Coloring Pigments and Dyes for. Plastics & Masterbatch

Transcription

1 Coloring Pigments and Dyes for Plastics & Masterbatch

2 Resun Colour is a professional colorants supplier of Organic Pigments, Inorganic Pigments, Solvent Dyes, Fluorescent Pigments, Pearlescent Pigments and other additive concentrates specially applied in Plastics Industries in Masterbatch & Compounding, Polymer Processing, PVC Processing, Fiber Production, Resin Manufacturing and etc. Established in 1998 and backed by 3 full-service manufacturing facilities located in Shandong, Jiangsu and Zhejiang Province, as well as the close co-operations with major chemicals manufacturers and state-owned enterprises in China, Resun Colour has become one of the most active coloring materials suppliers with high-value products in a broad spectrum of shades ranging from red to violet for industrial colouring purposes. Resun Colour serves a broad base of customers in Plastic Industries and endeavors to provide our customers with the best combination of Value and Quality. Resun Colour has built up customers' confidence for years by continuous strict Quality Control System (QCS). We test every lot of products before shipment to measure up the standard. We file the lab test report of every lot for at least 6 months for quality track. We are equipped with advanced R&D facilities and lab instruments to cope with the cutting-edge technologies and test methods used in the industry. We do not allow goods lower than standard or with "marginal" quality to be shipped to customers. We optimize the quality to meet or exceed customer s requirements. All production facilities are ISO9001:2000 approved. Resun Colour s knowledge and experiences in plastic-purposed colorants help our customers find the best solution to meet the technical, production and marketing challenges. Resun Colour is expert in supplying high quality coloring materials with wide spectrum range and high performance applied in most polymers such as PE, PP, PS, HIPS, PET, PVC, UPVC, ABS, PC, SAN and to serve our customer s needs in plastic industries including: Packaging Home appliances Housewares Carpet & Textiles Construction Electronics Furniture Wire & Cable Resun Colour is sticking at understanding the requirements of different markets, and providing our customers with high quality products at competitive prices, professional services and technical advices. Customer s Satisfaction Our No.1 Value Quality Control We give no compromise in Quality Competitive Prices We pursue Long-term business with mutual benefits Resun Colour's commitment to quality and service is absolute! Resun Colour is committed to serve customers' needs by supplying high quality products made to measure up their specific requirements. Resun Colour is sticking at understanding the requirements of different markets and providing our customers with high quality products, competitive prices, professional services and technical advices. Resun Colour strives to be a professional chemical supplier in the plastic industry and endeavors to become customers valuable solution to coloring demand.

3 Organic Pigments for Plastics and Masterbatch Resun Colour supplies high quality organic pigments specially selected for plastics applications in a broad spectrum of shade. These pigments present wide range of technical properties and offer customers both economical and high-performance coloring solutions with excellent heat resistance, high light fastness, good bleeding fastness, easy dispersion in most types of plastics including polyolefins, PVC, rubber, styrenics, engineering polymers, etc. Product Name Ref. Shade in Resistance & Polymer Suitability (C.I. No.) LDPE Compound Fastness Full / 1:10 TiO2 Heat Light Migra-ti Masterbatch PVC PU EVA Rubber ( C) on PE PP PS ABS 1201 Benzidine Yellow G (Pigment Yellow 12) Benzidine Yellow 2GS (Pigment Yellow 14) Benzidine Yellow GG (Pigment Yellow 17) Permanent Yellow P (Pigment Yellow 62) Benzidine Yellow 10G (Pigment Yellow 81) Permanent Yellow HRT (Pigment Yellow 83) Isoindoline Yellow P (Pigment Yellow 139) Fast Yellow H4G (Pigment Yellow 151) Permanent Yellow HG (Pigment Yellow 180) Permanent Yellow TR (Pigment Yellow 183) Permanent Yellow HGR (Pigment Yellow 191)

4 Product Name Ref. Shade in Resistance & Polymer Suitability (C.I. No.) LDPE Compound Fastness Full / 1:10 TiO2 Heat Light Migra- Masterbatch PVC PU EVA Rubber ( C) tion PE PP PS ABS 2207 Permanent Orange G (Pigment Orange 13) Permanent Orange HR (Pigment Orange 36) Fast Red BBC (Pigment Red 48:2) Fast Red 2BP (Pigment Red 48:2) Fast Red 2BSP (Pigment Red 48:3) Lake Red C (Pigment Red 53:1) Lake Red CN (Pigment Red 53:1) Lithol Rubine 4BP (Pigment Red 57:1) Carmine 6B (Pigment Red 57:1) Quindo Magenta (Pigment Red 122) Permanent Red F5RK (Pigment Red 170) Permanent Red F3RK (Pigment Red 170) Permanent Pink BH3C (Pigment Red 176) Fast Red DPP (Pigment Red 254)

5 Product Name Ref. Shade in Resistance & Polymer Suitability (C.I. No.) LDPE Compound Fastness Full / 1:10 TiO2 Heat Light Migra- Masterbatch PVC PU EVA Rubber ( C) tion PE PP PS ABS 4421 Phthalocyanine Blue B (Pigment Blue 15:0) Phthalocyanine Blue BSP (Pigment Blue 15:1) Phthalocyanine Blue BGSP (Pigment Blue 15:3) Phthalocyanine Green GP (Pigment Green 7) Phthalocyanine Green GF (Pigment Green 7) Permanent Violet RL (Pigment Violet 23) Permanent Violet BL (Pigment Violet 23) Legend: = Good, = Partly Applicable, - = Not Suggeted Remarks: Light Fastness is assessed on a 1-8 scale from "Poor" to "Excellent" by using the 8 step blue scale to DIN Other Fastness Properties are assessed on a 1-5 scale from "Considerable affected" to "Not affected". Declaration: The printed colours on this brochure may not be exactly same as the true pigment colours. The information contained herein is to the best of our knowledge true and accurate, Resun Colour assumes no legal responsibility for use or reliance upon the above information since the conditions of use are beyond our control. Resun Colour strongly recommends a careful testing and screening before using the products in production.

6 Solvent Dyes for Plastics Application Resun Colour s PLASTR Series Solvent Dyes are widely applied to the dyeing of various plastics and petroleum products such as PS, AS, ABS, HIPS, PMMA, PET, PBT, PC, UPVC, RP, VC, PA, PP, PE etc., as well as decoration materials, paints, printing inks, plastic colorant etc. It can also be applied to the dyeing of thickeners for polyester fiber, acrylic fiber, polyvinyl chloride fiber etc. Solvent dyes are with good solubility and miscibility in organic solvents, and can be used in single shade or mixed in proportion. Solvent dyes are dissolved in plastic in molecular-distribution. The shade can be adjusted in demand, Transparent color can be obtained in clear resin, while the un-transparent color with titanium pigment. Product Name C.I. No. Heat Light Migration Reference The Equivalents Resistance Fastness Resistance Shade 550 Oil Yellow R Solvent Yellow C (BASF) Waxoline Orange EP 560 Transparent Yellow 4R Solvent Yellow C (BASF) Sudan Yellow Transparent Yellow GR Solvent Yellow C (ROSA) Rosaplast Yellow G 533 Transparent Yellow PS Solvent Yellow C (KEY) Keyplast Yellow YC 570 Transparent Yellow 3GS Solvent Yellow C (BASF) Sudan Yellow Transparent Yellow 3GL Solvent Yellow C N/A 580 Transparent Yellow 3G Solvent Yellow C (BASF) Themoplast Yellow Fluorescent Yellow 3G Solvent Yellow C (DyStar) Hostasol Yellow 3G 520 Transparent Yellow 3GP Solvent Yellow C (BASF) Waxoline Yellow 3GP FW 526 Fluorescent Yellow 10G Solvent Yellow C (DyStar) Macrolex Fl. Yellow 10GN 530 Transparent Yellow GHS Solvent Yellow C (BASF) Waxoline Yellow 5RP FW 540 Transparent Yellow 3GL Solvent Yellow C (DyStar) Solvaperm Yellow G 760 Transparent Orange 3G Solvent Orange C (BASF) Waxoline Orange 3GP FW 763 Fluorescent Red GG Solvent Orange C (HOE) Hostasol Red GG 786 Transparent Orange G Solvent Orange C (BASF) Sudan S Orange Transparent Red H2R Solvent Red C (BASF) Waxoline Yellow 5RP FW 430 Transparent Red 2B Solvent Red C (BASF) Waxoline Red O 425 Transparent Red B Solvent Red C N/A 450 Transparent Red H5B Solvent Red C (BASF) Waxoline Rubine TR FW 480 Transparent Red GS Solvent Red C (BASF) Waxoline Red M FW 435 Transparent Red EG Solvent Red C (BASF) Waxoline Red YP FW 446 Transparent Red FB Solvent Red C (BAY) Macrolex Red GS 449 Transparent Red HFG Solvent Red C (KEY)Keyplast Fluorescent Red G 479 Transparent Red A2G Solvent Red C (DyStar) Macrolex Red E2G 454 Transparent Red BB Solvent Red C (BASF) Thermoplast Red Transparent Red BK Solvent Red C N/A 497 Fluorescent Red GK Solvent Red C (KEY) Keyplast Fluo.Red FB 491 Transparent Red 6B Solvent Red C N/A 210 Transparent Blue 2G Solvent Blue C 5 4 (BASF) Waxoline Blue RP FW 220 Transparent Blue 2B Solvent Blue C (BASF) Waxoline Blue AP FW 260 Transparent Blue GN Solvent Blue C (ICI) Filester Blue GN

7 Product Name C.I. No. Heat Light Migration Reference The Equivalents Resistance Fastness Resistance Shade 250 Transparent Blue GR Solvent Blue C 5 4 (HDC) Elbaplast Blue G 297 Transparent Blue RR Solvent Blue C (DyStar) Macrolex Blue RR 260 Transparent Blue B Solvent Blue C (KEY) Keyplast Blue KK 270 Transparent Blue R Solvent Blue C (DyStar) Polysynthren Blue R 110 Transparent Green 5B Solvent Green C (BASF) Waxoline Green G FW/G 120 Transparent Green 8G Solvent Green C (BASF) Fluouol Green Gold Transparent Green G Solvent Green C (BASF) Waxoline Green 6G FW 613 Transparent Violet B Solvent Violet C (BASF) Thermoplast Blue Transparent Violet HBL Solvent Violet C N/A 631 Transparent Violet RL Solvent Violet C (DyStar) Resolin Violet RL 636 Transparent Violet 3R Solvent Violet C (DyStar) Macrolex Violet 3R 637 Transparent Violet FBL Solvent Violet C 7 4 (CLH) Sandoplast Violet FBL 659 Transparent Violet R Solvent Violet C (DyStar) Solvaperm Red Violet R Remarks: Light Fastness is assessed on a 1-8 scale from "Poor" to "Excellent", Migration Resistance is assessed on a 1-5 scale from "Considerable affected" to "Not affected" PLASTR Series Solvent Dyes Application Chart Product/Index PS AS ABS PMMA PET PBT PC PA Solvent Yellow 33 Excellent Excellent Excellent Good Excellent Good Excellent Excellent Solvent Yellow 64 Excellent Excellent Excellent Excellent Excellent Good Good Good Solvent Yellow 93 Excellent Excellent Excellent Excellent Excellent Good Good Good Solvent Yellow 98 Excellent Excellent Excellent Excellent Excellent Good Good Good Solvent Yellow 114 Excellent Excellent Excellent Excellent Excellent Excellent Excellent Good Solvent Orange 60 Excellent Excellent Excellent Excellent Excellent Excellent Excellent Good Solvent Orange 63 Excellent Excellent Excellent Excellent Good Poor Good Good Solvent Red 23 Excellent Excellent Poor Excellent Poor Poor Solvent Red 25 Excellent Excellent Poor Excellent Poor Good Poor Good Solvent Red 52 Excellent Excellent Excellent Excellent Excellent Excellent Excellent Good Solvent Red 111 Excellent Good Good Good Good Good Good Good Solvent Red 135 Excellent Excellent Excellent Excellent Excellent Excellent Excellent Excellent Solvent Red 146 Excellent Excellent Excellent Excellent Poor Good Good Poor Solvent Red 149 Excellent Excellent Excellent Excellent Excellent Excellent Excellent Good Solvent Red 179 Excellent Excellent Excellent Excellent Excellent Excellent Excellent Good Solvent Red 196 Excellent Excellent Excellent Excellent Excellent Good Good Good Solvent Red 197 Excellent Excellent Excellent Excellent Excellent Good Good Good

8 Product/Index PS AS ABS PMMA PET PBT PC PA Solvent Blue 35 Excellent Good Good Excellent Good Poor Poor Poor Solvent Blue 36 Excellent Good Good Excellent Poor Poor Poor Poor Solvent Blue 78 Excellent Good Good Excellent Good Good Good Good Solvent Blue 97 Excellent Excellent Excellent Excellent Good Good Excellent Good Solvent Blue 104 Excellent Excellent Excellent Excellent Excellent Excellent Good Good Solvent Green 3 Excellent Excellent Excellent Excellent Good Good Excellent Good Solvent Green 5 Excellent Excellent Excellent Excellent Good Good Good Good Solvent Green 28 Excellent Excellent Excellent Excellent Excellent Excellent Excellent Excellent Solvent Violet 13 Excellent Excellent Excellent Excellent Good Good Good Poor Solvent Violet 26 Excellent Excellent Excellent Excellent Poor Good Poor Poor Declaration: The information contained herein is to the best of our knowledge true and accurate, Resun Colour assumes no legal responsibility for use or reliance upon the above information since the conditions of use are beyond our control. Resun Colour strongly recommends a careful testing and screening before using the products in production. Fluorescent Pigments AS Series Fluorescent Pigments AS Series (also named RH Series) Fluorescent Pigments have superior brightness, high tinctorial strength and more fluorescent when compared to other thermoplastic fluorescent pigments commercially available. AS Series Fluorescent Pigments are recommended for a wide range of applications including aromatic hydrocarbons, vinyl plastisols, organisols, vinyl coated fabric and other plastics applications with melt temperature below 190 degree. AS Series is also suitable in the coloring of the injection molding of ployolefins less than 190 degree. Technical Data: Specific Gravity (Density): Average Particle Size: Softening Point: Decomposition Point: DOP Absorption: 1.36g/cm microns 110C min. 190C max. 48g/100g max. ZQ Series Fluorescent Pigments ZQ Series Fluorescent Pigment features formaldehyde free, low mold plateout, melt-in, high tinting strength, excellent brightness. ZQ Series increase plastic compatibility, fade resistance and excellent heat stability in injection molded plastics up to 300 degree. Technical Data: Specific Gravity (Density): Average Particle Size: Softening Point: Decomposition Point: Processing Temperature: DOP Absorption: 1.2g/cm microns 130C min. 300C max. 185C min. 48g/100g max.

9 Color Reference Application of Fluorescent Pigments Item AS Series ZQ Series HDPE/LDPE PP PS PU EVA PVC PMMA - ABS - Remarks: = Good, = Partly Applicable, - = Not suggested Appendix: Equivalents to other foreign brands Equivalent AS Series ZQ Series DayGlo A, AX ZQ Ciba R, RS EA Radglo (Dutch) R6 K2000 DIC (JP) B3500, B2800 Vizitek Swada (UK) A/D, E, FEX, RTS XSP Seung (UK) FC, FB /NP FH Note: ZQ Series are essentially non-toxic and contain no constituent heavy metals, safe to be applied in the finished product such as toys to comply with currently available international regulations as below: 1. US ASTM F963:96a (4,3,5) Standard Consumer Safety Specification on Toy Safety. 2. EU European Standard on Safety of Toys, EN71 Remarks: Certain metal ions are known to cause color changes and loss of brightness with fluorescent Pigments. Plastic processing additives containing free Zinc, Magnesium, Calcium and Ferro will cause deleterious color effects when used in a plastic resin system containing AS and ZQ Series. If metal containing additives must be used, it is strongly suggested to be thoroughly tested for color stability before using in bulk production.

10 Inorganic Pigments for Masterbatch Synthetic Iron Oxides Pigments Chrome Yellow & Molybdate Pigments High Performance Mixed Metal Oxides for Masterbatch Carbon Black (Pigment Grade) and more Synthetic Iron Oxides Product Name Reference Shade Content Oil Residue On Water ph Moisture Density Full Shade / Fe2O3/Fe3O4 Absorption 325 Mesh Soluble value (max) (g/cm) ZnO reduced 1:10 (min.) (ml/100g) (max.) Salt (max.) Y101 Iron Oxide Red 96% % 0.5% % B Iron Oxide Red 96% % 0.5% % Iron Oxide Yellow 86% % 0.5% % Iron Oxide Yellow 86% % 0.5% % Iron Oxide Black 93% % 0.5% % Y Compound Ferric Green mixed % 2.0% % B Compound Ferric Green mixed % 2.0% % Iron Oxide Brown mixed % 1.0% % Iron Oxide Brown mixed % 1.0% % Iron Oxide Orange mixed % 1.0% % Chrome Yellow & Molybdate Pigments Chrome Yellow Pigment is a chromate of lead and is similar to the lead salt PbCrO4 that occurs naturally as the mineral crocoite. It is obtained synthetically as a yellow crystalline powder by precipitation from a solution of a lead salt (such as lead nitrate) and sodium chromate or sodium dichromate, and is used as a pigment either alone or in mixture with other compounds. Chrome yellow pigments are among several bright pigments with good hiding power that varies from light greenish yellow to reddish medium yellow. Molybdate Red has formular 25PbCrO4.4PbMoO4.PbSO4 with bright color of orange red, this pigment has perfect tinting strength and can be used in plastics and coating industries. Chrome Yellow pigments can be mixed with Molybdate Red in order to reach the desired shade between red and yellow.

11 Product Name Color Index Reference Shade Oil absorption (g/100g) Specific Gravity (g/cm3) Residue on 325m sieve (%, max) Heat resistance (Powder) Light fastne ss ph Value 1621 Lemon Chrome Yellow (C.I. Yellow 34) C Medium Chrome Yellow (C.I. Yellow 34) C Deep Chrome Yellow (C.I. Yellow 34) C Chrome Orange (C.I. Yellow 21) C Molybdate Red (C.I. Red 104) C Remarks: Light Fastness is assessed on a 1-8 scale from "Poor" to "Excellent" Pigment Grade Carbon Black for Masterbatch (C.I No. Black 7) Resun Colour supplies high quality Carbon Black (Pigment Grade) specially applied in plastics & masterbatch production in both economical grade (KV5319) and high performance grade (KV2869). Item KV5319 KV2869 Particle Size (um) 31± 2 21± 2 BET Specific Surface Area (m 2 /g) 88 ± ± 20 DBP Absorption (cc/100g, %) 75 ± 5 62 ± 5 Tint Strength (IRB3=100%, %) 108 ± ± 5 ph Value 8.4± ± 1 Volatile Content (below 950C, %) 3.1± ± 0.2 Apparent Density (g/l) 180 ± ± 20 Similar with Foreign Brand Cabot 430 Degussa Hiblack 50L Mitsubishi MA7 Cabot M800, Regal 660R Suggested Application All-purposed pigment black, good performance in plastic & masterbatch production with good dispersion and dilutability. High performance in plastic and masterbatch application featuring excellent dispersion, high gloss and high strength.

12 High Performance Inorganic Pigments (Mixed Metal Oxides) for Masterbatch High performance inorganic pigments (also named Mixed Metal Oxides) are crystallized color compounds in solid solution produced by the calcinations of two or more kinds of metal oxides including, Co, Cr, Fe, Cd, Se or other transition metal elements at high temperature. This type of pigments has a stable crystalline structure of rutile or spinel which provides outstanding properties in heat resistance, weather resistance and other chemical resistance. This type of pigments has very high performance as the colorants in plastics and masterbatch industry. Cadmium pigments have Cadmium as the main chemical components with shade ranging from yellow to red by increasing contents of Selenium added. Product Name (C.I.No.) Code Chemical Composition Weather Resistance Heat Resistance Reference Shade Titanium Nickle Yellow (C.I. Pigment Yellow 53) Titanium Chrome Yellow (C.I. Pigment Brown 24) Titanium Chrome Yellow (C.I. Pigment Brown 24) Cobalt Blue (C.I. Pigment Blue 28) Cobalt Green (C.I. Pigment Green 50) Copper Chrome Black (C.I. Pigment Black 28) 1302 Ti-Ni-Sb-O C 1402 Ti-Sb-Cr-O C 1406 Ti-Sb-Cr-O C 4803 Co-Al-O C 5003 Co-Ti-O C 7852 Cu-Cr-O C 112 Cd-S C Cadmium Yellow (C.I. Pigment Yellow 35) 113 Cd-S C 114 Cd-S C 115 Cd-S C 116 Cd-S C Cadmium Orange (C.I. Pigment Orange 20) 205 Cd-Se-S C 210 Cd-Se-S C 220 Cd-Se-S C 330 Cd-Se-S C 335 Cd-Se-S C Cadmium Red (C.I. Pigment Red 108) 340 Cd-Se-S C 345 Cd-Se-S C 350 Cd-Se-S C 355 Cd-Se-S C Other Available Inorganic Pigments for Masterbatch Chromium Oxide Green Ultramarine Blue Milori Blue Titanium Dioxide

13 Our Laboratory We are equipped with advanced R&D facilities and lab instruments to cope with the cutting-edge technologies and test methods used in the plastic and masterbatch industry. We test every lot of products before shipment to measure up the standard and file the lab test report of every lot for at least 6 months for quality track. We do not allow goods lower than standard or with "marginal" quality to be shipped to customers. quality to meet or exceed customer s requirements. We optimize the quality to meet or exceed customer s requirements.

14 The best combination of Value and Quality! Website: