Cell3Ditor Cost-effective and flexible 3D printed SOFC stacks for commercial applications
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1 Cell3Ditor Cost-effective and flexible 3D printed SOFC stacks for commercial applications Prof. Albert Tarancón Catalonia Institute for Energy Research, IREC Programme Review Days 2018 Brussels, November 2018
2 PROJECT OVERVIEW Call year: 2015 Call topic: FCH : Development of cost effective manufacturing technologies for key components or fuel cell systems Project dates: 01/07/ /12/2019 % stage of implementation 01/11/2018: 70% Total project budget: 2,191, FCH JU max. contribution: 2,180, Other financial contribution: 0 Partners: DANMARKS TEKNISKE UNIVERSITET (DTU), FRANCISCO ALBERO S.A. (FAE), 3DCERAM (3DCERAM), Promethean Particles Ltd. (PROM), University of La Laguna (ULL), SAAN Energi A.B. (SAAN), HyGear Fuel Cell Systems B.V. (HFCS) and FUNDACIO INSTITUT DE RECERCA DE L'ENERGIA DE CATALUNYA (IREC) 2
3 PROJECT SUMMARY Objective Development of 3D printing technology for the industrial production of SOFC parts (inkjet) and stacks (SLA+Robocasting). Intermediate goals Printable inks and slurries Multi-material ceramic 3D printer Single-step sintering Global positioning vs SoA Cell3Ditor Multi-material ceramic 3D printer Printable inks and slurries of advanced ceramics 3D printed SOFCs State-of-the-art N/A N/A N/A Application and market area Commercial segment of the stationary fuel cells market Huge potential Highly heterogeneous Selected target market: Europe 3
4 PROJECT PROGRESS Printable inks & slurries of functional ceramics Achievement to-date Functional ceramic powders or precursors 25% 50% 75% Printable inks & slurries Slurries preparation for SLA process and robocasting Formulation (YSZ, NiO-YSZ, LSM, LCTM & sacrificial) Rheological analysis Printability and Photo-curing properties Inks preparation for inkjet printing In-situ synthesis (YSZ, LSM, NiO-YSZ) Rheological analysis NiO-YSZ LSM-YSZ Sacrificial Photocured YSZ parts Printability NiO-YSZ (AFL)/YSZ LSM LSM
5 PROJECT PROGRESS Multi-material ceramic 3D printer Achievement to-date Single material 3D printer Multi-material 3D printer 25% 3D printer with multi-material capabilities SLA printer (YSZ) upgraded with robocasting (+4 materials) Multi-material Software upgrade 50% 75% 100% 5
6 PROJECT PROGRESS Multi-material 3D printing process Achievement to-date Single material printing Multi-material printing 25% 50% 75% 100% Multi-material 3D printing Nano-YSZ/NiO-YSZ SOFC parts by inkjet (functional layers on commercial substrates) SOFC SRU and stacks by SLA+Robocasting NiO-YSZ (AFL)/YSZ Sacrificial/YSZ NiO-YSZ/YSZ LSM-YSZ/YSZ
7 PROJECT PROGRESS Single-step sintering Achievement to-date Single layer sintering Co-sintering whole stack 25% 50% 75% 100% Single-step sintering of the whole SOFC stack T sint YSZ (SLA)~1250ºC ANODE NiO-YSZ (Rob) 50 um YSZ (SLA) CATHODE SINTERED YSZ (SLA) LSM YSZ IONIC CONDUCTIVITY SLA YSZ LSM-YSZ (Rob) YSZ (SLA) 7
8 Risks and Challenges Printable inks & Multi-material 3D Single-step 3D printing of slurries printing process sintering SOFCs Risk UV-absorbing materials Mitigation Photo-thermal curing Risk Multi-layer architectures Mitigation Laser machining Challenges Cosintering Compatibility of dense and porous structures Minimize tensile-stress Risk Low yield of inkjet Small fluidics (cleaning) Mitigation Robocasting Sacrificial material 8
9 Followers Followers Reads Communications Activities Website (2500+ visits) Communication General Society (3 actions) Twitter (430+ followers) (100+ tweets) Evolution (Months) YouTube (2 videos) ResearchGate (850+ reads) Evolution (Months)
10 Dissemination Activities 22 Conferences Plenary/Keynote: 2 Invited: 4 Oral: 9 Posters: 7 Dissemination 8 Publications Scientific: 7 Industrial: Fairs & Workshops Highlights 10
11 EXPLOITATION PLAN Exploitation Protection of the IPR: development of a Plan of Use and Dissemination of Foreground (PUDF), application for patents and adoption of a protecting before disseminating policy. Exploitation of outputs: generation of specific business plans for exploitable outputs (assessed by SSERR and Innovation Radar). 3D printing of functional ceramics 5kW SOFC system SOFC market share, by region in D Printing Sector Map. Source: Venture Scanner SWOT analysis of 3D printing industry of ceramics Addressable Market for fuel cells in non-residential buildings 2030 SWOT analysis of SOFC technology industry for stationary applications Creation of an Industry Advisory Board: to help on deployment and scalability issues. 11
12 EXPECTED IMPACT Impact Industry: 3 Patent applications. Code Concept B18678 EP/US/JP/KR/RU/CN/FR/UA HYBRID PRINTING PROCESS B20377 EP/US/JP/KR/RU/CN/FR/UA SACRIFICIAL MATERIAL APPROACH B20887 EP/US/JP/KR/RU/CN/FR/UA MULTIMATERIAL PRINTING Outputs generated within the project already in the partners portfolio: Ceramic nano-dispersions: Promethean Particles Ltd. Extension of ceramic pastes in catalogue: 3DCERAM Multi-material 3D printer: 3DCERAM Environmental: LCA assessment: o Reduction of waste material o Reduction of energy consumption Social: Growing awareness about 3D printing for energy Influence policy makers Cerame-Unie Conference Brussels, November 2017 Cell3Ditor activities at the National Science Days Article devoted to Cell3Ditor exposed at the Bilbao Fair
13 Cell3Ditor Cost-effective and flexible 3D printed SOFC stacks for commercial applications Prof. Albert Tarancón Catalonia Institute for Energy Research, IREC Programme Review Days 2018 Brussels, November 2018
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