Photo-Documentation of Ultraviolet Radiation Induced Visible Fluorescence on Daguerreotypes

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1 Photo-Documentation of Ultraviolet Radiation Induced Visible Fluorescence on Daguerreotypes Jiuan Jiuan Chen Paul Messier LLC Conservation of Photographs And Works on Paper

2 What will be covered 1. A brief introduction of how ultraviolet radiation induced visible fluorescence works 2. What we can see on daguerreotypes a. Plate b. Accessories: case, preserver, brass mat, cover glass, etc 3. How to record the fluorescence a. The basics: lamps, filters, setup, UV reference cards b. Action!

3 Part I: ultraviolet radiation induced visible fluorescence Electromagnetic Spectrum

4 1. UVA: 315 (320)-400 nm, longwave, black light, near-ultraviolet. 2. UVB: (320), middlewave 3. UVC: , shortwave, far-ultraviolet

5 some materials glow under UV visible fluorescence

6

7 Use visible fluorescence to Detect materials not visible to the naked eye Identify materials Evaluate treatment Document/Monitor condition of objects

8 UVA (longwave) v.s. UVC (shortwave) 1.DO NOT use UVB 2.Most materials that fluoresce are excited by UVA; UVA is used most often in conservation 3.UVA is less damaging for both human & objects; avoid UVC if at all possible. 4.In some cases, UVC can give information that cannot be obtained with UVA 8

9 Image credit: Claire Tragni Image credit: Claire Tragni

10 Part II: What we can see on daguerreotypes with UV Main components in a daguerreotype Case Brass mat/preserver Cover glass Tape/adhesive Plate

11 Wooden cases with coverings Normal illumination visible fluorescence, UVA

12 Normal illumination More Cases visible fluorescence, UVA

13 Matching lid & tray Normal illumination Visible fluorescence, UVA

14 Brass Mat & Preserver Normal illumination Visible fluorescence, UVC front back

15 Image credit: Claire Tragni Cover Glass Normal illumination Visible fluorescence, UVC Image credit: Claire Tragni

16 Tape & Adhesive Image credit: Claire Tragni Image credit: Claire Tragni Image credit: Claire Tragni Image credit: Claire Tragni Visible fluorescence, UVA Before tape removed Tape/adhesive removed After treatment

17 Plate Normal illumination Visible fluorescence, UVC

18 Plate Normal illumination Visible fluorescence, UVC

19 visible light UVC Image credit: Claire Tragni & Taina Miller

20 Visible light UVC Image credit: Claire Tragni

21 visible light UVC Image credit: Claire Tragni

22 Visible light UVC Image credit: Claire Tragni

23

24 All Images by Claire Tragni Edge tarnish Tarnish in the form of a ring Dipped in sodium cyanide Modern daguerreotype

25 Greenish fluorescence on daguerreotypes under UVC 1. Copper cyanide compound 2. Possibly from a. Plate making process b. Image making process c. Previous treatment--cleaning tarnish with cyanide solution

26 Part III: How to record the fluorescence UV sources Different UV lamps Filters Setup workflow

27 Lamps 3. Internal filtered UV lamps 4. External filtered UV lamps 1. High pressure UV lamps 2. LED UV lamps

28 UVA, Longwave Ultraviolet Radiation High Pressure Mercury Lamps

29 UVA, Longwave Ultraviolet Radiation Low Pressure Mercury Lamps

30 Low Pressure Mercury UVC Bulbs Quartz envelope

31

32 Filtration for UV-induced visible fluorescence photography Block UV & IR produced from lamps and record only visible fluorescence emitted by the object Near IR emission from UV lamps, 725nm to 800 nm with peak at 735nm Cut wavelengths shorter than 400 nm and greater than 700 nm Filters to use: Kodak 2E 32

33 B+W 486 PECA 916 PECA 700 2E

34 Protect Yourself 1. Avoid direct exposure to UVC 2. Protect eyes 3. Cover exposed skin 4. Be aware of ozone a. Ozone will be generated when UVC is turned on b. Ozone sensitive objects should not be exposed to UVC c. Can cause respiratory problems

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