Technical Information FK05

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1 Technical Information FK05 Performance Pigments and Colors InstantColor for the Stoneware Industry A New Era in Ceramic Stains The Performance Pigments and Colors division of Ferro develops, produces, and markets pigments, special glasses, glazes, and special coating materials. In the ceramic industry, we are world famous for our innovative, high-quality colouring products. Our most important goal is to maintain a high level of product quality and to maximize customer satisfaction. To ensure this, we emphasize dialogue and partnership with our customers, focusing on the challenges of their markets and on their suggestions and requirements, as well as on our mutual desire to protect the environment. As a result, we are always ready with the most creative and ambitious new products our customer need. Innovative, powerful colours can be created from the basic range, while pastel tones can be easily matched. Quality Controls Ensure Stains Meet Stoneware Requirements Stains for the stoneware industry must meet specific requirements. Usually they are fired several hours at a temperature > 1200 C, and must remain true, constant, and specific in colour. It is also advantageous if they are capable of being fired a second time at high temperature without deterioration of colour and surface. This enables a repair or decorating firing for bigger stoneware objects. Ongoing research and development is the basis of the high quality of our stains, as we continually improve not only their composition, but also our production technology and test methods. InstantColor : Reliable, Ready-to-use Colours Optimal colour, chroma, and brilliance all this from a ceramic stain that is so easy to use. Ordinary glaze stains must be ground in a ball mill before mixing. InstantColor stains consist of uniformly minute particles that are dissolved instantly in the glaze slurry. Extremely fine grains mean far easier dispersibility and more uniform coverage, less production time, and less waste. The InstantColor stoneware line is a range of breakthrough products that give the stoneware industry the tools it needs to create fashionable fixtures fast and reliably.

2 page 2/6 FK05 11/12 We ensure that our products meet these requirements by putting them through rigorous quality checks. All stains are tested at 1250 C for 13 hours. They are also checked for shade variation, dispersibility, and fineness. Every batch is compared with a colour master, and tested for grain size and sieve residue % of InstantColor particles (with exception of inclusion pigments) are guaranteed to be smaller than 32 μm. In every case you can expect uniformly coloured glazes, with no agglomerates to cause ugly spots after firing. The detailed test conditions for all our products are specified in the corresponding data sheets, which we will gladly send to you on request. The Advantages of the InstantColor Series Brilliant Colours: The 16 basic shades are pure, strikingly bright colours. Deep intensity is combined with a brilliant finish. Miscibility: An infinite number of colours can be prepared from the basic range. Colours can be easily adjusted right in the barrel. Extremely Fine, Uniform Particles: 99,9 % of InstantColor grains are smaller than 32 μm. Easy Dispersibility: Environmental Compatibility: All InstantColor Stoneware pigments are lead free and consequently particularly suitable for lead free glazes. Stains that use cadmium to achieve brilliant reds, oranges, and yellows encapsulate the colour crystals in zirconium silicate, creating totally inert inclusion pigments. Flawless Appearance: InstantColor brings a more uniform, flawless surface to opaque glazes. Flexible Production: Small batches are a snap. Switching from one colour to another is so easy, it makes just-in-time production a reality. No mills to clean, no colour contamination, and no waste. Cost-Effectiveness: Requiring no capital investment, no mill clean-up time, less water for disposal, and providing highefficiency intense colours with minimal waste, the InstantColor range is extremely costeffective to use. Help When You Need It: The product without the service is only half of what you need. We offer the whole package. Our highly trained development teams, production and engineering staff are backed up by customer service technicians ready to listen to your concerns. For further information please call our technical service department. Readily dispersed in standard slurries, InstantColor stains offer flexible handling.

3 FK05 11/12 page 3/6 Table 1: InstantColor stoneware stains composition, crystal structure and firing conditions Pigment System Colour Shade Crystal Sieve Residue Firing Tmax/ C Structure (>32 μm) Conditions Co-Cr-Al Chrome Green Spinel 1400 <0,1 % ox./red Zr-V-Si Turquoise Blue Zircon 1350 <0,1 % ox./slightly red Co-Al Cobalt Blue Spinel 1450 <0,1 % ox./red Co-Si Cobalt Blue Olivine 1450 <0,1 % ox./red Zr-Si-Cd-S-Se Brilliant Orange Zircon 1350 <5,0 % ox Zr-V Havanna Baddeleyite 1400 <0,1 % ox./red Zr-Pr-Si Intense Yellow Zircon 1250 <0,1 % ox Zr-Si-Cd-S Yellow Zircon 1350 <5,0 % ox Co-Cr-Fe-Ni Black Spinel 1300 <0,1 % ox Sn-Sb-V Neutral Grey Rutile/ Cassiterite 1300 <0,1 % ox Zr-Si-Co-Ni Zircon Grey Zircon 1350 <0,1 % ox./slightly red Zn-Al-Cr-Fe Biscuit Spinel 1300 <0,1 % ox Zn-Cr-Fe Wood Brown Spinel 1300 <0,1 % ox Ca-Sn-Si-Cr Rose Sphene 1250 <0,1 % ox Zr-Si-Cd-S-Se Intense Red Zircon 1350 <5,0 % ox Zr-Fe-Si Coral Zircon 1250 <0,1 % ox. 1 GHS symbol 08, 09; H phrases 315, 317, 334, 341, 350i, 360D, 372, 411 Table 2: Glaze system compatibility Pigment R 2O MgO CaO ZnO PbO SnO 2 B 2O 3 ZrO 2 Colour addition for colour examples transparent glaze opaque glaze % in A 2 % in B % in A 2 % in B % in A 2 % in B % in A 2 % in B % in A 2 % in B % in A 2 % in B % in A 2 % in B % in A 2 % in B % in A 2 % in C % in A 2 % in B % in A 2 % in B % in A 5 % in D % in A 5 % in D % in A 2 % in B % in A 5 % in C % in A 2 % in B 1 GHS symbol 08, 09; H phrases 315, 317, 334, 341, 350i, 360D, 372, 411 : well suitable combinations : unsuitable combinations Table 3: Glaze composition for colour examples Glaze A B C D SiO 2 64,7 61,7 65,3 60,7 Al 2O 3 13,9 10,9 10,0 13,1 ZrO 2-8,4 8,1 6,0 CaO 10,4 11,8 10,3 9,8 BaO 3,4-1,7 3,2 ZnO 3, ,2 K 2O 2,2 0,8 2,1 2,1 Na 2O 1,0 4,5 1,6 0,9 MgO 0,8 1,9 0,9 0,8 B 2O 3 0, ,2

4 page 4/6 FK05 11/12 Fig. 1: InstantColor colour samples in transparent glaze A* Chrome Green Turquoise Blue Cobalt Blue Cobalt Blue Brilliant Orange Havanna Intense Yellow Yellow Black Neutral Grey Zircon Grey Biscuit Wood Brown Rose Intense Red Coral * Quantities of colour addition for this glaze is listed in table 2. While every attempt has been made to reproduce colours exactly, the samples printed here may differ slightly from the finished ceramic products. Each InstantColor stain must be used according to the parameters stipulated on its accompanying technical data sheet. Please refer to these sheets for full information.

5 FK05 11/12 page 5/6 Fig. 2: InstantColor colour samples in opaque glazes B, C or D* Chrome Green Turquoise Blue Cobalt Blue Cobalt Blue Brilliant Orange Havanna Intense Yellow Yellow Black Neutral Grey Zircon Grey Biscuit Wood Brown Rose Intense Red Coral * Quantities of colour addition for this glaze is listed in table 2. While every attempt has been made to reproduce colours exactly, the samples printed here may differ slightly from the finished ceramic products. Each InstantColor stain must be used according to the parameters stipulated on its accompanying technical data sheet. Please refer to these sheets for full information.

6 page 6/6 FK19 11/12 The information and statements contained herein are provided free of charge. They are believed to be accurate at time of publication, but Ferro makes no warranty with respect thereto, including but not limited to any results to be obtained or the infringement of any proprietary rights. Use or application of such information or statements is at user s sole discretion, without any liability on Ferro s part. Nothing herein shall be construed as a license of or recommendation for use that infringes upon any proprietary rights. All sales are subject to Ferro s General Conditions of Sale and Delivery. PPC IS FK05 11/12 D Ferro GmbH Performance Pigments and Colors Gutleutstr Frankfurt/M. Tel. ++49/(0)69/ Fax ++49/(0)69/ pigments@ferro.com

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