OROTAN N-4045 Pigment Dispersant

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1 OROTAN N-4045 Pigment Dispersant Description OROTAN N-4045 is a higher solids version of OROTAN N Both have the same composition, same efficiency and overall performance. OROTAN N-4045 is a polycarboxylic acid pigment dispersant that offers excellent performance at an economical price. OROTAN N-4045 can be used for a wide variety of latex paint formulations. It is recommended for low sheen flat through semi-gloss Acrylic, Styrene-Acrylic and Vinyl Acrylic formulations and is effective over a ph range of 6.5 to 10 with a wide temperature range. OROTAN N-4045 pigment dispersant is supplied at 45% solids in the sodium form. It is highly compatible with anionic HASE and ACRYSOL DR associative Rheology Modifiers providing excellent heat age and viscosity stability. It is a very low foaming dispersant and is very efficient to disperse mineral slurries. OROTAN N-4045 is most commonly used at levels of 0.3%-1.0% active ingredient based on total weight of pigment and extenders. Characteristics of the Product Lower formulated cost Low millbase viscosity for efficient dispersion Wide versatility. Can be used in flats through semi gloss formulations Highly compatible with anionic HASE and ACRYSOL DR type rheology modifiers Excellent colour acceptance with high reproducibility Excellent heat-age and shelf stability Low odour Easy to process and handle Typical Properties These properties are typical but do not constitute specifications. Appearance Chemical Type Clear, yellow liquid Anionic ph (as shipped) Solids % 45 Specific gravity at 25 C 1.3 Formulations Guidelines Technical Evaluation of OROTAN N-4045 Versus Competitive Dispersants I. Introduction In order to evaluate the performance of OROTAN N-4045, Rohm and Haas s European Coatings Laboratory compared OROTAN N-4045 with two competitive polyacid dispersants in acrylic matt and silk paints. For each dispersant, a dispersant demand curve was generated by plotting Brookfield viscosity versus the level of dry dispersant on dry powders. Next, the minimum dispersant levels were determined. The matt paints were then formulated at two levels: 2x and 4x the minimum dispersant level. The gloss paint was formulated at 2x the minimum dispersant level. The paints were then tested for initial viscosity, viscosity variation with time, contrast ratio, gloss, scrub resistance and drying time. A summary of the key observations follows.

2 II. Evaluation in Matt Paint (77% PVC/23% Volume Solids) A. Dispersant Demand OROTAN N-4045 demonstrated similar efficiency as Competitor 1 and both were more efficient than Competitor 2 in the matt paint that was evaluated. B. Drying time (300 µ application) Dispersant at 2x the minimum level Thickener OROTAN N-4045 Competitor 1 Competitor 2 HEC 23 min 20 min 19 min ACRYSOL DR-73 ER 22 min 21 min 20 min Dispersant at 4x the minimum level Thickener OROTAN N-4045 Competitor 1 Competitor 2 HEC 22 min 21 min 22 min ACRYSOL DR-73 ER 20 min 20 min 19 min The paints formulated with OROTAN N-4045 had drying times similar to those of the two competitive polyacid dispersants.

3 C. Scrub Resistance (number of cycles to reach 50% loss) The matt paints formulated with OROTAN N-4045 provided a similar level of scrub resistance as paints formulated with the two competitive polyacid dispersants. III. Evaluation in Silk Paint (35% PVC/26% Volume Solids) A. Dispersant Demand In the silk paint, the efficiency of OROTAN N-4045 is similar to that of Competitor 1, however both OROTAN N and Competitor 1 are more efficient than Competitor 2.

4 B. Gloss Measurement Cellulosic thickened paints Gloss 20 Gloss 60 Gloss 85 OROTAN N Competitor Competitor ACRYSOL DR-73 ER thickened paints Gloss 20 Gloss 60 Gloss 85 OROTAN N Competitor Competitor Gloss level was comparable among the silk paints formulated with OROTAN N-4045 and Competitor 1, however, both provided higher gloss levels than the silk paints formulated with Competitor 2. C. Viscosity Stability on Heat Ageing Paints formulated with all three dispersants demonstrated similar viscosity stability. Safe Handling Information Rohm and Haas Company maintains comprehensive and up-to-date material safety data sheets (MSDS) on all of its products. These sheets contain pertinent information that you may need to protect your employees and customers against any known health or safety hazards associated with our products. Rohm and Haas Company recommends that you obtain copies of our material safety data sheets from your local Rohm and Haas representative on each of our products prior to its use in your facilities. We also suggest that you contact your supplier of other materials recommended for use with our products for appropriate health and safety precautions prior to their use.

5 ACRYSOL, AVANSE, DRYCRYL, ELASTENE, FASTRACK, KATHON, LIPACRYL, MAINCOTE, OROTAN, PARALOID, PRIMAL, QUICK SET, ROPAQUE, ROVACE and SKANE are trademarks of Rohm and Haas Company, or of its subsidiaries or affiliates. These suggestions and data are based on information we believe to be reliable. They are offered in good faith, but without guarantee, as conditions and methods of use of our products are beyond our control. We recommend that the prospective user determines the suitability of our materials and suggestions before adopting them on a commercial scale. Suggestions for uses of our products or the inclusion of descriptive material from patents and the citation of specific patents in this publication should not be understood as recommending the use of our products in violation of any patent or as permission or license to use any patents of the Rohm and Haas Company. For further details, please contact your local Account Manager or local Business Representative. Rohm and Haas, 2007 All rights reserved. August 2005