Synexil Osakryl SYNTHOS DISPERSIONS MAIN AREAS OF ACTI VITY DISPERSIONS SALES MARKETS

Transcription

1 OSA S20

2 Synexil Osakryl Synthos S.A. grew out of the companies Firma Chemiczna Dwory S.A. and Kaucuk a.s. SYNTHOS, the current name of the company (introduced in 2007), derives from a fusion of two words of Greek origin, synthesis (join) and orthos (proper, right). The name replicates the Company s mission which is to manufacture and supply its clients with chemical products for further processing, contributing to the development of each client s business. The name also reflects the nature of the Company s operations in chemical synthesis. SYNTHOS S.A. after acquisition of the INEOS Styrenics in August 2016, manages production plants in, Czech Republic, the Netherlands, and France. Oświęcim Sochaczew HEADQUARTER Breda Netherlands Wingles France Nowa Sarzyna Ribécourt France Kralupy Czech Republic Wola Krzysztoporska The activity of SYNTHOS S.A. concentrates on five main groups of products: synthetic rubbers, styrene plastics, specialist products (acrylic and vinyl dispersion, and latex and dispersion adhesives), plant protection products and liposomes. SYNTHOS S.A. is the largest European producer of synthetic rubbers and expandable polystyrenes (EPS). SYNTHOS S.A. makes sure that buyers are satisfied with the scope of raw materials, semifinished products and chemical products. The company focuses its activities on quality and efficient customer service, as well as on the innovative character of products, attractive prices, ecological safety of their technologies and products, and on occupational safety. This effort has been backed up by the implementation of a certified Integrated Quality, Environment and Work Safety Management System. In 2011, the company launched production of neodymiumcatalyzed butadiene rubber (NdBR) in the production plant in Czech Republic (Karlupy). High quality neodymiumcatalyzed butadiene rubber is used for mixture for production of advanced car and truck tires and various rubber technical products. In 2014 the Boryszew ERG S.A. Dispersion and Adhesive manufacturing unit was added to Synthos S.A. In August 2015, Synthos S.A. completed the construction of a modern SSBR rubber production plant. Synexil, Osakryl are market brands of water dispersions produced by Synthos S.A. Both groups include acrylic and styreneacrylic products as well as acrylic monomer copolymers with other monomers and dispersions based on vinyl acetate. Synthos aqueous dispersions portfolio satisfies the needs of coatings and building and construction industry for such applications as paints, plasters, primers, putties including decorative (stuccos), varnishes and coatings for wood, adhesives for various applications such as: for wood, paper& packaging and many others. Synthos pays special attention to the ecological aspect of these products. None of dispersions contain APEO emulsifiers (alkylphenol ethoxylates), solvents, hazardous plasticizers or other substances harmful to human health or the environment included in the REACH Candidate List of Substances of Very High Concern (SVHC). All our products undergo rigorous internal quality control based on an integrated ISO system into which additional parameters, important from our business partners point of view, can be included on the client s request. MAIN AREAS OF ACTI VITY Household chemistry Adhesives 6% 2% Glass fibres and textiles 2% Paints and coatings 34% Building & construction chemistry 56% SYNTHOS DISPERSIONS DISPERSIONS SALES MARKETS

3 OSA S20 OSAKRYL OSA S20 is a styreneacrylic dispersion recommended as binder for the production of interior and exterior paints, as well as protectivedecorative plasters and primers. Thanks to its properties, the binder may be used in silicone and silicate coatings. Universal styreneacrylic dispersion Osakryl OSA S20 in exterior paints Raw material % wt. Water 18,00 Calgon N 0,10 BK Giulini Attagel 50 0,30 BASF Cellosize HEC QP 300 0,15 Conducted tests showed that the Osakryl OSA S20 is freezethaw resistant dispersion. Borchi Gen AP 0,60 OMG Borchers Agitan 282 0,15 Munzing The method implemented consisted in carrying out multiple freezethaw cycles. During one cycle the product sample was kept in 40 C for 6 hours, then in +23 C for 18 hours. 10 such cycles were carried. After each cycle a viscosity test was performed. Tytanpol R001 5,00 ZCh Police Intalc 8CG 5,00 Paltentaler Minerals Intalc ,00 Paltentaler Minerals Minex S4 10,00 Sibelco Omyacarb 2VA 30,00 Omya Osakryl OSA S20 freezethaw resistant dispersion Osakryl OSA S20 18,00 Synthos Eastman EEH 0,40 Eastman Aquacer 539 2,00 Byk Rocima 551 0,10 Rocima 350 0, Brookfield viscosity [mpa s] Technical parameters: high wet scrubbing resistance good adhesion to substrate Product advantages: contains environmentally friendly emulsifiers (APEO free) solvent free Solids content, % Brookfield viscosity, mpa.s 7,58,5 The binders presented in the comparison have similar basic physical and chemical parameters. 3 cycle 4 cycle 5 cycle 6 cycle 7cycle 8 cycle 9 cycle 10 cycle Before freezing and after the test the coating was homogeneous. Only an increase in the dispersion s viscosity was observed. Dispersion with APEO emulsifier Osakryl OSA S20 Requirements Test method Viscosity [mpa s] PN EN ISO 2555 Viscosity after aging (28 days) [mpa s] PN EN ISO ,2 4,5 15 PN EN ISO 2813 Whiteness (C/20) 77,94 78,37 75 PNC81913:1998 p Yellowishness (C/2o) 2,69 2,64 PN EN ISO Quantitative covering at 99% opacity 279,7 265,5 Qualitative covering at 99% opacity III III III (white paint) PN C ,6 396,9 IV IV PN C PNC81913:1998 p <0.25 perfect match, <1.0 difference not visible to the naked eye Gloss determined at measurement angle 850 Wet scrubbing resistance 49±1 Colour difference, green paint, E (C/2o), without exposure standard 0, Colour difference, red paint, E (C/2o), without exposure standard 0,09 23±2 Tg, C ca Tg, C ca. 23 MFFT, C 23±2 Brookfield viscosity, mpa.s 2 cycle Qualitative covering at 99,5% opacity MFFT, C Mean particle size, nm Mean particle size, nm before 1 cycle freezing Quantitative covering at 99,5% opacity BASIC PARAMETERS The aim of this comparison is to evaluate the properties of an exterior paint after replacing the binder with an environmentally friendly (APEO free) dispersion. Paints test results good covering and colour resistance under various atmospheric conditions A comparison of exterior paints based on Osakryl OSA S20 dispersion and its market analouge containing an APEO emulsifier ph Manufacturer Osakryl OSA S20 allows to manufacture exterior paints with similar parameters to paints based on a binder containing APEO emulsifiers. The basic paint parameters, i.e. density, ph, gloss, whiteness, yellowishness, are comparable in both cases. When using the Osakryl OSA S20 dispersion for exterior paints, it may be required to make a correction in the amount of titanium dioxide in the formulation or the amount of white paste in the tinting system. A product made on the Synthos binder is characterised by higher stability of viscosity after aging. The wet scrubbing resistance of the paints is similar, formulations based on Osakryl OSA S20 may require a small correction of the hard fillers used.

4 Osakryl OSA S20 in acrylic plasters Osakryl OSA S20 in silicone plasters Raw material % wt. Manufacturer Water 9,65 Calgon N 0,10 BK Giulini Laviothix P 100 0,10 Laviosa Tylose MH YP2 0,20 SE Tylose Securon 98/2 0,20 Cognis Agitan 282 0,15 Munzing Tytanpol R001 1,01 ZCh Police Talk ASE 60 10,06 Paltentaler Minerals Intalc 8CG 2,01 Paltentaler Minerals Dolomit P60 10,16 ZSMiCh Piotrowice Osakryl OSA S20 12,07 Synthos Eastman EEH 0,25 Eastman Arbocel B 400 0,50 Rettenmaier Fluocast 2,01 Rettenmaier Wukonil HB 300 0,80 Omya Rocima 551 0,15 Rocima 350 0,30 Piasek 0,20,5 8,04 KP Osiecznica Carolith 0,51,0 21,12 Omya Carolith 1,0 1,5 21,12 Omya A comparison of acrylic plasters based on Osakryl OSA S20 dispersion and its market analouge containing an APEO emulsifier. The aim of this comparison is to evaluate the properties of an acrylic plaster after replacing the binder with an environmentally friendly (APEO free) dispersion. The binders presented in the comparison have similar basic physical and chemical parameters. Binder was replaced in the ratio 1:1. Raw material % wt. Manufacturer Water 11,0 Calgon N 0,10 BK Giullini Arbocel P 4000 S 0,20 Rettenmaier Laviothix P100 0,10 Laviosa Tego Dispers 747W 0,20 Evonik Tego Foamex 26 0,15 Evonik Kronos ,00 Kronos Talk ASE 60 10,00 Paltentaler Minerals Arbocel UFC 8 M 1,00 Rettenmaier Sibelite M ,80 Quartzwerke Tego Phobe ,00 Evonik Osakryl OSA S20 12,50 Synthos Eastman EEH 0,35 Eastman Arbocel B 400 1,00 Rettenmaier Rocima 551 0,40 Dow Chemicals Tego Phobe ,00 Evonik Glass Bubbles S60HS 2,00 3M Carolith 0,205 mm 8,00 Omya Carolith 0,51,0 mm 20,00 Omya Carolith 1,0 1,5 mm 20,00 Omya Plasters test results Plaster test results Adhesion to concrete [MPa] Water absorption, w [kg/m 2 h 0,5 ] Diffusion equivalent air thickness, S d [m] Water vapour transmission rate, V [g/m 2 d] Dispersion with APEO emulsifier Osakryl OSA S20 Requirements Test method 1,79 ± 0,1 1,83 0,3 PNEN 1542:2000 0,0403 0,0892 Class W1 (high) w> 0,5 Class W2 (medium) 0,1 < w 0,5 Class W3 (low) w 0,1 0,49 0,47 Class V1 (high) V > 150; S d < 0,14 Class V2 (medium) 15 < V 150; 0,14 S d < 1,4 47,65 49,02 Class V3 (low) V 15; S d 1,4 PNEN 10623:2008 PNB10106:1997 Adhesion to concrete [MPa] Water absorption, w [kg/m 2 h 0,5 ] Diffusion equivalent air thickness, S d [m] Water vapour transmission rate, V [g/m 2 d] Silicone plaster Requirements Test method 1,0± 0,1 0,3 PNEN 1542:2000 0,022 Class W1 (high) w> 0,5 Class W2 (medium) 0,1 < w 0,5 Class W3 (low) w 0,1 0,30 Class V1 (high) V > 150; S d < 0,14 Class V2 (medium) 15 < V 150; 0,14 S d < 1,4 76,71 Class V3 (low) V 15; S d 1,4 PNEN 10623:2008 PNB10106:1997 Osakryl OSA S20 allows to manufacture acrylic plasters with similar parameters to those based on a binder containing APEO emulsifiers. The information given herein is based on trials carried out by SYNTHOS S.A. according to current standards and the present state of our knowledge. They do not guarantee certain properties of the products nor their suitability for a specific purpose. Users are advised to make their own tests to determine the safety and suitability of each such material or combination of materials for their own purpose.

5 Contact and information Our cooperation with clients in the area of water dispersions mostly focuses on building longterm and partner relationships. Therefore, we provide all necessary technical assistance together with the preparation of formulations of products, taking into account the individual requirements of a specific client. TECHNICAL SERVICE Tel.: dsts@synthosgroup.com SALES DEPARTMENT Tel.: ds@synthosgroup.com SYNTHOS S.A. ul. Chemików Oświęcim, POLAND tel fax VAT EU PL