Museum Microclimates Copenhagen Conference November Marion F. Mecklenburg Smithsonian Museum Conservation Institute

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Museum Microclimates Copenhagen Conference 19-23 November 2007 Marion F. Mecklenburg Smithsonian Museum Conservation Institute

My thanks to all of the organizers for this conference. My congratulations to all of the authors for the papers and posters presented. You have addressed a lot of the issues I have wanted to look into at myself and I thank you for that.

It is everyone s hope that we all come away from this conference with new insights and understanding.

There are several main themes that seem to be reoccurring: Passive environmental control of buildings and controlling the environment in historic buildings. Monitoring the environment of buildings and related spaces and exhibition cases. The effects of dust and pollution. The effects of light and biological considerations. The effects of environmental variation on the. structural stability of collections.

The objectives are: Preservation of the collections Preservation of the buildings Enhanced visitor experience Reduction in energy costs

Passive environmental control of buildings and controlling the environment in historic buildings These are important areas because: Not every community can support the high cost of a HVAC retrofit even when it is possible. Energy cost are getting out of hand. When use inappropriately, induced moisture from HVAC systems can destroy buildings. The use of natural buffering and thermal mass can be very effective.

Sometimes however we lose sight of the effective management of existing HVAC systems. We can use passive control recommendations to our benefit even in buildings with HVAC systems. Papers in this conference discussed thermal inertia (mass) and buffered environments that help stabilize the environment. We can make these concepts work for even modern buildings.

In 2004 the Smithsonian adopted new environmental guidelines. Former Environmental Recommendations Of 50% RH +/- 5% RH 21 o C +/- 1 o C New Environmental Recommendations Of 45% RH +/- 8% RH 21 o C +/- 2 o C

Some of the energy conservation measures at the SI Blue Taking advantage of passive behavior HVAC - running smaller/less boilers in the summer HVAC - secured/setback air handling equipment during unoccupied hours HVAC - raised chilled water supply set point; lowered boiler supply set point HVAC - secured outside air and exhaust during unoccupied hours HVAC - raised space temperature set point Hot water - lowered supply temperature; secured during unoccupied hours Power- secured non-essential pumps where appropriate Lighting dimmed, secured, disconnected, removed exterior/interior lighting Lighting rescheduled to shut off during unoccupied hours Lighting installation of LED exit signs and occupancy sensors.

The energy budget for the SI in FY 2006 was $32,800,000 US (over 600 buildings) However by making even modest adjustments * We saved $2.7 million in the last half of FY 2006, and about $1.5 million in the first quarter of FY 2007, mainly through changes in HVAC operations. The temperature and humidity guidelines help us because they are credible and because they are broad and flexible enough to accommodate energy-saving strategies. David Hauk, Chief Energy Management Branch OFEO This is about a 17% savings on an annual basis, about $6,000,000 US.

The effects of environmental variation on the collections The big hole in much of our understanding revolves around the effects of the environment on structural damage. For example, we constantly refer to the effects of temperature and relative humidity on the structural stability of collections. What s the difference?

Historically there has been considerable confusion and controversy with regards to determining the correct temperature and relative humidity settings for museums and galleries. Few were able to say with any certainty what caused damages in any specific object. There have certainly been anecdotal reports but rarely were specific details available. For example, let s look at a few damaged objects.

20 th Century musical instrument with cracked varnish on wood substrate.

George Parker, Untitled, (Lower Ausable Lake at Indian Head), American, 1911, 48in. x 35.5in.. (Photo by James Hamm and courtesy of the Adirondack Museum in Blue Mountain Lake, N.Y.)

19th century American landscape, oil on canvas.

20th century American abstract, oil and acrylic on canvas. (Photo by James Hamm and courtesy of the owner)

All of the objects just seen were damaged by exposure to low temperatures (sub zero) and RH played no role at all. The reason these object were damaged by low temperature is because all oil, alkyd and acrylic paints have low glass transition temperatures. If the ambient temperature falls enough below the glass transition temperature, the paint layers can crack. Let s try again

Detail, 20th century English Abstract, oil on canvas. (Photograph courtesy of Richard Saltoun and taken by Steve Gayler)

Detail, 20th Century Italian, Photograph courtesy of Matteo Doria Rossi

The 1st painting shown was damaged by rolling and neither temperature or relative humidity played any role in the damage. The reason the damages are so extensive with interlayer cleavage was that zinc oxide was mixed with the other pigments in the oil. Zinc is notorious for cracking and delaminating. (Research on the mechanical properties of artists paints at the SI, MCI)

We certainly need to be able to accurately assess the effects to temperature and RH Independently.

What we need is a Better estimate of impact Agnes Brokerhof

Taking the next step Two case studies.

Warm Feet and Cold Art: Is This the Solution? Polychrome Wooden Ecclesiastical ArtClimate and Dimensional Change. Tone M. Olstad and Annika Haugen This paper and those like it are critically important since they address very real problems. Let s try to answer some of those questions.

Figure 1. The macro area is 115 mm. It is divided into micro areas. Each micro area is 1 mm and is marked by drilled holes (white dots) in the paint. Two parallel lines of 57 and 58 pairs of holes were drilled. A micro area is the distance between the lines which are formed between the middle of two pairs of drilled holes (white dots). One micro area is the distance between the two black arrows on the figure.

At the end of their paper Tone M. Olstad and Annika Haugen asked the following questions. future work In the future the following questions need to be answered: - Is damage in the paint layer related to micro movements in the wood caused by fluctuations in climate? - Are visible damages in the paint layers related to intermittent heating? - Is it significant if the values of RH or T rise or fall?

Measuring deformation is important when discussing the effects of RH on Wooden Polychrome Art. But deformation alone will not be sufficient to determine the damage mechanism or the range of RH causing the damage. It is necessary to know the mechanical properties of the materials and have a method to model the internal stresses developed by deformation. For example.

0.607 mm shrinkage Longitudinal direction 50% RH to 30% RH Radial direction

Longitudinal direction 0.607 mm swelling 50% RH to 70% RH Radial direction

Note: No stress even though deformed. Longitudinal direction 50% RH to 70% RH Radial direction

Longitudinal direction European poplar gesso layer two layers of oil paint RH change from 50% to 30% Full equilibrium Maximum deformation 1.198 mm Radial direction

Longitudinal direction Max Stress = 1.986 MPa Radial direction Note: maximum stress is perpendicular to maximum MPa deformation and in the direction of least deformation.

Gesso layer, maximum stress in the longitudinal direction is 1.986 MPa MPa

It is now possible to compare actual material test data to the computer model results.

Gesso 10A 6 15.6% RH, 23.6 C Stress (MPa) 5 71% PVC with W&H hide glue 48.7% RH, 23.1 C 4 3 2 84.1% RH, 23.2 C 1 0 0 0.005 0.01 0.015 Strain 0.02 0.025 0.03

Gesso 0 Free Swelling Strains Colletta 9B -0.005 9A -0.01 10A 9A. Flake, PVC= 67% 9B. Flake, PVC= 67% 10A. W&H, PVC= 71% 10B. W&H, PVC= 71% -0.015-0.02 0 20 Restrained tests of different gesseos 2.5 10A Stress (MPa) 2 10B 11A 1.5 11B 1 12A 0.5 12B 0 0 20 40 60 Relative Humidity (%) 80 100 40 60 80 Relative humidity (%) 10B 100

Fra Lippo Lippi and workshop, Florentine, c. 14061469, The Nativity, probably c 1445, oil and tempera (?) on panel, 9 1/8 in. x 21 ¾ in. (23.2 x 55.3 cm), Samuel H. Kress Collection, 1939.1.279. (courtesy of the National Gallery of Art, Washington, D.C.)

Wood longitudinal direction All of the cracks originated in the gesso layer and are perpendicular To the grain of the wood. The environmental ranges in RH had to have exceeded 70% to 20% for this damage to occur. The wood is acting as a restraint to the gesso layer.

We keep referring to the adverse effects of fluctuating RH. What is the difference between the set point and allowable fluctuations?

RELATIVE HUMIDITY STABILITY ZONES Focus of this Biological attack talk Physical properties Deliquescent salts Ceramics Building condensation Bronze disease Cellulose Protein Bone Pyrite oxidation Unstable glass Mineral hydrates 0 Caution Avoid 10 20 30 40 50 60 Relative Humidity, % 70 80 90 100

But as David Erhardt said we used the yield point of materials to determine The allowable fluctuation.

The stress strain test: Stress is force divided by the cross-sectional area of the sample and Strain is the change in the sample length divided by it original length. 2.5 year long test of hide glue at 50% RH and 22C 50 The modulus or stiffness Stress (MPa) (or force) 40 Elastic (reversible) region Breaking point 30 20 Initial yield point at 0.005 10 plastic (permanent deformation) region 0 0 0.01 0.02 0.03 Strain (or elongation) 0.04 0.05

It has been suggested in some talks that any RH fluctuation causes damage, this is not necessarily true.

P 50 mm 25 mm (typ) a (crack length) 255 mm (typ) ASTM Standard Specimen P/2 P/2 Cyclic Fatigue Results of English Lime Wood. Cycle from P1 to P2 at 3 Hertz Crack tip length calculated by Crack Tip Opening Displacement (CTOD) and periodically checked using a microscope.

P 25 mm (typ) 50 mm Load range 35 N to 343 N @ 3 hertz. Change in crack length ~0.10mm a (crack length) 255 mm (typ) ASTM Standard Specimen P/2 P/2 M63B English Lime - Tangential (3-Pt. Bend) Crack Length (mm) 13.7 13.68 13.66 13.64 13.62 13.6 13.58 0 5000 10000 Cycles 15000

P 25 mm (typ) 50 mm Load range 31.6 N to 302 N @ 3 hertz. Change in crack length ~0.03 mm a (crack length) 255 mm (typ) ASTM Standard Specimen P/2 P/2 Crack Length (mm) M63D English Lime Tangential (3-Pt. Bend) 12.81 12.8 12.79 12.78 12.77 0 5000 10000 15000 Cycles

P 25 mm (typ) 50 mm Load range 29 N to 285 N @ 3 hertz. No change in crack length a (crack length) 255 mm (typ) ASTM Standard Specimen P/2 P/2 M63E English Lime - Tangential (3-Pt. Bend) Crack Length (mm) 13.5 13.4 13.3 13.2 13.1 13 0 5000 10000 Cycles 15000 20000

Cyclic Crack Thresholds in English Lime Load at Crack Initiation (N) 1000 Computer Model, Loading from Constant Failure Stress 800 600 Experimental, Tangential Grain Direction Loads FromTheoretical Fracture Toughness, K 400 200 0 0 5 10 15 20 25 30 35 Crack Length (mm) 40 45 There is a threshold for fatigue below which cracks do not continue to grow. 50

English Lime - Tangential Stress levels at crack growth initiation. 6 Stress (MPa) 5 4 3 2 1 Humidity induced deformations must be in this range. 0 0.000 1.000 2.000 Strain (%) 3.000

Woods can sustain considerable cyclic fatigue as well as large changes in RH when restrained. Restrained cycling of wood samples. (tangential direction) 6 Stress (MPa) 5 4 Am Mahagony 3 Cotton Wood White Oak 2 1 0 0 20 40 60 Relative Humidity (% ) 80 100

Where do we go next? There are a lot of questions that could be answered by including mechanics into the discussions. If we can establish safe RH and RH ranges for objects we can: Target case designs and know when they are really needed. Know what heating systems will work best for churches. Develop an accurate assessment of the effectiveness of both active and passive environmental controls. Incorporate energy costs into the equation.

We have a large data base of information on the mechanical and dimensional properties of cultural materials and have developed modeling protocols to assist researchers who might be interested. Contact information: Marion F. Mecklenburg mecklenburgm@si.edu