Myrifilm Zero-VOC Coalescing Solvent

Transcription

1 Myrifilm Zero-VOC Coalescing Solvent

2 Myrifilm Coalescing Solvent in Compliant Coatings Zero-VOC Low Odor High-Efficiency, Lower Usage Lower Formulation Costs Smaller environmental footprint Bio-based solvent produced from renewable sources Performs in Wide Range of Resins 2

3 Myrifilm Coalescing Solvent Application Testing Areas & Protocol Performance Comparable to Industry Standard Texanol TM * Performance Comparable to Other Coalescing Solvents Performs In a Broad Range of Resin Types High Efficiency May Result in Lower Formulation Costs Performs Well in Commercial Coatings Formulations * Texanol TM, TXIB TM and Optifilm TM are registered tradeamark owned by Eastman Chemical Company. RHOPLEX TM is a registered trademark owned by Rohm and Hass Company. ORGAL is a registered trademark owned by Organik Holding Anonim Sirketi Joint Stock Company TURKEY ACRONAL and STYROFAN are registered trademarks owned by BASF AKTIENGESELLSCHAFT CORPORATION 3

4 Myriant Tested Typical Formulation Application Area Application Areas for Myrifilm Testing Architectural Coatings Construction and Adhesives General Industrial Graphics 5.35 MM MT resin 2.39 MM MT resin 1.5 MM MT resin 466 kmt resin Acrylic, Styrene/Acrylic, EVA Resin Pigment Coalescing Solvent Performance Additives Styrene/Butadiene, Styrene/Acrylic, Acrylic Resin Pigment Coalescing Solvent Performance Additives Acrylic, Styrene/Acrylic Resin Pigment Coalescing Solvent Performance Additives Acrylic Resin Pigment Coalescing Solvent Performance Additives Semi-gloss acrylic paint [Rhoplex TM SG-30, Orgal P855RR] Myrifilm vs.: Texanol TM, TXIB TM, Optifilm TM 400, DPnB Acrylic (Rhoplex TM SG-30, Acronal S504) Styrene/Acrylic (Acronal 296D) Styrene/Butadiene (Styrofan ND 593) Tested film forming effectiveness vs. Texanol TM No testing performed Tested general paint and finished coating properties 4

5 Myriant- Cal Poly Development Partnership Leader in development and testing of waterborne coatings systems Polymer development and characterization Formulation development Performance characterization VOC method development Western Coatings Technology Center Google Maps Image Sponsors: BASF, Boeing, Dunn Edwards, DuPont, ET Horn, Guidant, Kelly-Moore Paints, Rohm and Haas, Sherwin Williams, Valspar, Vista Paint 5

6 Myrifilm Key Performance Parameters Myrifilm evaluated for the following characteristics Viscosity Sag Leveling Contrast Ratio Tint Strength Gloss Block resistance Scrub Resistance 6

7 Myrifilm Coalescing Solvent Application Testing Areas & Protocol Performance Comparable to Industry Standard Texanol TM Performance Comparable to Other Coalescing Solvents Performs In a Broad Range of Resin Types High Efficiency May Result in Lower Formulation Costs Performs Well in Commercial Coatings Formulations 7

8 Myrifilm vs. Texanol TM Property Semi-Gloss Acrylic with Myrifilm Semi-Gloss Acrylic with Texanol TM Myrifilm KU Viscosity (immed./24 h) 87.9/ /107.8 Texanol TM Sag Sag Leveling 4 4 Contrast ratio (Air-dry, 24h) Scrub Resistance Leveling Gloss 20 /60 / /74.4/ /75.3/ Block Resistance (120 F, 24 h) 5 6 Scrub Resistance (2400 cycles) 8 8 Block Resistance Normalized Contrast Ratio Low Temperature Coalescing (40 F, 10 mil) 5 5 Tint Strength (Red) %T SUC Myrifilm Texanol Normalized 60 Gloss Gloss and Contrast Ratio Scaled to a Maximum Value of 10 Tint Strength (Yellow) %T SUC Tint Strength (Blue) %T SUC VOC (ASTM ) Odor Low High Myrifilm performs as well as Texanol TM in typical acrylic formulation with Zero VOC & Low Odor lb/gal density, 33.97% solids in formulation. Dow Rhoplex SG-30 Binder resin (47.7 % w/w); 2.5 wt% coalescent relative to binder resin; TiO 2 Pigment with final PVC Based on Dow recommended formulation for this resin. 8

9 Myrifilm Coalescing Solvent Application Testing Areas & Protocol Performance Comparable to Industry Standard Texanol TM Performance Comparable to Other Coalescing Solvents Performs In a Broad Range of Resin Types High Efficiency May Result in Lower Formulation Costs Performs Well in Commercial Coatings Formulations 9

10 Myrifilm vs. Other Coalescents Myrifilm Texanol TM TXIB TM Optifilm TM 400 DPnB lb/gal density, 33.97% solids in formulation. Dow Rhoplex SG-30 Binder resin (47.7 % w/w); 2.5 wt% coalescent relative to binder resin; TiO 2 Pigment with final PVC Based on Dow recommended formulation for this resin. Myrifilm performs as well as Texanol TM, TXIB TM, and Optifilm TM in a typical acrylic formulation 10

11 Myrifilm vs. Other Coalescents Property Semi-Gloss Acrylic with Myrifilm Semi-Gloss Acrylic with Texanol TM Semi-Gloss Acrylic with TXIB TM Semi-Gloss Acrylic with Optifilm TM 400 Semi-Gloss Acrylic with DPnB KU Viscosity (immed./24 h) 87.9/ / / / /95.4 Sag Leveling Contrast ratio (Air-dry, 24h) Gloss 20 /60 / /74.4/ /75.3/ /75.1/ /78.0/ /73.3/96.2 Block Resistance (120 F, 24 h) Scrub Resistance (2400 cycles) Low Temperature Coalescing (40 F, 10 mil) Tint Strength (Red) %T SUC Tint Strength (Yellow) %T SUC Tint Strength (Blue) %T SUC VOC Odor Low High High Medium High lb/gal density, 33.97% solids in formulation. Dow Rhoplex TM SG-30 Binder resin (47.7 % w/w); 2.5 wt% coalescent relative to binder resin; TiO 2 Pigment with final PVC Based on Dow recommended formulation for this resin. Myrifilm performs as well as Texanol TM, TXIB TM, and Optifilm TM in a typical acrylic formulation with Zero VOC & Low Odor 11

12 Myrifilm Coalescing Solvent Application Testing Areas & Protocol Performance Comparable to Industry Standard Texanol TM Performance Comparable to Other Coalescing Solvents Performs In a Broad Range of Resin Types High Efficiency May Result in Lower Formulation Costs Performs Well in Commercial Coatings Formulations 12

13 Myrifilm Coalescing Performs in Broad Range of Resin Types KU (Initial) KU (24h) Low Temperature Coalescing (10 mil film) Low Temperature Coalescing (5 mil film) Rhoplex TM SG-30 (Acrylic) with Myrifilm Rhoplex TM SG-30 (Acrylic) with Texanol TM Styrofan ND 593 (Styrene/Butadiene) with Myrifilm Styrofan ND 593 (Styrene/Butadiene) with Texanol TM Acronal S504 (Acrylic adhesives) with Myrifilm Acronal S504 (Acrylic adhesives) with Texanol TM Acronal 296D (Styrene/Acrylic) with Myrifilm Acronal 296D (Styrene/Acrylic) with Texanol TM Myrifilm performs better than Texanol TM in a broad range of typical waterborne resins 35% solids in formulation. 3 wt% coalescent relative to binder resin. 13

14 Myrifilm Coalescing Solvent Application Testing Areas & Protocol Performance Comparable to Industry Standard Texanol TM Performance Comparable to Other Coalescing Solvents Performs In a Broad Range of Resin Types High Efficiency May Result in Lower Formulation Costs Performs Well in Commercial Coatings Formulations 14

15 Myrifilm Retains Performance at Lower Concentration Blocking Normalized contrast ratio Normalized 60 Gloss Myrifilm performs as well as Texanol TM at HALF the concentration Dosage Myrifilm 1.2 wt% relative to resin Texanol TM 2.4 wt% relative to resin Leveling Normalized 85 Gloss KU Viscosity Contrast Ratio Sag Myrifilm 50% loading Myrifilm Texanol Standard Dosage Texanol TM 60 Gloss Gloss Sag Leveling 5 5 Blocking lb/gal density, vol% solids in formulation. Orgal P885RR binder resin (38.9 % w/w); 2.5 wt% coalescent relative to binder resin; TiO 2 Pigment with final PVC

16 Myrifilm Coalescing Solvent Application Testing Areas & Protocol Performance Comparable to Industry Standard Texanol TM Performance Comparable to Other Coalescing Solvents Performs In a Broad Range of Resin Types High Efficiency May Result in Lower Formulation Costs Performs Well in Commercial Coatings Formulations 16

17 Myrifilm Performance in Commercial Coatings Property Semi-Gloss Interior Acrylic with Myrifilm Semi-Gloss Deep Base Acrylic with Myrifilm Satin Interior Acrylic with Myrifilm KU Viscosity (24h/7 d) 102/ / /105 Contrast ratio (Air-dry, 24h) Gloss 20 /60 / /51.1/ /51.9/ /18.6/36.2 Yellowness Index (24h) Freeze Thaw Stability (5x, D KU) F Oven Stability (10d, D KU) Block Resistance (RT, 24 h/3d/7d) 8/9/9 7/8/8 8/9/9 Block Resistance (120 F, 24 h/3d/7d) 6/7/8 3/4/6 6/8/8 Pendulum Hardness Scrub Resistance pass pass pass Low Temperature Coalescing pass pass pass Stain Resistance Pass pass pass 17

18 Myrifilm Coalescing Solvent in Compliant Coatings Zero-VOC Low Odor High-Efficiency, Lower Usage Lower Formulation Costs Smaller environmental footprint Bio-based solvent produced from renewable sources Performs in Wide Range of Resins 18