Pigments for digital printing. High-performance colorants for premium inkjet inks and electrophotographic toners

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1 High-performance colorants for premium inkjet inks and electrophotographic toners

2 3 Table of contents Table of contents About BASF Colors & Effects 4 Formulating tools for highperformance digital printing 6 Pigments for digital commercial printing 8 Process and spot color pigments 10 Pigment preparations 11 Pigments for digital packaging printing 12 Process and spot color pigments 14 Pigments and dyes for industrial inkjet printing 16 Color pigments 18 Solvent dyes 19

3 4 About BASF Colors & Effects We live colors. We boost effects. BASF is the global specialist for chemistry with centuries-long experience and soughtafter experts. Our Colors & Effects brand incorporates BASF s distinct dyes and pigments, with a range unrivaled in the industry and the basis of our market leadership. We understand that you need a diverse selection backed by our global expertise to continue to grow your business. This is why we offer a comprehensive portfolio to help you stay competitive, including high-performance pigments specially developed for digital printing.

4 Formulating tools for high-performance digital printing Formulating tools for high-performance digital printing 6 7 Formulating tools for high-performance digital printing Digital printing is a fast-growing industry with specific requirements for innovative products. BASF offers a broad range of raw materials for the formulation of best-inclass digital inks. BASF Colors & Effects comprehensive range of organic pigments, pigment preparations and dyes for inkjet inks and electrophotographic toners help to create vivid and long-lasting color prints for all digital printing applications, including commercial, publication, packaging, industrial or home and office printing. The products listed herein are the top selection of classical and high-performance pigments and dyes for the effective formulation of aqueous, solvent-borne and UV-curable inkjet inks, as well as powder and liquid electrophotographic toners. They are the best choice for superior and innovative digital inks. At BASF Colors & Effects, we want to be the supplier of choice for the digital printing industry. For specific formulation requirements or a complete list of products, please contact your BASF Colors & Effects. BASF Colors & Effects supplies organic pigments under the brands Cinquasia, Cromophtal, Irgalite, Irgazin, Heliogen and Paliotol. Solvent dyes are supplied under the brands Orasol and Neptun. Cinquasia Cinquasia are high-performance red, magenta and violet quinacridone pigments that combine outstanding color strength, excellent dispersibility and transparency with excellent fastness to light, weather, heat and chemicals. They are recommended for aqueous, solvent-based and energy-curable inkjet inks and electrophotographic toners. Cromophtal Cromophtal is a high-grade range of azo-condensation, dioxazine, pteridine and benzimidazolone pigments with high transparency, high color strength and very good fastness properties. The Cromophtal pigments cover a wide range of colors and provide excellent rheology and dispersibility in all kind of digital inks. Irgazin Irgazin are high-performance yellow, red and orange organic pigments from the DPP and isoindolinone chemical classes. They are characterized by their outstanding weathering resistance and tinctorial properties. Highly indicated for applications where resistance to extreme conditions, best coloristic properties and high transparency are required. Suitable for all types of digital printing inks and applications. Paliotol Paliotol consists of high-performance organic yellow pigments of greenish to reddish shades, mainly based on quinophthalone and isoindoline chemical classes. With their excellent color strength, rheological properties and fastness, they are recommended for both electrophotographic toners and inkjet inks. Heliogen Heliogen are phthalocyanine blue and green pigments with high color strength, good transparency and excellent fastness properties, for inkjet inks and electrophotographic toners. Heliogen pigments are copper complexes, with the exception of Heliogen Blue D 7490, which is copper-free. Orasol and Neptun Orasol and Neptun are metal-complex and metalfree solvent dyes, respectively. They offer outstanding color strength, chroma and transparency, combined to relatively good light fastness properties and are suitable for solvent-borne inkjet inks and electrophotographic toners. Irgalite Irgalite includes azo pigments with excellent color strength, good transparency and rheology for aqueous, solvent-based and energy-curable inks. They offer relatively good fastness to chemicals and light for various end-use digital printing ink applications.

5 Pigments for digital commercial printing 9 Pigments for digital commercial printing Digital printing, both electrophotography and inkjet, has been widely used for years for commercial and publication printing and is today well established and competing with conventional printing technologies, particularly lithography and screen. For the most demanding applications Except for home and office printing, commercial printing is the largest segment of digital printing. It includes advertising print such as posters, promotional brochures, catalogues, inserts, flyers or direct mail, as well as transactional print (financial documents like statements, bills and invoices), manuals, leaflets, office stationery or security printing. Digital publication printing (e.g. newspaper, magazines, directories, books) has taken off over the last few years, thanks to the development of high speed web-fed or sheet-fed inkjet and electrophotographic presses (both mono and full-color). For medium- to large-format printing for advertorial or fine-art reproduction purposes, coloristic properties and durability are key parameters when selecting pigments for digital ink formulation. Our high performance organic pigments offer excellent color strength, chroma and light fastness and are particularly suitable for the most demanding digital commercial printing applications. Maximum color strength and transparency In addition to pigments, BASF Colors & Effects offers Microlith K, which are state-of-the-art pigment preparations consisting of high performance pigments pre-dispersed in a vinyl co-polymer. They are widely used in solvent-based inkjet inks for wide-format indoor and outdoor graphics. Their small particle size and extremely narrow particle size distribution, obtained by our specialized manufacturing process, affords maximum color strength and transparency as well as outstanding dispersion stability. Microlith K pigment preparations, which come as low-dusting granules, are very easily incorporated into usual ink jet ink solvents like ketones, glycol ethers or glycol ether esters (or blends thereof) by means of just a dissolver or other high-speed mixers, without the need for milling. They also have limited compatibility with selected UV monomers and might therefore be used for the straightforward formulation of UV-curable inks. BASF Colors & Effects offers further Microlith preparations, covering a wide range of chemical types, shades, and fastness performance. For a complete list of products, please contact your BASF Colors & Effects representative.

6 Pigments for digital commercial printing Pigments for digital commercial printing Process and spot color pigments Pigment preparations 1 Suited 2 Highly recommended 0 Potentially suited 1 Suited 2 Highly recommended Product Colour Index Chemistry Inkjet Electrophotography Aquoeus Solvent-borne UV-curable Key properties Product Colour Index Pigment content [%] Inkjet Electrophotography Aquoeus Solvent-borne UV-curable Key properties Paliotol Yellow D 0960 PY 138 Quinophthalone Cromophtal Yellow D 1040 PY 93 Azo condensation Cromophtal Yellow L 1061 HD PY 151 Benzimidazolone Paliotol Yellow D 1080 J PY 138 Quinophthalone Cromophtal Yellow D 1085 J PY 150 Azo metal complex Paliotol Yellow D 1155 PY 185 Isoindoline Paliotol Yellow D 1819 PY 139 Isoindoline Irgazin Yellow D 1999 PY 110 Isoindolinone Greenish yellow, high transparency and fastness to weathering Greenish process yellow with high transparency and excellent light fastness Greenish process yellow with good rheology and outdoor durability Process yellow, optimized hue and rheology in UV and solvent inkjet ink systems, excellent light fastness Standard process yellow with high color strength, transparency and weather fastness State-of-the-art process yellow with outstanding color strength, excellent rheology and high transparency Red-shade yellow with excellent color strength and fastness to light Red-shade yellow, high color strength and transparency, outdoor durability Microlith Black 0066 KJ PBk Standard black Microlith Yellow 1061 KJ PY Greenish process yellow, high light fastness Microlith Yellow 1550 K PY Reddish yellow with excellent color strength Microlith Yellow 2040 KJ PY Red-shade yellow, high color strength and transparency Microlith Red 3630 KJ PR Mid-shade red, high color strength Microlith Red 3890 K PR Bluish red, excellent light fastness Microlith Magenta 4330 KJ Yellow-shade process magenta with high color strength Microlith Magenta 4535 KJ PR Blue-shade magenta with high color strength Microlith Violet 5700 K PV Mid-shade violet, outstanding color strength Microlith Blue 7080 KJ PB 15: Standard process blue Microlith Green 8750 K PG Standard blue-shade green Cromophtal Orange D 2961 PO 64 Benzimidazolone Mid-shade orange with excellent strength, highly transparent Irgazin Red L 3630 PR 254 DPP Cinquasia Red L 4105 HD PV 19 Quinacridone Cinquasia Magenta D Quinacridone/DPP Cinquasia Magenta D 4500 J - Quinacridone Mid-shade red, high color strength, transparency and light fastness, might be used to shade quinacridone magenta pigments Yellow-shade process magenta, good dispersibility and rheology High-performance rubine, outstanding color strength and light fastness Very clean and chromatic blue-shade magenta, excellent transparency and light-fastness Cinquasia Magenta K 4535 PR 202 Quinacridone Blue-shade magenta, high color strength and light fastness Cinquasia Magenta D 4545 J - Quinacridone Cinquasia Magenta D 4550 J PR 122 Quinacridone Cromophtal Violet D 5800 PV 23 Dioxazine Heliogen Blue D 7079 PB 15:3 Cu-Phthalocyanine Bluish process magenta with excellent strength and low viscosity, good outdoor durability Blue-shade magenta, excellent dispersibility in aqueous ink systems, excellent strength and chroma Mid-shade violet, outstanding color strength, transparency and dispersibility Standard process blue, excellent dispersibility in water-based inks and powder electrophotographic toners Heliogen Blue D 7088 PB 15:3 Cu-Phthalocyanine Standard process blue, high color strength and transparency Heliogen Blue D 7110 F PB 15:4 Cu-Phthalocyanine Process blue with high strength and excellent dispersibility and rheology in UV ink sytems Heliogen Cyan S 7320 PB 15:3 Cu-Phthalocyanine Optimized for aqueous inkjet, excellent dispersibility Heliogen Green D 8730 PG 7 Cu-Phthalocyanine Standard blue-shade green with excellent durability

7 Pigments for digital packaging printing 13 Pigments for digital packaging printing Packaging print is still dominated by conventional printing processes, particularly gravure, fl exo and offset printing, but digital printing is growing strongly and has started to evolve from a minority to a mainstream process. Strong momentum Labels are by far the largest segment of digital packaging printing, but the penetration of digital printing into other packaging printing segments, specifi cally cartons, corrugated, fl exibles, rigid plastics and metals is gaining strong momentum, thanks mainly to the recent development of inkjet and electrophotographic presses specifi cally addressing those markets. Thought for food BASF Colors & Effects has established a portfolio of pigments compliant with food contact compliance, which consists of products for which food-contact statements are available. These are regularly updated based on legislations and recommendations by the relevant regional and national organizations or authorities. Performance and safety For creative, attractive and colorful packagings that increase the perceived value of food, beverages and consumer goods at point of sale, BASF Colors & Effects offers a premium selection of classical and high-performance organic pigments. Those pigments provide excellent color strength, very vibrant and durable colors, along with the required dispersibility and rheology for digital inks applied on various packaging substrates, including paper/ cardboard/carton, plastics, fi lms and foils. With leadership comes responsibility BASF Colors & Effects is a signatory of Responsible Care. This is a global chemical industry initiative aimed at achieving continuous performance improvements in the fi elds of environment, health and safety. Besides design and attractiveness, another critical aspect of packagings is consumer safety, particularly when it comes to food packaging. Food packaging represents more than 50% of the global consumer packaging market and 75% of packaging is printed. Therefore, food packaging as well as other sensitive applications like beverage, health care and cosmetics packaging systematically needs to be taken into consideration when developing digital inks for packaging printing.

8 Pigments for digital packaging printing Pigments for digital packaging printing Process and spot color pigments 1 Suited 2 Highly recommended 1 Suited 2 Highly recommended Product Colour Index Chemistry Inkjet Electrophotography Aquoeus Solvent-borne UV-curable Recommended for sensitive applications Paliotol Yellow D 0960 PY 138 Quinophthalone Cromophtal Yellow L 0990 PY 128 Azo condensation Cromophtal Yellow D 1040 PY 93 Azo condensation Paliotol Yellow D 1155 PY 185 Isoindoline Cromophtal Yellow D 1500 PY 95 Azo condensation Irgalite Yellow K 1740 PY 83 Diarylide Paliotol Yellow D 1819 PY 139 Isoindoline Irgazin Yellow L 2060 PY 110 Isoindolinone Irgazin Orange D 2905 PO 71 DPP Cromophtal Orange K 2960 PO 64 Benzimidazolone Cromophtal Orange D 2961 PO 64 Benzimidazolone Irgalite Orange D 2980 PO 34 Diarylide pyrazolone Cromophtal Scarlet D 3430 PR 166 Azo condensation Cromophtal Scarlet D 3540 PR 166 Azo condensation Product Colour Index Chemistry Inkjet Electrophotography Aquoeus Solvent-borne UV-curable Recommended for sensitive applications Cinquasia Pink K 4430 FP PR 122 Quinacridone Cinquasia Magenta D 4500 J - Quinacridone Cinquasia Magenta L Quinacridone Cinquasia Magenta D 4550 J PR 122 Quinacridone Cromophtal Violet D 5700 PV 37 Dioxazine Cromophtal Violet D 5800 PV 23 Dioxazine Heliogen Blue D 6700 T PB 15:6 Cu-Phthalocyanine Heliogen Blue D 7079 PB 15:3 Cu-Phthalocyanine Heliogen Blue D 7088 PB 15:3 Cu-Phthalocyanine Heliogen Blue D 7092 PB 15:3 Cu-Phthalocyanine Heliogen Blue D 7110 F PB 15:4 Cu-Phthalocyanine Heliogen Blue D 7490 PB 16 Phthalocyanine Heliogen Green D 8725 PG 7 Cu-Phthalocyanine Heliogen Green D 8730 PG 7 Cu-Phthalocyanine Irgazin Red L 3550 HD PR 255 DPP Cromophtal Red D 3635 PR 144 Azo condensation Irgazin Red L 3670 HD PR 254 DPP Irgalite Red D 3785 PR 48:2 Azo 2B Toner (Ca) Cromophtal Red D 3890 PR 144 Azo condensation Irgalite Rubine D 4240 PR 57:1 4B Toner (Ca) Irgalite Rubine D 4242 PR 57:1 4B Toner (Ca) Irgalite Rubine D 4280 PR 57:1 4B Toner (Ca) Cinquasia Magenta D Quinacridone / DPP

9 Pigments and dyes for industrial inkjet printing 17 Pigments and dyes for industrial inkjet printing Industrial printing encompasses a number of applications, including signs and displays, textile printing, architectural decoration (floor and wall covering, furniture decoration, vinyl curtains and tablecloths, glass decoration), coding and marking, printed electronics, 3D printing or liquid deposition. The digital printing technology of choice for industrial printing is inkjet. Comparable with conventional printing BASF Colors & Effects has selected a range of pigments for industrial inkjet that meet the specific requirements of aforementioned applications in terms of color reproduction and print durability, and enable to achieve high-quality prints that compete on an even footing with prints obtained by gravure or screen printing. Pigment dispersions for industrial inks BASF Colors & Effects also offers pigment dispersions in liquid or granular form, which might be used for the formulation of water-based or solvent-borne industrial inkjet inks. Those dispersions are available under the brand names Dispers, Luconyl NG, Xfast, Microlith and Euvinyl. Please contact your BASF Colors & Effects representative for more information. Solvent dyes for coding and marking plus special applications requiring highest chroma and transparency For coding and marking by continuous inkjet, BASF Colors & Effects offers Orasol and Neptun solventsoluble black and color dyes for printing of information and data such as expiry dates, lot numbers or bar codes on a variety of substrates and items, such as packaging materials, plastics (e.g. wire and cable marking) or metals. Orasol and Neptun dyes might also be used for solvent-based packaging printing, particularly on metal foil and transparent film, where they offer outstanding color strength, chroma and transparency. Further solvent dyes are available in the Orasol and Oracet product ranges, please contact your BASF Colors & Effects representative for more information. Range Dispers Luconyl NG Xfast Microlith WA Microlith K Euvinyl C Type of preparation Liquid for w/b systems Surfactant based (nonionic), resin-free Liquid for w/b systems Surfactant based (nonionic), resin-free Solid for w/b systems Surfactant based (nonionic), resin-free Solid for w/b systems Resin-based (acrylic) Solid for s/b systems (UV possible) Resin-based (vinyl) Solid for s/b systems (UV possible) Resin-based (vinyl)

10 Pigments and dyes for industrial inkjet printing Pigments and dyes for industrial inkjet printing Color pigments Solvent dyes 1 Suited 2 Highly recommended Product Colour Index Chemistry Aquoeus Solvent-borne UV-curable Key properties Product Colour Index Chemistry Key properties Paliotol Yellow D 0960 PY 138 Quinophthalone Greenish yellow, high transparency and fastness to weathering Cromophthal Yellow L 0990 PY 128 Disazo condensation Greenish yellow, good transparency and rheology, high weather-fastness Cromophthal Yellow L 1061 HD PY 151 Benzimidazolone Greenish process yellow with good rheology and outdoor durability Paliotol Yellow D 1080 J PY 138 Quinophthalone Process yellow, optimized hue and rheology in UV and solvent inkjet ink systems, excellent light fastness Cromophtal Yellow D 1085 J PY 150 Metal complex Paliotol Yellow D 1155 PY 185 Isoindoline Standard process yellow with high color strength, transparency and weather fastness State-of-the-art process yellow with outstanding color strength, excellent rheology and high transparency Paliotol Yellow D 1819 PY 139 Isoindoline Red-shade yellow with excellent color strength and fastness to light Irgazin Yellow L 2040 PY 110 Isoindolinone Reddish yellow, transparent, excellent fastness properties Irgazin Orange D 2905 PO 71 DPP Yellowish orange, excellent light fastness Cromophtal Orange D 2961 PO 64 Azo heterocycle Mid-shade orange with excellent strength, highly transparent Irgalite Orange D 2980 PO 34 Disazopyrazolone Excellent strength, good rheology Cromophtal Scarlet D 3430 PR 166 Disazo condensation Yellowish red with excellent dispersibility, high color strength and transparency Irgazin Red L 3630 PR 254 DPP Mid-shade red, high color strength, transparency and light fastness Cromophtal Red D 3635 PR 144 Disazo condensation Irgazin Red D 3656 HD PR 254 DPP Opaque, versatile mid-shade red Mid-shade red with high color strength, transparent with excellent fastness to weathering Irgalite Rubine L 4025 PR 264 DPP Very strong bluish red, excellent fastness properties Orasol Black X45 SBk 28 1:2 Cr Complex Greenish black with high solubility in ketones Orasol Black X51 SBk 27 1:2 Cr Complex Deep black, excellent light fastness Orasol Black X55 SBk 29 1:2 Cr Complex Deep black, broad solubility spectrum, high light fastness Neptun Yellow 075 SY 162 Azo Greenish yellow with excellent strength and chroma, metal-free Orasol Yellow 152 SY 88 1:2 Cr complex Mid-shade yellow, broad solubility spectrum, high light fastness Orasol Yellow 157 SY 82 1:2 Cr complex Mid-shade yellow with high light fastness Orasol Yellow 190 SY 89 1:2 Co complex Strong, reddish yellow with broad solubility spectrum and high light fastness Orasol Orange 247 SO 11 1:2 Co complex Mid-shade orange, high light fastness Orasol Orange 251 SO 54 1:2 Cr complex Mid-shade orange with excellent solubility in polar solvents Orasol Orange 272 SO 99 1:2 Cr complex Reddish orange with outstanding color strength, high solubility and excellent light fastness Orasol Red 355 SR 119 1:2 Cr complex Yellowish red, high color strength Orasol Red 363 SR 125 1:2 Co complex Very clean and strong mid-shade red Orasol Red 365 SR 160 1:2 Cr complex Mid-shade red, broad solubility spectrum, good light fastness Orasol Red 395 SR 122 1:2 Cr complex Bluish red, excellent bleeding resistance Orasol Red 471 SR 118 1:2 Co complex Rubine red, good light fastness Orasol Pink 478 SR 127 1:1 Cr complex Clean magenta shade, excellent alcohol solubility Orasol Blue 825 SB 67 Cu Phthalocyanine Greenish blue with best bleeding resistance Orasol Blue 855 SB 70 Cu Phthalocyanine Greenish blue, economical Irgalite Rubine D 4240 PR 57:1 BONA, Ca Process magenta, high strength and transparency Cinquasia Pink K 4430 FP PR 122 Quinacridone Bluish process magenta, high strength and fastness Cinquasia Magenta D 4500 J - Quinacridone Cinquasia Magenta D 4545 J - Quinacridone Very clean and chromatic blue-shade magenta, excellent transparency and light-fastness Bluish process magenta with excellent strength and low viscosity, good outdoor durability Cromophtal Violet D 5700 PV 37 Dioxazine Reddish violet, outstanding color strength, transparency and dispersibility Cromophtal Violet D 5800 PV 23 Dioxazine Mid-shade violet, outstanding color strength, transparency and dispersibility Paliogen Blue L 6495 F PB 60 Indanthrone Reddish blue with excellent fastness Heliogen Blue D 6700 T PB 15:6 Cu-Phthalocyanine Most reddish CuPC type, high strength and transparency Heliogen Blue D 7088 PB 15:3 Cu-Phthalocyanine Standard process blue, high color strength and transparency Heliogen Blue D 7110 F PB 15:4 Cu-Phthalocyanine Greenish process blue with high strength and excellent dispersibility and rheology in UV ink sytems Heliogen Green D 8730 PG 7 Cu-Phthalocyanine Standard blue-shade green with excellent durability

11 Contacts Asia Pacific BASF Colors & Effects Shanghai Ltd. No 300, Jiang Xin Sha Road Shanghai China Americas BASF Colors & Effects USA LLC West Eleven Mile Road Southfield, MI USA Europe BASF Colors & Effects GmbH An der Rheinschanze Ludwigshafen Germany Visit our website: The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our products to ensure that any proprietary rights and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene measures adequate for handling chemicals must be observed. (07/2017) = Registered trademark of BASF SE

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