Results Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 12 of 594

13 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : NELAC Certified - L138 Analytical Method: 881B Prep Method: 355A Field D: Desc/Location: Sample Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: Parameter Method Reporting Limit Limit Result Data Flag Dilution Units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc SURROGATE RECOVERES: 1 Tetrachloro-m-xylene 1 Decachlorobiphenyl Limits Results 33% 7% 1 Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 13 of 594

14 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Project No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK7L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 9/16/213 Received Date: 11/7/213 Sample Time: 132 Prep. Date: 11/18/213 Matrix: TSSUE Analysis Date: 11/2/213 Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: B113 % Moisture: No Moisture Present Level: LOW Method Reporting Data Dilution Parameter Limit Limit Result Flag units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp'-ddt beta-bhc SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Results 71% 72% Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 14 of 594

15 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: Desc/Location: Sample Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: MAK9L MAKU MLTARY RESERVATON 9/16/ TSSUE 5 g 1 ml No Moisture Present ARDL Lab No. : Lab Filename: Received Date: Prep. Date: Analysis Date: nstrument D: QC Batcq: Level: /7/213 11/18/213 11/2/213 B113 LOW Parameter alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp'-ddt beta-bhc ND 4 ND 4 ND 4 ND 4 ND 4 ND 4 ND 4 ND UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG SURROGATE RECOVERES: Limits Results Tetrachloro-m-xylene % Decachlorobiphenyl % Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 15 of 594

16 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Project No. : NELAC certified - L138 Analytical Method: 881B Prep Method: 355A Parameter UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results 62% 71% Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 16 of 594

17 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: Desc/Location: Sample Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: MAK11L MAKU MLTARY RESERVATON 9/16/ TSSUE 5 g 1 ml No Moisture Present ARDL Lab No. : Lab Filename: Received Date: Prep. Date: Analysis Date: nstrument D: QC Batch: Level: /7/213 11/18/213 11/2/213 B113 LOW Parameter alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp 1 -DDT beta-bhc ND 4 ND 4 ND 4 ND 4 ND 4 ND 4 ND 4 ND UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results 34% 59% Surrogate recoveries marked with 1*1 indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 17 of 594

ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois 62864 Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Project No.

: 6562-6 Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date : 9/18/213 Received Date: 11/7/2 13 Sample Time: 75 Prep.

18 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Project No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A! Field D: MAK13L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date : 9/18/213 Received Date: 11/7/2 13 Sample Time: 75 Prep. Date : 11/18/213 Matrix : TSSUE Analysis Date: 11/2/213 Amount Used : 5 g nstrument D: Final Volume: 1 ml QC Batch: B113 % Moisture : No Moisture Present Level : LOW! Method Reporting Data Dilution Pa rameter Li mit Limit Result Flag Units Factor! alpha-bhc p gamma-bhc (Lindane) 4 4 ND delta-bhc 4 4 ND Heptachlor p Aldrin Heptachlor Epoxide pp' -DDT 4 4 ND beta-bhc! jsurrogate RECOVERES: jtetrachloro- m-xylene jdecachlorobiphenyl Limits Results 3 7% 65 %! Surrogate recoveries marked wi th ' * ' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 18 of 594

19 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: Desc/Location: Sample Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: TSSUE 5 g 1 ml No Moisture Present Parameter alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc P P SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results % % Surrogate recoveries marked with '* indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 19 of 594

20 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Field D: MAK22L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 9/27/213 Received Date: 11/7/213 Sample Time: 1255 Prep. Date: 11/18/213 Matrix: TSSUE Analysis Date: 11/2/213 Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: B113 % Moisture: No Moisture Present Level: LOW Method Reporting Data Dilution Parameter Limit Limit Result Flag units Factor alpha-bhc P gamma-bhc (Lindane) delta-bhc Heptachlor P Aldrin Heptachlor Epoxide pp' -DDT beta-bhc SURROGATE RECOVERES: Limits Results Tetrachloro-m-xylene % Decachlorobiphenyl % Surrogate recoveries marked with '* indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 2 of 594

21 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: Desc/Location: Sample Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: MAK23L MAKU MLTARY RESERVATON 9/27/ TSSUE 5 g 1 ml No Moisture Present ARDL Lab No. : Lab Filename: Received Date: Prep. Date: Analysis Date: nstrument D: QC Batch: Level: /7/213 11/18/213 11/21/213 B113 LOW Parameter Method Reporting Limit Limit Result SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 21 of 594

22 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/9/213 1 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (SOSl) 1 Project No. : Analytical Method: SOSlB 1 NELAC Certified - L13S Prep Method: 355A l Field D: MAK24L/25L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 9/27/213 Received Date: 11/7/2l3 Sample Time: 1255 Prep. Date: 11/1S/213 Matrix: TSSUE Analysis Date: 11/21/213 Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: B113 % Moisture: No Moisture Present Level: LOW Method Reporting Data Dilution 1 Parameter Limit Limit Result Flag Units Factor alpha-bhc P 1 gamma-bhc (Lindane) 1 delta-bhc 1 Heptachlor 1 Aldrin ND ND 67. ND P UG/KG UG/KG UG/KG UG/KG Heptachlor Epoxide 4 4 ND pp' -DDT 4 4 ND beta-bhc 4 4 ND SURROGATE RECOVERES: 1 Tetrachloro-m-xylene 1 Decachlorobiphenyl Limits Results 4S% 64% Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (SOSl) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 22 of 594

23 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (SOSl) Proj ect No. : Analytical Method: SOSlB NELAC Certified - L13S Prep Method: 355A Field D: MAK25L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 9/27/213 Received Date: Sample Time: 1255 Prep. Date: Matrix: TSSUE Analysis Date: Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: % Moisture: No Moisture Present Level: /7/213 11/1S/213 11/21/213 B113 LOW Parameter Method Reporting Limit Limit Result Data Flag Dilution units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc P 1 SURROGATE RECOVERES: Limits Results. 1 Tetrachloro-m-xylene S% 1 1 Decachlorobiphenyl % Surrogate recoveries marked with '* indicates they are outside standard limits. Sample CHLORNATED PESTCDES (SOSl) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 23 of 594

24 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Project No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK47L ARDL Lab No.: Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/15/213 Received Date: 11/7/213 Sample Time: 1158 Prep. Date: 11/18/213 Matrix: TSSUE Analysis Date: 11/21/213 Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: B113 % Moisture: No Moisture Present Level: LOW Method Reporting Data Dilution Parameter Limit Limit Result Flag Units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Results 11% 64% Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 24 of 594

25 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 r Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV.Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC certified - L138 Prep Method: 355A Field D: MAK29L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/11/213 Received Date: Sample Time: Matrix: Amount Used: Final Volume: 155 TSSUE 5 g 1 ml Prep. Date: Analysis Date: nstrument D: QC Batch: %- Moisture: No Moisture Present Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter Method Reporting Limit Limit Result Data Flag Dilution Units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide PP' -DDT beta-bhc SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results 55%- 32% Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 25 of 594

26 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK3L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/11/213 Received Date: Sample Time: Matrix: 95 TSSUE Prep. Date: Analysis Date: Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: % Moisture: No Moisture Present Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter Method Reporting Limit Limit Result Data Flag Units Dilution Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide PP' -DDT beta-bhc SURROGATE RECOVERES: Limits Results Tetrachloro-m-xylene %. Decachlorobiphenyl % Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 26 of 594

27 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : 'Analytical Method: 881B NELAC certified - L138 Prep Method: 355A Field D: MAK33L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/11/2'13 Received Date: Sample Time: Matrix: Amount Used: Final Volume: %' Moisture: 15 TSSUE 5 g 1 ml No Moisture Present Prep. Date: Analysis Date: nstrument D: QC Batch: Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter Method Reporting Limit Limit Result Data Flag Dilution Units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results 46%' 44% Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 27 of 594

28 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: B81B NELAC Certified - L13B Prep Method: 355A Field D: MAK34L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/11/213 Received Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: 15 TSSUE 5 g 1 ml No Moisture Present Prep. Date: Analysis Date: nstrument D: QC Batch: Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter Method Reporting Limit Limit Result Data Dilution Flag Units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide PP' -DDT beta-bhc ' SURROGATE RECOVERES: 1 Tetrachloro-m-xylene 1 Decachlorobiphenyl Limits Results 29% 38% 1 Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 28 of 594

29 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : NELAC Certified - L138 Analytical Method: 881B Prep Method: 355A Parameter Method Reporting Limit Limit Result Data Flag Dilution units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc SURROGATE RECOVERES: Limits Results Tetrachloro-m-xylene % Decachlorobiphenyl % Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 29 of 594

30 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 \ Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK41L ARDL Lab No. : Desc/Location: Sample Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: Parameter alpha-bhc MAKU MLTARY RESERVATON 1/11/ TSSUE 5 g gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide PP' -DDT beta-bhc 1 ml No Moisture Present Lab Filename: Received Date: Prep. Date: Analysis Date: nstrument D: QC Batch: Level: Method Reporting Limit Limit Result /7/213 11/19/213 11/21/213 B1132 LOW Data Flag Dilution Units Factor SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results Surrogate recoveries marked with '*' indicates they are outside standard limits. 39% 52% Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 3 of 594

31 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK42L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/11/213 Received Date: Sample Time: 14 Prep. Date: Matrix: TSSUE Analysis Date: Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: % Moisture: No Moisture Present Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter Method Reporting Limit Limit Result Data Flag Units Dilution Factor alpha-bhc' gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results 32% 41% Surrogate recoveries marked with '* indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 31 of 594

32 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK43L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/11/213 Received Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: 14 TSSUE 5 g 1 ml No Moisture Present Prep. Date: Analysis Date: nstrument D: QC Batch: Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter Method Reporting Limit Limit Result Data Flag Dilution Units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp'-ddt beta-bhc SURROGATE RECOVERES: 1 Tetrachloro-m-xylene 1 Decachlorobiphenyl Limits Results 43% 51% 1 Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 32 of 594

33 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK44L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/15/213 Received Date: Sample Time: Matrix: Amount Used: 925 TSSUE 5 g Prep. Date: Analysis Date: nstrument D: Final Volume: 1 ml. QC Batch: % Moisture: No Moisture Present Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter Method Reporting Limit Limit Result Data Flag Dilution units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp'-ddt beta-bhc 4 4. ND SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results 46% 56% Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 33 of 594

34 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK45L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/15/213 Received Date: Sample Time: 125 Prep. Date: Matrix: TSSUE Analysis Date: Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: % Moisture: No Moisture Present Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide PP' -DDT beta-bhc Method Reporting Limit Limit Result Data Dilution Flag Units Factor P SURROGATE RECOVERES: 1 Tetrachloro-m-xylene 1 Decachlorobiphenyl Limits Results 83% 51% 1 Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 34 of 594

35 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No.: Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK46L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/15/213 Received Date: Sample Time: 115 Prep. Date: Matrix: TSSUE Analysis Date: Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: % Moisture: No Moisture Present Level: /7/213 11/19/213 11/21/213 B1132 LOW Parameter Method Reporting Limit Limit Result Data Flag Dilution units Factor alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc P SURROGATE RECOVERES: 1 Tetrachloro-m-xylene 1 Decachlorobiphenyl Limits Results 88% 59% 1 Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 35 of 594

36 ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 12/5/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: MAK49L ARDL Lab No. : Desc/Location: MAKU MLTARY RESERVATON Lab Filename: Sample Date: 1/15/213 Received Date: 11/7/213 Sample Time: 1225 Prep. Date: 11/19/213 Matrix: TSSUE Analysis Date: 11/21/213 Amount Used: 5 g nstrument D: Final Volume: 1 ml QC Batch: B1132 % Moisture: No Moisture Present Level: LOW Method Reporting Parameter Limit Limit Result SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Surrogate recoveries marked with '*' indicates they are outside standard limits. Sample CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 36 of 594

37 QC Summary Forms Surrogate Summary if applicable Spike Blank and/or MS Summary Blank Results & Blank Summary if applicable STD Area Summary if applicable Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 37 of 594

38 ARDL NC. BLANK SPKE/SPKE DUPLCATE REPORT 4 Aviation Drive; P.O. Box 1566 Lab Report No: 6562 Project Name: MAKU MLTARY RESERV Proj ect No. : Analysis: CHLORNATED PESTCDES (88l) Matrix: Amount Used: QC Material 5 g QC Batch: Level: BlOl3 LOW Spike Parameter Result Spike Level Spike Duplicate Duplicate % Rec Result Level alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp'-ddt beta-bhc SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Spike %R Duplicate %R '*' indicates a recovery outside of standard limits. Spike Blanks for CHLORNATED PESTCDES (881) Mt. Vernon L Report Date: ll/2l/2l3 Analytical Method: 88lB Prep Method: 355A Prep. Date: ll/l8/2l3 Analysis Date: ll/2/2l3 Duplicate Recovery % Rec Limits RPD RPD Limit %R Limits Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 38 of 594

39 Lab Report No: 1l/21/2l3 MATRX SPKE/SPKE DUPLCATE REPORT ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon L Report Date: Project Name: MAKU MLTARY RESERV Project No.: Analysis: CHLORNATED PESTCDES (881) Analytical Method: 881B Prep Method: 355A Field D: MAK47L Desc/Location: MAKU MLTARY RESERVATON Sample Date: 1/15/213 Sample Time: 1158 Matrix: MSC MATERAL Prep. Date: Amount Used: % Moisture: QC Batch: Level: 11/18/213 5 g No Moisture Present B113 LOW ARDL Lab No. : Lab Filename: Received Date: 11/7/213 Analysis Date: 11/21/213 Sample Parameter Result MS MS Result Level MS % Rec MSD Result MSD Level MSD % Rec % Rec Limits RPD RPD Limit alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc ND ND ND ND ND ND ND * * ll SURROGATE RECOVERES: Tetrach1oro-m-xylene Decachlorobiphenyl MS %R MSD %R %R Limits 'nc' indicates sample >4X spike level. f*' indicates a recovery outside of standard limits. Matrix Spikes for CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 39 of 594

40 ARDL NC. BLANK SPKE/SPKE DUPLCATE REPORT 4 Aviation Drive; P.O. Box 1566 Lab Report No: 6563 Project Name: MAKU MLTARY RESERV Proj ect No. : Analysis: CHLORNATED PESTCDES (88l) Matrix: Amount Used: QC Material 5 g QC Batch: Level: Bll32 LOW spike Parameter Result spike Level Spike Duplicate Duplicate % Rec Result Level alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp'-ddt beta-bhc SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Spike %R Duplicate %R * indicates a recovery outside of standard limits. Spike Blanks for CHLORNATED PESTCDES (881) T""T' Mt. Vernon L Report Date: 1l/22/2l3 Analytical Method: 88lB Prep Method: 355A Prep. Date: ll/l9/2l3 Analysis Date: ll/2l/2l3 Duplicate Recovery % Rec Limits RPD RPD Limit %R Limits Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 4 of 594

41 Lab Report No: llj22j2l3 MATRX SPKE/SPKE DUPLCATE REPORT ARDL NC. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon L Report Date: Project Name: MAKU MLTARY RESERV Proj ect No.: Analysis: CHLORNATED PESTCDES (88l) Analytical Method: 88lB Prep Method: 355A Field D: MAK49L Desc/Location: MAKU MLTARY RESERVATON Sample Date: lo/l5/2l3 Sample Time: l225 Matrix: MSC MATERAL Prep. Date: Amount Used: % Moisture: QC Batch: Level: lljl9/2l3 5 g No Moisture Present BlOl32 LOW ARDL Lab No.: 6563-l2 Lab Filename: Received Date: ll/7/2l3 Analysis Date: ll/2lj2l3 Sample Parameter Result MS MS Result Level MS % Rec MSD Result MSD Level MSD % Rec % Rec Limits RPD RPD Limit alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp'-ddt beta-bhc ND ND ND ND ND ND ND * * * 5.9 * * * * SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl MS %R MSD %R %R Limits 'nc' indicates sample >4X spike level. * indicates a recovery outside of standard limits4 Matrix Spikes for CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 41 of 594

42 METHOD BLANK REPORT ARDL nc. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6562 Report Date: 11/21/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : NELAC Certified - L138 Analytical Method: 881B Prep Method: 355A Field D: Desc/Location: Sample Date: Sample Time: Matrix: Amount Used: Final Volume: % Moisture: NA NA NA NA QC Material 5 g 1 ml NA ARDL Lab No. : Lab Filename: Received Date: Prep. Date: Analysis Date: nstrument D: QC Batch: Level: B1 NA 11/18/213 11/2/213 B113 LOW Parameter alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp' -DDT beta-bhc Method Reporting Data Limit Limit Result Flag ND ND ND ND ND ND ND ND units UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG SURROGATE RECOVERES: Tetrachloro-m-xylene Decachlorobiphenyl Limits Results % Surrogate recoveries marked with '*' indicates they are outside standard limits. Blank for Run B113 CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 42 of 594

43 METHOD BLANK REPORT ARDL nc. 4 Aviation Drive; P.O. Box 1566 Mt. Vernon llinois Lab Report No: 6563 Report Date: 11/22/213 Project Name: MAKU MLTARY RESERV Analysis: CHLORNATED PESTCDES (881) Proj ect No. : Analytical Method: 881B NELAC Certified - L138 Prep Method: 355A Field D: NA Desc/Location: NA Sample Date: NA Sample Time: NA Matrix: QC Material Amount Used: 5 g Final Volume: 1 ml!?o Moisture: NA Parameter alpha-bhc gamma-bhc (Lindane) delta-bhc Heptachlor Aldrin Heptachlor Epoxide pp '-DDT beta-bhc ARDL Lab No. : Lab Filename: Received Date: Prep. Date: Analysis Date: nstrument D: QC Batch: Level: B1 NA 11/19/213 11/21/213 B1132 LOW Method Reporting Data Limit Limit Result Flag ND ND ND ND ND ND ND ND units UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG SURROGATE RECOVERES: Limits Results Tetrachloro-m-xylene !? Decachlorobiphenyl !? Surrogate recoveries marked with '*' indicates they are outside standard limits. Blank for Run B1132 CHLORNATED PESTCDES (881) Page 1 of 1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 43 of 594

44 Sample Preparation nformation (Not Applicable for VOA Purge and Trap Method) Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 44 of 594

45 Pest SOLS DATE: 11/18/213 CUST:Maku Military Reservation Oahu BATCH # B113 ARDL# 6562 SAMPLES: BLK; PEST SP BLK; thru 12 QC SAMPLE: ms/msd SOLVENT USED: MeCL 2 # 628 Hexane # 4772 REAGENTS USED: Na 2 S 4 # Florisil # SURROGATE # PEST SPKE # CONC CONC 1 PPM _X_ AMOUNT 2 ul _X_ 1 PPM _X_ AMOUNT 2 ul _X_ EXTRACTON METHOD: SONCATON _X_ DLUTON MED/LEV FNAL VOLUME 1 ml CLEAN-UP METHOD: GPC X GPC CURVE DATE: 1/28/ Florisil EXTRACTON PERSONNEL: SMN JAD SPKER: SMN WTNESS: JAD SAMPLE # WEGHT 1 Q ph Vf SAMPLE # WEGHT 1 Q ph Vf BLK 5. Q ml ms 5.3 q ml SP BLK 5. Q " " msd 5.2 q " " Q " " " " Q " " Q " " " " " " " " " " " " " " " " " " RECEVED BY: _--=.V-""--' DATE: -Lf-'--'q'_+L- ;::1 DELVERED BY: ---.::::o.5:.-..:.rnrj---=- DATE:_---i1L(-/--L-1 ---!-/---= 3=-----_ ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 45 of 594

46 ) " " 3 PROJECT ----_ Notebool< No Continued from Page 11 Q.Q. \1Y'4. i ll 18J tw' i _+ ' f f W "t-(ir i '\- l'elv>{) 'i t b <!t.-- \' 1(' L Continued on Page Read and Understood By / 1- _s_d'\'z:..-_'---\\)-ll-ll ' -.ff--+-"'i9-1_d_-= /--r!-/-!s---' ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 46 of 594

47 . 4A 42 Notebook No. h - -.) PROJECT - Continued From Page - )1 l) / f'.. 2 ) L/ i- '1 1' \ \7- )3 1'1 l5 Jb r--r \ -) -/ -/2.. -1fJ B 1 j() Continued on Page \ l( (l3 Read and Understood By Signed Date ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 47 of 594

$L Notebook No. ----'21_4----"3" 91 PROJECT Continued From Page -;-- s- -'oc:- 1-' 1- i- ' - 11p"- t-o'g'- -'9 1 - '' = 9'- -OL. ''=-:66 - '" t7 - - - ( -'. nl :;:: \ ; 'Z-.' 'r -t- - ' "\ }'\ t F ff.$

48 L Notebook No. ----'21_4----"3" 91 PROJECT Continued From Page -;-- s- -'oc:- 1-' 1- i- ' - 11p"- t-o'g'- -'9 1 - '' = 9'- -OL. ''=-:66 - '" t ( -'. nl :;:: \ ; 'Z-.' 'r -t- - ' "\ }'\ t F ff. H- \ J- - c..!j f'. - J.-.::> {\ C> - T '' '. - tt' r t'r' * (J - "..t. v \" L 1_ - t<" fa i-oe OC 9 - \ d =FFoi'f:l )\:.- _ O!.O Oc-.L 11' f-: ' > "!- " "- - brr. \ '''' d-- f eel1±: i fd rj ( Continued on Page " \Jv U try jl3 Read and Understood By / ;:/'3-- Signed Date Signed Date ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 48 of 594

49 Pest SOLS DATE: 11/19/213 CUST:Maku Military Reservation Oahu BATCH # B1132 ARDL # 6563 SAMPLES: BLK; PEST SP BLK; thru 12 QC SAMPLE: ms/msd SOLVENT USED: MeCL 2 # 628 Hexane # 4772 REAGENTS USED: Na 2 S 4 # Florisil # SURROGATE # PEST SPKE # CONC CONC 1 PPM _X_ AMOUNT 2uL _X_ 1 PPM _X_ AMOUNT 2 ul _X_ EXTRACTON METHOD: SONCATON _X_ DLUTON MED/LEV FNAL VOLUME 1 ml CLEAN-UP METHOD: EXTRACTON PERSONNEL: GPC_X_ Florisil SMN JAD GPC CURVE DATE: 1/28/13 SPKER: SMN WTNESS: JAD SAMPLE # WEGHT 19 ph Vf SAMPLE # WEGHT 19 BLK ml ms SP BLK 5. 9 " " msd " " " " " " ()') cj v.v"'" 13 " 1M> " /-y 1/ '/;3 DELVERED " rj " " " " " " " " " " " " " " " R ECEVED BY: if' ph " BY: SrrvJ Vf 1 ml " DATE: _-<LJf--!'1A))'.L:..1 DATE:_i--/7-_o_' f..2.-ft..::::3':.- ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 49 of 594

50 '--.' t. Noteboo! No PRO.JECT Continued from Page _--.--_-.---_ _.-_--; r--_._ r L l--_+_-b--+ i +--+-_+-+--h cl-+_ _--+-_l-+_ :1 t _ O- ')--+\ f-- +--_+c_-+_\--+- ' e. '1 -: CA (\r. -e- '.ljl.'_+_-t- + \+JJ_4 t:: "+n'--'j+-----i \\jt"'o"gll-i /1\--..:)h-\e"'--t T { V \ -J Signed Read and Understood By -/JJt!t3 Date == ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 5 of 594

51 2416 Notebook No. ' 43 PROJECT Continued From Page H J ftl 13 P D:::' -h- Q- if )Ov \ :>1.) B c-. b \.. 1F A \ c\ v. ' D V '2 l \\ '\ s.(j \ De rtl ;-1.s?8 \\A. L/ $b :3 '- \ -:-L -f-j G '.- b \ - +-"1- \\ -- l'l - f /. ).- \( 15 - ll. 1& -\ Lfl1 S /"" ' /' /...(11 r '- " "'-.. " --. < f\.j... "" '... " """ \'-... "" "" r < r_ ; /' P":!J( >V. / v""" r ". -) ""... '. "-1.. '-... """ Continued Read and Understood By. on Page D(\ ll/l/l3 Ov dl '-.-/ Signed Date Signed Date ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 51 of 594 V

$Notebook No. _2_14----"3 91 PROJECT Continued From Page 1 - 'ot- H 1--'2:= L'o '- 'o'p"- '-'9'- 1--9- '- Pos'- 'o 1 - ( -' '- l - _OL H - t:;" - - -- i -" rq ::;: \) ; 'j. ' --. -;-.. - \ Y r-' \... f:.$

52 Notebook No. _2_14----"3 91 PROJECT Continued From Page 1 - 'ot- H 1--'2:= L'o '- 'o'p"- '-'9' '- Pos'- 'o 1 - ( -' '- l - _OL H - t:;" i -" rq ::;: \) ; 'j. ' --. -;-.. - \ Y r-' \... f:. "v.; - r-!j - f-- f' '. T. " ' r ;: -.t T - ct- :9- ". ) -. r t'r" J.1: v /1 Va \ "" ;:::Og=FF D LO 1--\1-:- OC h 9... p... p-.l " C r 2" m -. - r!.. H---.'"."-' - -'-... _.. '- +.. H.jL ' ;.1 8- "J±l:d= H..:.L.. Read and Understood By J1/JUi'3 f<w 11 D U( Continued on Page /L;;-;); Signed Date Signed Date ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 52 of 594

53 Notebook No PROJECT Continued From Page Benner Circle l--l _ RESTEK a""'''''a1682' Clltlllog# f-----f-----f n-triacontane d62 Standard MdelnUSA 6 uglml aach n Methylene Chloride _+_ Lot# A97861 Exp.Date: 1/22 1 u 118ennerCh'cle ---i RESTE\. "'f". 'A '"'' Clltalog# Residual Range Calibration. Standard (RCS) 6 ug/ml each n Methylene Chloride Lot# A97417 Exp. Date: 9/22 M4ce n USA.. : D e2 \ \111"'i t') J Store: 25'C nominal J SjY\r' \\)L 1- }13 Read and Understood By Continued on page Sf!! Signed Date Date ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 53 of 594

54 olutes; ';res! nc Regstered ;; _!!!"... 3\':::;'=- Certified erence Material CRM SO N-43 Accredited Scopes: absolutestandards.com TFED WEGHT REPORT Lot # i/ {.. C /.- - j Formulated By: Vincent K. Criscio Jr. DATE Reviewed By: Pedro L Rentas DATE Acetone Solvent(s): K25E CLP Pesticide Surrogate Standard Part Number: Lot Number: Description: " 2. components Storage: 4 C Expiration Date: Nominal Concentration (pg/ml): 2. 5E-5 Bal;mce Uncertainty.58 FlaskUnccrloiniy Weight(s) shown below were combined and diluted to: 5. MSDS nformation Actual Actual Expanded (Solvent Safety lnfo. On Attacbed pg.) Lot Nominal Purity Uncertainty l Target LDSO Weight(g) Cone (ug/ml) Uncertainty CAS# OSHA PEL (TWA) RM# Number Cone (ug/rul) (%) Purity Weight(g) Compound N/A N/A N/A N/A Tetrachloro-m-xylene.. Oecachlorobiphenyl (29) TC: lbsb'j223.!!>.o-= " Method GCSMSD-7_M: Column:SPB-5 (3m X.25mm D X :25jJm film thickness) Temp 1 = 15 C (4min')r Temp 2 = 29 C (13.5 min')r Rate = 8 C/min. njector B= 2 C Detector B = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis performed by Candice Warren. ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 54 of Z 3 zaoooo MSDRT 22 (min.) 7.45 Name 2A56-Tetrachloro-m-xylene i.g 2 ROOOO 22.7 Decachlorobiphenyl lzddo TiPle-> art # 223 Lot # ::;.. 1of2 Printed: 11/3/2121:8:38 AM

55 18 Notebook No PROJECT ' Continued From Page ---- J \ '\\if \ \ l/ /{3 Continued\pn Page Read and Understood By ARDL nc Signed Report Numbers Date 6562 & Limu - Pesticides 881B? igned - Revision 1 Date Page 55 of 594

56 Notebook No PROJECT Continued From Page / - 11 ' Part #: 7918 Laboratory Use Only - See MSDS Lot #: Exp: Storage 4 'c /../...! h j.j k 4.4'-DDT dl /.' 1 uglml in hexane 1 ml ABSOLUTE STANDARDS NC J!{ f..d::; "'- Part #: 7922 Lot #: 6171 Laboratory Use Only - See MSDS 'r' :--:lr--4--clr l l EXP:61715 Storaae 4 'C 1.Pl/!L:!J A// Heptachlor. Jj: 'Pfi : /----' 1 uglml in hexane 1 ml T. B.SOLUTE STANDARDS NC. " ' Part #: 795 Laboratory Use Only - See MSDS Lot #: 3212 Exp: 3217 Storage 4 C Heptachlor epoxide (somer8) 1 ug/ml in hexane 1 ml ABSOLUTE STANDARDS NC i at 3/ /& 13) 1/ l ( ( { J /) / / l/ ) r L Continued on Page Read and Understood By ARDL nc Report Numbers 6562 & Limu - Pesticides 881B Signed Date!j- Signed Revision 1 Page Date 56 of 594 cr!j

57 56 Notebook No. _'_3_2_' _7_8_ PROJECT ': Continued From Page y Part #: 7916 Lot #: a-bhc Laboratory Use Only - See MSDS Exp: Storage 4 c - " '1 uglml in hexane 1 ml ABSOLUTE STANDARDS NC. - Part#: Lot #: beta-bhc Laboratory Use Only - See MSDS Exp: Storage 4 'c - 1 ug/ml in acetone 1 ml ABSOLUTE STANDARDS NC _ n.1 rljg:17... f) ". Part #: 7948 Laboratory Use Only - See MSDS Lot #: 6171 Exp: Storage 4 C d-bhc. '. 1 uglml in hexane 1 ml ABSOLUTE STANDARDS; NC. :j) ;= ) j'if-!'-"-' J. J / t) t> J b;!z- Part #: 7949 Laboratory Use Only - See MSDS Lot #: 3212 Exp: 3217 Storage 4 C gamma-bhc ----t---+ [Lindanel 1 uglml in hexane 1 ml ABSOLUTE STANDARDS NC Part #: 7915 Laboratory Use Only - See MSDS Lot #: Exp: Storage 4 C Aldrin 1 uglml in hexane 1 ml ABSOLUTE STANDARDS NC Continued on Page Read and Understood By dj1 / () )-;}7 l ARDL nc Report Numbers 6562 & Limu - Pesticides Signed U 881B - Revision 1 DekePage l. 57 of 594 Signed

58 SO ge '")S Registered SO _..>-43 Accredited Scopes: Certified 1. ]ence Matrial CRM solute St"-----ards nc. 368-ii3i. v.absolutestandards.corri Lot # mfed WEGHT REPORT E Hexane Solvent(s): K38E DATE a-shc \ jyk.e)_-- 11J1/..--il.. ' / Formulated By: Paul Barron Part Number: Lot Number: Description: Reviewed By: Pedro L. Rentas DATE Refrigerate (4 C) 1 Expiration Date: Recommended Storage: Nominal Concentration (pg/ml): 5E-5 Balance Uncertainty.2 Flask Uncertainty Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Conc(/lg/mL) Uncertainty CAS# OSHA PEL (TWA) LD5 Actual Weight (g) Target Weight (g). Nominal Purity Uncertainty Cone CJ./g/mL) (%) Purity Lot Number Comoound RM# 1. a-shc N/A orl-rat 177mg/kg 'Method GC7MSD-LM: Colu=: SPB-68 (3m X.25mm ill X.25}lm flm thiclaless) Temp 1 = 15 C (4min.) Temp 2 = 29 C (13.5 min.) Rate = 8 C/min. njector B= 2 C Detector B = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis performed by Nicole Davis. Scan 567 (1.329 min): 7916.D 219 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 58 of Printed: 1/17/213 2:3:7 PM

59 solute Stards nc. SO 9 '"2S Registered Certified "renee Material CRM SO ;-43 Accredited w.absolutestanaards.com Scopes: Lot # RTFED WEGHT REPORT Acetone Solvent(s): K42E9... 1""" \:#.C-../ /""&:::... :n /' -;:>./ _ b-bhc Part Number: Lot Number: Description: Formulated By: "-Bryan Njeba DATE Reviewed By: Pedro L. Rentas DATE Refrigerate (4 C) 1 Expiration Date: Recommended Storage: Nominal Concentration (pg/ml): 5E 5 Balance Uncertainty.2 RaskUncertainty Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Actual Target Nominal Purity Uncertainty Conc(llg/mL) 'Uncertainty CAS# OSHA PEL (TWA) LOSO Weight (g) Weight (g) Lot Number Cone (llg/ml) (%) Purity Compound RM# 1. b-bhc 39 ER N/A orl rat6mg/kg 'Method GC7MSD-1.M: Column: DB-35MS (3m X.25= ill X.25}lm film thickness) Temp 1 = 15 C (4min.) Temp 2 = 29 C (13.5 min.) Rate = goc/min. njector B= 2 C DetectorB = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis perfo=ed by Gina McLane Scan 55 (9.917 min): TC: bundance Abundance 1 9 9'f H H \ Cl Cl :f 1-\ H H ] \ \ 11 \1\ m 8..L ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 59 of m/z->o ' ' ' i :::;= j j Time-->O ' art# Lot # of2 Printed: 1/17/213 2:3:9 PM

60 SO 9C '"2S Registered SO _.;-43 Accredited Scopes: Certified h_.;rence Material CRM solute Stards nc absolutestanaards.com Lot # TFED WEGHT REPORT / Formulated By: Justin Dippold DATE Hexane Solvent(s): H33E d-bhc Part Number: Lot Number: Description: Expiration Date: Storage: 4 C 6171 Reviewed By: Pedro L. Rentas DATE Nominal Concentration (pg/ml): 1 SE-OS Balance Uncertainty.4 FlaskUncertainty 25. Weight(s) shown below were combined and diluted to: MSDS nformation Actual Actual Expanded (Solvent Safety nfo. On Attached pg.) Weight (g) Cone(/ig/mL) Uncertainty CAS# OSHA PEL (TWA) LCSO Purity Uncertainty Target Nominal Lot (%) Purity Weight (g) Cone (/ig/ml) Compound RM# Number N/A orl-rat 1 OOOmg/kg d-bhc 4 EROS18S-1 Method GC8MSD-7.M: Column:SPB-5 (3m X.25mm D X.25Jlm film thickness) Temp 1 = 15 C (4min.) Temp 2 = 29 C (13.5min.) Rate = 8 C/min. njector B= 2 C Detector E = 275 C Split Ratio = 1:1 Scan Rate = 2. Analysis performed by: Candice Warren. Scan 559 (1.425 min): [858']7948.D lle: [BSS')7S()6.D "'"= Abundanc ls ld4( S 1aoooo C H 15 mood Haooo C H C 13 nodod H.llDOO" H 1 soooo 8 7C ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 6 of QO 411 nrtz-> zs.oo 1 ilme Printed: 1117/213 2:3:11 PM 1of2 art # 7948 Lot # 6171

61 SO 9(' )S Registered Certified J.._ "renee Material CRM SO _ Accredited Scopes: solute St'"ards nc absolutestandards.com Lot # itfed WEGHT REPORT i/ j{ C - - j Hexane Solvent(s): K38E g-bhc (Lindane) Part Number: Lot Number: Description: Formulated By: Vincent K. Criscio Jr. DATE 3217 Refrigerate (4 C) 1 Expiration Date: Recommended Storage: Reviewed By: Pedro L. Rentas DATE Nominal Concentration ((1g/mL): 5 E-5 Balance Unccrl:linty.2 RaskUncerl:linty Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Actual Expanded (Solvent Safety nfo. On Attached pg.) Weight(g) Cone (l1g/ml) Uncertainty CAS# OSHA PEL (TWA) LOSO Lot Nominal Purity Uncertainty; Target Compound RM# Number Cone Clg/mL) (%) Purity Weight(g) 1. g-bhc (Lindane) O.5mgfm3 (skin) orl-rat76mgfkg 'Method GC7MSD-1.M: Column: SPB-68 (3mXO.25mmD X.25}lmfilm thickness) Temp 1 = 15 C (4min.) Temp 2 =29 C (13.5 min.) Rate = 8 C/min. njectorb= 2 C DetectorB = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis performed by Nicole Poisson. Scan 689 ( min): ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 61 of oj Printed: 1/17/213 2:3:19 PM art # 7949 Lot # of2

62 solute StC'.--.(ards nc. SO 9 "1S Registered Certified h. fence Material CRM SO Accredited w.absolutestanoclrds.com Scopes: Lot # RTFED WEGHT REPORT fl i t '" /'t' "-'t! /} (] t: 'V ll"tjr. f.. telt/. o. / :' "t:.. _;;..rlt.'..!":;'... '[t;j'gti_i...t:..-' \..; Hexane SolvEint(s): Formulated By: Gabriel Helland DATE Aldrin Part Number: Lot Number: Description: Refrigerate (4 C) 1 Expiration Date: Reviewed By: Pedro L Rentas DATE Recommended Storage: Nominal Concentration (pg/ml): 5E-5 Balance Uncertainty.2 RaskUncertainty Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Actual Target Nominal Purity Uncertainty Lot ConcClg/mL) Uncertainty CAS# OSHA PEL rrwa) LDSO Weight (g) Weight g) Conc (lg/ml) (%) Purity Number Compound RM# 1. Aldrin mgfm3 (skin) orl-rat3gmgfkg 'Method GC8MSD-7.M: Colum.n:SPB-S (3m X.2Smm D X.2S}tm film thickness) Temp 1 = ls C (4min.) Temp 2 = 29 C (13.5min.) Rate = 8 c/min. njector B= 2 C DetectorB = 275 C Split Ratio = 1:1 Scan Rate = 2. Analysis performed by: Candice Warren. TC: [B5B']7915. Scan 739 ( min): [BSB']7915. Abundance Abundance j 6\ l C _ Cl. / /Cl. f C. Cl ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 62 of s rwz-> 3. 5 Tim&-> )art# 7915 Lot # of 2 Printed: 1/17/213 2:3:3 PM

63 SO 9(' "1S Registered Certified h. 1enee Material CRM SO J-43 Accredited Scopes: solute St ards nc w.absolutestandards.com Lot # RTFED WEGHT REPORT Hexane Solvent(s): JJ..J;. i.) {l.: 1'l "'-...'.l!':/f ( t: k" '7 ' i.. t: v... fi. }....J:.:.F'_h' ii_j - -'" J.f t Formulated By: Gabriel Helland DATE. 1!1.ii r\ 1 dn {... t "'... l '-DDT Part Number: Lot Number: Description: Reviewed By: Pedro L. Rentas DATE Refrigerate (4 ac) 1 Expiration D9-te: Recommended Storage: Nominal Concentration (pg/ml): 5 E-5 Boancc Uncertainty.2 Flask Uncertainty Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Conc (llg/ml) Uncertainty CAS# OSHA PEL rrwa) LDSO Actual Weight(g) Lot Nominal Purity Uncertainty; Target Compound RM# Number Cone (ug/ml) (%) Purity Weight(g) 1. 44'-DDT 11 ER NfA orl-rat 87mg/kg 'Method GC7MSD-1.M: Column: DB-35MS (3m X.25mm 1 X.25J1m film thickness) Temp 1 = 15 a C (4min.) Temp 2 = 29 a C (13.5 min.) Rate = 8 a C/min. njector B= 2aC Detector B = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis performed by Gina McLane Scan 1262 (19.27 min): TC: Abundance Abundance CCl 3 -o-l-- -a a ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 63 of miz--> Time-->O Printed: 1/17/213 2:3:17 PM 1 of 2 =>art# 7918 Lot # 62413

64 Absolute StC'ards nc. SO ge )S Registered Certified J....)rence Material CRM SO _..;-43 Accredited Scopes: Lot # CERTFED WEGHT REPORT Hexane Solvent(s): H33EOS Heptachlor Part Number: Lot Number: Description: Formulated Bv: Justin Dippold DATE Expiration Date: 8torage: 4 C Reviewed By: Pedro L. Rentas DATE Nominal Concentration (Jig/mL): 1 5E-5 Balance Uncertainty.4 Bask Uncertainty 25. Weight(s) shown below were combined and diluted to: MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Actual Nominal purity Uncertainty; Target Lot Cone (pg/ml) Uncertainty CAS# OSHA PEL \TWA) LD5 Weight(g) Cone (pg/ml) (%) Purity Weight(g) Compound RM# Number 1. Heptachlor JD O.5mgim3 (skin) orl-rat 4mgikg Method GCBMSO-7.M: Column:SPB-S (3m X.2Smm 1 X.2Sl-m film thickness) Temp 1 - is C (4min.) Temp 2-29 C (i3.5min.) Rate - SOC/min. njector B- 2 C Detector B C Split Ratio = 1:1 Scan Rate = 2. Analysis performed by: Candice Warren. Scan 664 (11.7B7 min): [BSB'j7B11.D lc[bsb']7l11.d Abundance AOUrDaii::: )fc5 C C C C C'2!j C C ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 64 of = iooo 25 SOOOO COOO Tim;-' ] 25. lo.l1o m!z-) 53 Part# 7922 Lot # of2 Printed: 1/17/213 2:3:13 PM

65 AOSQlute stc'ards nc. Certified h... "renee Material CRM SO _..)-43 Accredited SO 9C ")S Registered Scopes: Lot # CERTFED WEGHT REPORT Hexane Sovent(s): K38E J- i/ j{ C - Heptachlor epoxide (isomer B) Part Number: Lot Number: Description: Formulated Bv: Vincent K. Criscio Jr. DATE Refrigerate (4 ec) 1 Expiration Date: Recommended Storage: Nominal Concentration (Jg/ml): Reviewed By: Pedro L. Rentas DATE 5E-5 Balance Uncertainly.2 FlaskUnccrtainlY Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Actual Target Lot Nominal Purity Uncertainty; Compound RM# Number Cone (pg/ml) (%) Purity Cone (llg/ml) Uncertainty CAS# OSHA PEL \l"wa) LOSO Weight(g) Weight(g) 'Method GC7MSD-7.M: Column: SPB-6S (3m X.25mm D X.25Jlm film thickness) Temp 1 = 15 C (4min.)' Temp 2 = 29 C (13.5 min.) Rate = SOC/min. njector ' 1. Heptachlor epoxide (isomer B) N/A arl-rat 47mg/kg B= 2 o e Detector B = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis performed by Lance R. Boynton. Scan 89 ( min): P D TC: P D Abundance Abundance &1 CC 16 C C 't ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 65 of C C : 15: 2: 25: 3: m/z-->o Time-->O Part# 795 Lot # of2 Printed: 1/17/213 2:3:15 PM ;

66 Standards Preparation nformation Rev. 1.1 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 66 of 594

67 Notebook No Continued From Page PROJECT RESiEk Cataiog# BeMUCrete Be'elonlePA1S623 Degradation Calibration Mixture 1-2( uglml each n MTBE Lot# A95542 Exp. Date: Store: 1'C or colder -- 7 f? lif /1! ' -- -[1' () '1 r8.) - U - \ ) Continued on Page Read and Understood By _o1}3- Da-L Signed ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 67 of 594

68 . /'.... RESTEK CERTFED.REFERENCE MATERAL 11 Benner Circle Bellefonte PA Tel (8) Fax: (814) Cei1ificate ()f Analysis wwin.restek.com FOR LABORATORY USE ONLY-READ SDS PROR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. Catalog No. : Lot No.: A95542 Description: Degradation Calibration Mixture System Evaluation Mix 1-2[1g/mL MTBE1 muampul Container Size: 2 ml Pkg Amt: > 1 ml Expiration Date: January Storage: 1 C or colder CERTFED VALUES.. Compound.' Endrin CAS # (Lot LB8879 5V) Purity 99% 2 44'-DDT CAS # (Lot ERO236-3) Purity 99% Grav. Cone. (weight/volume) 1.5 )lg/ml 2.5 )lg/ml Expanded Unertainty. (95% C.L.; 'K=2) -' -. +/ )lg/ml Gravimetric +/ )lg/ml Unstressed +/ )lg/ml Stressed +/ )lg/ml Gravimetric +/ )lg/ml Unstressed +/ )lg/ml Stressed Solvent: MTBE CAS # Purity 99% ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 68 of 594

69 32('9 64.' Notebook No. PROJECT - --." Continued From Page fq i t ) f i i i \ 'j'i " ' :' 1 / " '! j' /.' i / /... _."..._.... " l t-.. Part #: 7979 Laboratory Use Oilly - See MSDS ; 7191 Exp: Storage 'c EPA Method 833 Analyte /<..'<-<'1! /1 /7 1 /J RDX 1 uglml in acetonitrile 1 ml !. A8SLUTE STANDARDS NC... / '.\ i... / <./ /:...; 7 i. : '. 1 /' /' / / Continued on Page.;> R' aod U"'''' Signed Date Signed ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 69 of 594

$58 Notebool< No. 32 7 8 PROJECT. Continued From Page ---- V " ' 1/' f" _ '-r--" ----. -- lf / \ (. if f --'- r T / ')( ( / rrj. /o "'LA 1j.;.$

70 58 Notebool< No PROJECT. Continued From Page ---- V " ' 1/' f" _ '-r--" lf / \ (. if f --'- r T / ')( ( / rrj. /o "'LA 1j.;.itf '2 p$ /J _ v / / / / ReaMind understlod By <V/f '--!. 11fo.;--';; 13. Qv /db-'-//n 1x(J. /ulu/:] ed Date.. l \ tj.li- Date ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 7 of 594

71 Notebook No PROJECT Continued From Page Part #: 7918 Laboratory Use Only - See MSDS Lot #: Exp: Storage 4 'c / 57 44'-DDT 1 uglml in hexane 1 ml ABSOLUTE STANDARDS NC. « / Part #: 7922 Lot#: Heptachlor. Laboratory Use Only - See MSDS Exp: Storaae 4 C ' 1 uglml in hexane 1 ml._ ABSOLUTE STANDARDS ' - Part #: 795 Laboratory Use Only - See MSDS Lot #: 3212 Exp: 3217 Storage 4 c Heptachlor epoxide (SomerB) 1 ug/ml in hexane 1 ml ABSOLUTE STANDARDS NC fj / L 1 ( / {/)r ' /./ Continued on Page Read and Understood By Signed Date (J Signed Date ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 71 of 594 Cr()

72 Notebook No. v_ PROJECT Continued From Page ---- r.. _. _ - Part #: 7916 Lot #; a-bhc -. 1 ug/ml in hexane Laboratory Use Only See MSDS Exp: ABSOLUT/i STANDARDS NC. '> Storage 4 'c --+-; _t --t-- t +-_t l./j{)...-- Part #: Lot #: beta-bhc Laboratory Use Only See MSDS Exp: Storage 4 C 1 ug/ml in acetone ; 1 ml ABSOLUTE STANDARDS NC. " $f=-8-=f:-b-..-- F-i=k-. ;-;; i "... /) J -- -'" i Part #: 7948 f---'+---f Lot#: 6171 d-bhc Laboratory Use Only See MSDS Exp: Storage 4 C A.1 j i---l---i\ 1 uglml in hexane 1 ml ABSOLUTE STANDARDS / Part : 7949 Laboratory Use Only - See MSDS Lot #: 3212 Exp: 3217 Storage 4 C gamma-bhc [Lindane] ug/ml in hexane 1 ml ABSOLUTE STANDARDS NC A A Part #: 7915 Laboratory Use Only - See MSDS Lot #: Exp: Storage 4 C Aldrin \?"'" 1 uglml in hexane 1 ml ABSOLUTE STANDARDS NC AY Continued on Page Read and Understood By dii Signed 71 Signed ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 72 of 594

73 SO 9C "1S Registered psolute Ste'ards nc. -9B Cerlified t- rence Matrial CRM SO r43 Accredited ww.absolutestandards.com Scopes: Lot # ERTFED WEGHT REPORT Hexane Solvent(s): K38E41 /.:7. tz-!l...f--1 _/ 92712" j:'v{l a-shc Part Number: Lot Number: Description: Formulated By: Paul Barron DATE Refrigerate (4 C) Expiration Date: Recommended Storage: Reviewed By: Pedro L. Rentas DATE 1 Nominal Concentration (jig/ml): SE-OS Balance UncertainlY.2 Flask Uncertainty Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Conc(pg/mL) Uncertainty CAS# OSHA PEL (TWA) LDSO Actual Target Weight (g) Weight (g) Purity Uncertainty (%) Purity Nominal Cone (llg/ml) Lot Number Compound RM# 1. a-shc N/A orl-rat177mg/kg 'Method GC7MSD-l.M: Column: SPB-68 (3m X.25= D X.25Jlm:film thickness) Temp 1 = 15 C (4min.) Temp 2 = 29 C (13.5 min.) Rate = 8 C/min. njector B'= 2 C DetectorB = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis performed by Nicole Davis. TlC: 7916D Scan 567 (1.329 min): Abundance Abundance 4 16 C H H C H H 1 C 13 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 73 of 594 'OOO C H "' l OOOOOJ m/z-->o Tirne--==--o 5.bo 1: 15: 2: 25: 3: Part# 7916 Lot # f2 Printed: 1/17/213 2:3:7 PM

74 SO 9C ')S Registered Certified J... "renee Material CRM [SO Accredited Scopes: bsolute Stards nc w.absolutestanaards.com Lot # CERTFED WEGHT REPORT Acetone Solvent(s): K42E '-. Formulated By: "'Bryan Njeba DATE.i;:...;>. /" o:q " 'R /'" c::::::-.a:;/ 1# b-bhc Part Number: Lot Number: Description: Reviewed Bv: Pedro L. Rentas DATE Refrigerate (4 C) 1 Expiration Date: Recommended Storage: Nominal Concentration (pg/ml): 5E-5 Balance Uncertainty.2 FlaskUncertainty Weight(s) shown below were combined and diluted to: 25. MSDS nformation (Solvent Safety nfo. On Attached pg.) CAS# OSHA PEL (fwa) LDSO Expanded Uncertainty Actual Conc{Jg/mL) Actual Weight (g) Target Weight (g) Purity Uncertainty (%) Purity Nominal Lot Number Conc (/lg/ml) Compound RM# 1. b-bhc 39 ER N/A orl-rat 6mg/kg 'Method GC7MSD-l.M: Column: DB-35MS (3m X.25mm ill X.25}lm film thickness) Temp 1 = 15 C (4min.) Temp 2 = 29 C (13.5 min.) Rate = goc/min. njector B= 2 C Detector B = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis perfo=ed by Gina McLane Scan 55 (9.917 min): TC: Abundance Abundance ] t H H C C C 1 9 ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 74 of H H m/z-->o Time->O Part# Lot # of2 Printed: 1/17/213 2:3:9 PM

75 Absolute Stards nc. [SO 9C ")S Registered Certified Jr..-rence Material CRM SO _..)-43 Accredited ww.absolutestandards.com Scopes: Lot # CERTFED WEGHT REPORT 6171 Formulated By: Justin Dippold DATE Hexane Solvent(s): H33E d-bhc Part Number: Lot Number: Description: Expiration Date: Storage: 4 C 6171 Reviewed By: Pedro L Rentas DATE Nominal Concentration (pg/ml): 1 5E-5 Balance Uncertainty.4 Flask Uncertainty 25. Weight(s) shown below were combined and diluted to: MSDS nformation Actual Actual Expanded (Solvent Safety nfo. On Attached pg.) Weight (g) Conc(llg/mL) Uncertainty CAS# OSHA PEL (TWA) LOSO Target Uncertainty Nominal Purity Lot Weight (g) Purity Conc (llg/ml) (%) Number RM# Comoound <3 N/A orl-rat 1mglkg ER d-bhc Method GCSMSD-7.M: Column:SPB-5 (3m X.25mm D X.25Jm film thickness) Temp 1 = 15 C (4min.) Temp 2 = 29 C (13.5min.) Rate = SOC/min. njector B= 2 C Detector E = 275 C Split Ratio = 1:1 Scan Rate = 2. Analysis performed by: Candice Warren. Scan 559 (1.425 min): [BSB']794B. ls 1\t::[BSBt)79S.D t::: Abundance 1C\4': C H C H 13 lloool noooo H H [l[) ' >\ 3 \ \ m:z-> Tll '' lo.oo "-" 3. ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 75 of ljr J. ii [ ll Printed: 1/17/213 2:3:11 PM 1of2 Part# 7948 Lot # 6171.

76 .bsolute St'ards nc. SO 9C ")S Registered O Cerlified f.k --renee Material CRM SO _.r43 Accredited vww.absolutestandards.com Scopes: CERTFED WEGHT REPORT Lot # i/ j{ Solvent(s): K38E41 Hexane ( - - j Formulated By: Vincent K. Criscio Jr. DATE Part Number: 7949 Lot Numoer: 3212 Description: g-bhc (Lindane) 3212 Reviewed Bv: Pedro L. Rentas DATE 3217 Refrigerate (4 C) 1 Expiration Date: Recommended Storage: Nominal Concentration (J.g/mL): 5 E-5 Balance Uncertainty Weight(s) shown below were combined and diluted to: FlaskUnccrtainty MSDS nformation Lot Nominal Purity Uncertainty; Target Actual Actual Expanded (Solvent Safety nfo. On Attached pg.) Compound RM# Number Cone (llg/ml) (%) Purity Weight(g) Weight(g) Cone Clg/mL) Uncertainty CAS# OSHA PEL (TWA) LOSO 1. g-bhc (Lindane) O.5mgfm3 (skin) orl-rat76mgfkg 'Method GC7MSD-1.M: Column: SPB-68 (3m X.25= D X.25}'m flm thickness) Temp 1 = 15 C (4min.) Temp 2 = 29 C (13.5 min.) Rate = 8 C/min. njector B::;: 2 C Detector B = 29 C. Split Ratio = 1: 1 Scan Rate = 2. Analysis perfo=ed by Nicole Poisson. TC: Scan 689 ( min): Abundance Abundance C H ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 76 of C 35 l " C C j H H C H ] ' m/z--> 1 ' i i Time--> Printed: 1/17/213 2:3:19 PM Part# 7949 Lot # of2

77 SO 9 ")S Registered SO _A3 Accredited Scopes: Certified h fence Material CRM bsolute St&V- 4 ards nc ww.absolutestanaards.com Lot # ERTFED WEGHT REPORT Hexane Solvent(s): fl Jf /1...l:{ r) f {f.."7 l "'p ':; J '. -l 't'""1 li "1. f '.' j/ '"(..'4--J?:':"'" l-l..&=."'l--... tt:tft... ;i.z Formulated By: Gabriel Helland DATE Aldrin Part Number: Lot Number: Description: Reviewed By: Pedro L. Rentas DATE Refrigerate (4 C) 1 Expiration Date: Recommended Storage: Nominal Concentration (pg/ml): SE-OS Balance Uncertainty.2 Flask Uncertainly Weight(s) shown below were combined and diluted to: 25. MSDS nformation (Solvent Safety nfo. On Attached pg.) Expanded Actual Actual Target Purity Uncertainty Nominal Lot CAS# OSHA PEL (TWA) LOSO Uncertainty Conc(pg/mL) Weight (g) Weight (g) (%) Purity Conc (pg/ml) Number Compound RM# 1. Aldrin O.2Smg/m3 (skin) orl-rat 39mg/kg 'Method GCSMSD-7.M: Colurnn:SPB-S (3m X.25mm D X O.25Jlm film thiclmess) Temp 1 = 15 C (4min..) Temp 2 = 29 C C13.5min.) Rate = 8 C/min. njector B= 2 C Detector B = 27SoC Split Ratio = 1:1 Scan Rate = 2. Analysis performed by: Candice Warren. TC: [B5B']7915.D Scan 739 ( min): [858']7915.D Abundance Abundance 6\6 j CC ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 77 of 594 / C j?/ C Cl BOOO S1 nul-> SO Tim5-> Part# 7915 Lot # of2 Printed: 1/17/213 :3:3 PM

78 SO c -::ls Registered "SO >-43 Accredited Certified h renee Material CRM bsolute St"---ards nc Scopes: ww.absolutestanaards.com Lot # ERTFED WEGHT REPORT '""J1;<j! fj Hexane Solvent(s): Y " j'""'1 t ] 't't.[x..a':7."7:t"'\..j.:.... l' {lr:--..fj'" Formulated By: Gabriel Helland DATE {{ -'; J* '/:." tl ; '-DDT Part Number: Lot Number: Description: Reviewed By: Pedro L. Rentas DATE Refrigerate (4 C) 1 Expiration Date: Recommended Storage: Nominal Concentration (f1g/ml): 5E-5 Balance Unccrlainty.2 Flask Uncerlainty Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Cone (pg/ml) Uncertainty CAS# OSHA PEL <:rwa) LDSO Actual Lot Nominal Purity Uncertainty; Target Weight(g) Compound RM# Number Cone (pg/ml) (%) Purity Weight(g) 1.44'-DDT 11 ER N/A orl-rat87mg/kg 'Method GC7MSD-1.M: Column: DB-35MS (3m X.25mm 1 X.25fJm film thickness) Temp 1 = 15 C (4min.) Temp 2 = 29 C (13.5 min:). Rate = BOC/min. njector B= 2 C Detector B = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis performed by Gina McLane ' Scan 1262 (19.27 min): TC: Abundance Abundance J31 CCls a-{)-l- -a ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 78 of m/z _> J \1111 t)a Alii' Jill ' \ ' ' ' ' ' J ' 1 ' pO : 3: 5. 1: 15:Q 2: Time-->o 1of2 Printed: 1/17/213 2:3:17 PM Part# 7918 Lot # 62413

79 SO 9C "2S Registered SO _..;-43 Accredited Scopes: l'ifid J.. mnctj Mafelial CRM bsolute Stards nc ww.absolutestandards.com Lot # CERTFED WEGHT REPORT Formulated Bv: Justin Dippold DATE Hexane Solvent(s): H33E Heptachlor Part Number: Lot Number: Description: Expiration Date: Storage: 4 C 6171 Reviewed By: Pedro L. Rentas DATE Nominal Concentration (pg/ml): 1 5E-5 Balance Uncertainty Weight(s) shown below were combined and diluted to: FlaskUncertainty MSDS nformation Lot Nominal Purity Uncertainty; Target Actual Actual Expanded (Solvent Safety nfo. On Attached pg.) Compound RM# Number Cone C/lg/mL) (%) Purit)' Weight(g) Weight(g) Cone (pg/ml) Uncertainty CAS# OSHA PEL rrwa) LOSO 1. Heptachlor JD O.Smg/m3 (skin) orl-rat4mg/kg Method GCBMSD-7.M: Column:SPB-5 (3m X.25mm D X.25!1m film thickness) Temp 1-15 C (4min.) Temp 2-29 C (13.5min.) Rate - 8 C/min. njector B- 2 C Detector B- 275 C Split Ratio = 1:1 Scan Rate = 2. Analysis performed by: Candice Warren. Scan 664 ( min]: [BSB']7922.D 1[BSB']7S22.D Ab"dance Atiundanc= :: >:1 11 C C C)fC51 'h- C C f ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 79 of >:1 9 4 BOOOO 3>:1 7 3 BOOOO 25 >: >: Tim;.-;. 1 1>: >:1 4 4>: ] 3. m!z-> :: >:1 Part# 7922 Lot # of2 Printed: 1/17/213 2:3:13 PM

80 Absolute Stards nc. SO ge )S Registered Certified J....renee Material CRM SO _..>-43 Accredited Scopes: Lot # [/ j( c. - - J Formulated By: Vincent K. Criscio. Jr. DATE Hexane Solvent(s): K38E Heptachlor epoxide (isomer B) CERTFED WEGHT REPORT Part Number: Lot Number: Description: 3212 Reviewed By: Pedro L. Rentas DATE 3217 Refrigerate (4 C) 1 Expiration Date: Recommended Storage: Nominal Concentration (ug/ml): 5E-5 Balance Uncertainty.2 Flask UncertainlY Weight(s) shown below were combined and diluted to: 25. MSDS nformation Actual Expanded (Solvent Safety nfo. On Attached pg.) Cone (llg/ml) Uncertainty CAS# OSHA PEL r:rwa) LOSO Actual Weight(g) Lot Nominal Purity Uncertainty; Target Compound RM# Number Cone (ug/ml) (%) Purity Weight(g) 1. Heptachlor epoxide (isomer B) N/A orl-rat 47mg/kg 'Method GC7MSD-7M; Column: SPB-68 (3m X.25mmD XO.25}lmfilm thickness) Temp 1 = 15 C (4min.) Temp 2 = 29 C (135 min.) Rate = 8 C/min. njector' B=2 C Detector B = 29 C. Split Ratio = 1:1 Scan Rate = 2. Analysis performed by Lance R. Boynton. Scan 89 ( min): P7'93-2.D Abundance TC: P D 353 Abundance CC C C 16.3 C''Lz: a 14.2 C C ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 8 of '" " 'J " Tme--> 'i ' ).n "n'nn " nn nn nn m/z-->o Part# 795 Lot # of2 Printed: 1/17/213 2:3:15 PM

$3279 42 Notebook No. ----." Continued From Page PROJECT ------------- ) U{-b'OOf ra -Z:;DtN ti_tfzl q- - 112-/ f()tj (-L lk...lj' r- d/t "?/7V - / J /! ' ( <' J >-7 tt=lta.vttt/(-1-r-il-t-t-it.$

81 Notebook No " Continued From Page PROJECT ) U{-b'OOf ra -Z:;DtN ti_tfzl q / f()tj (-L lk...lj' r- d/t "?/7V - / J /! ' ( <' J >-7 tt=lta.vttt/(-1-r-il-t-t-it.at-1dgtv-t-t-t-t')v-=t1!"- <;;n!c;::::. cdo p.f f-i!co'rfl'!j\. '. t7 oj1a ( cf '' L Part #: 223 Laboratory Use Only - See MSDS Lot #: 2212 Exp: 2217 Storage 4 C irf 1-' CLP - Pesticide Surrogate Spike Solution /J 2 components! '. 2 ug/ml in acetone 1 ml ABSOLUTE STANDARDS NC ". r ' 1 - ) yll Y j Continued on pae 7 (Read and Understood By Signed ;J Signed Date ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 81 of 594

82 solute S; 3Jds nc. SO 9 1S Registered ''(:....:;(.3:;- Scopes: Certified h... A:rence Material CRM SO "..)-43 Accredited absoutestandards.com Lot # TFED WEGHT REPORT i/!(.. c /..- - J Formulated By: Vincent K. Criscio Jr. DATE Reviewed By: Pedro L Rentas DATE Acetone Solvent(s): K25E Part Number: lot Number: Description: elp Pesticide Surrogate Standard 2 components 2217 Storage: 4 C Expiration Date: Nominal Concentration (ug/ml): 2 SE-OS BaJ;mce Uncertainly.58 FlaskUnccrbiniy Weight(s) shown below were combined and diluted to: 5. MSDS nformation Actual Actual Expanded (Solvent Safety nfo. On Attached pg.) Lot Nominal Purity Uncertainty; Target Weight(g) Cone (pg/ml) Uncertainty CAS# OSHA PEL [rwa) loso Compound RM# Number Cone (Pg/roL) (%) Purity Weight(g) NfA NfA NfA NfA Tetrachloro-m-xylene 2. Decachlorobiphenyl (29) 1l 1656']223 ;!l."llm zan 4 3BOOOO 36 Method GC8MSD-7.M: Column:SPB-5 (3m X.25mm D X.25-1m film thickness) Temp 1 = 15 C (4min')r Temp 2 = 29 C (13.5 min')r Rate = SOC!min'r njector B= 2 Cr Detector B = 29 C. Split Ratio = 1:l r Scan Rate = 2. Analysis performed by Candice Warren. ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 82 of MSDRT (min.) 22 Name r4r5 6-Tetrachloro-m-xylene lboooo 22.7 Decachlorobiphenyl BOOOO Bple-> :lart# 223 Lot # ;=- 1f2 Printed: 11/3/212 1:8:38 AM

Notebool< No. 3279 41 PROJECT Continued From Page ---- 1/.' t 1c q J t /t f;. f l / t - / / V / V / 7 1/ - -- ' / ::';S23 M'"klUSA -+-/)c.tflhy-.wtf} ll1f /11'li )/" [1:7 --!-- Catalog# 31464 " f/.

83 Notebool< No PROJECT Continued From Page /.' t 1c q J t /t f;. f l / t - / / V / V / 7 1/ - -- ' / ::';S23 M'"klUSA -+-/)c.tflhy-.wtf} ll1f /11'li )/" [1:7 --!-- Catalog# " f/..l )k _-l-j-_h_w l + f-f-- RESTEK ' --l-----" Motor Oil Composite Standard 1 saooc c;/ b ef is / 'AU h. tu X1fo -/l'otlb 11 b) 6ug/mLeach n Metl1ylene Chloride 6 tlq 11f( [. f 11M /.. Pf']A. 1'1/'7 --- Lol# A94493 Exp Date: OS/22 Store: 25'C nominal? 11'1-of; /;r.--j V f Read and Understood By Continued on Page j-3 ate s'f 2 ARDL nc Signed Report Numbers 6562 & Limu - Pesticides 881B - Revision 1 Page 83 of 594

84 4 Notebook No. 32 :7 9 PROJECT. Continued From Page ---- C)L t..x 17 _- -v ( :; Of) 1 /. 1'/<' )..L / dro v 1 A - / r / A. -r---::::.. r- {}f)'k- Read and Understood By ARDL nc Signed Report Numbers Date 6562 & Limu - Pesticides (/ 881B Signed - Revision 1 Page 84 of 594

$Notebook No. 3279 23 PROJECT. :2--" Continued From Page ---- A r { j _+_LJOO+!./k@+'t+/(4JK/R:v/b'VL+)dOk / l- (. 'tla rjtl1/u)/ t/5/l--'1tf $.h K.J lei 2.) a;f2-f'\.$

85 Notebook No PROJECT. :2--" Continued From Page ---- A r { j _+_LJOO+!./k@+'t+/(4JK/R:v/b'VL+)dOk / l- (. 'tla rjtl1/u)/ t/5/l--'1tf $.h K.J lei 2.) a;f2-f'\.=----t / tj 7- f CJ rt/ (l / '-'/J / hip'-/ (); J 1'.4-. al<t-//-'t-::o /_f_-::s f t i --l=:::::t::j--t-+-h-:i-t----t-t'-j---t-t::-t-a- jl J L; r -;41J h;j AlJjJl)J-+"i----+::---j - t 1L4J11 Y t!/ CJnLjJ/):! /J (-r 1'F-");' ";;.-}j/'a.r A _-- --«._... - '''r---r-- --._. 1 --'" ofh-j_1 Read and Understood By Signed Date P ARDL nc Report Numbers 6562 & Limu - Pesticides 881B - Signed Revision 1 Page 85 of 594

CERTIFICATE OF ANALYSIS

CERTIFICATE OF ANALYSIS ATTENTION 1000 Lewes Blvd. Whitehorse, YT Y1A 6N2 Miles Hume PO NUMBER RECEIVED / TEMP 2018-08-23 12:50 / 16 C INFO Contract No. C00044694 (Vanier) COC NUMBER B65313/14/37/38/40