Characterisation of Photovoltaic Materials and Cells

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Standard Measurement Services and Prices Reference 1 Large area, 0.3-sun bias spectral response Wavelength measurement range: 300 1200 nm; Beam power monitoring and compensation; Measurement cell size: Up to 160 x 160 mm 2 ; Repeatability: Within 0.4% in integrated I sc ; Probe beam spatial uniformity: 5%; Bias light spatial uniformity: 2%; Stage temperature control range: 20-60 C (±0.5 C); Price as of 1 Nov 2018 (US Dollars) IEC 60904-8 1 st cell: $300; 2 nd cell onwards: $180 We welcome customers to have cells preconditioned by light soaking at SERIS at a low cost (see item 5). 2 Determination of linearity of spectral response with respect to irradiance Spectral response at 1%, 5%, 10%, 30%, 100% of 1-sun bias; Specifications of spectral response analyser as per Item 1. IEC 60904-8 IEC 60904-10 1 st cell: $500; 2 nd cell onwards: $450 3 Xenon lamp based I-V characterization under AM1.5G with spectral mismatch correction Class AAA steady-state solar simulator; Measurement cell size: Typically up to 160 x 160 mm 2 (please enquire about other sizes); 0.3-sun bias spectral response (See Item 1); Spectral match to AM1.5G spectrum: ±12.5%; Spatial non-uniformity: 2%; Stage temperature control range: 15-70 C (±0.5 C); Area measurement included (refer to Item 6); IEC 60904-1 IEC 60904-7 IEC 60904-9 1 st cell: $350; 2 nd cell onwards: - $210 (with SR for every cell) or - $80 (SR only for 1 st cell, spectral mismatch correction based on 1 st cell) We welcome customers to have cells preconditioned by light soaking at SERIS at a low cost (see item 5). 1

Standard Measurement Services and Prices Reference 4 5 LED light based I-V characterization under AM1.5G or arbitrary spectrum conditions with spectral mismatch correction Plasma lamp based light soaking Class AAA steady-state solar simulator; 0.3-sun bias spectral response (See Item 1); Set of 21 LED wavelengths tunable to compose arbitrary spectra as defined by customer; Measurement cell size: Up to 160 x 160 mm 2 ; Spatial non-uniformity: 2%; Stage temperature control range: 20-60 C (±0.5 C); Area measurement included (refer to Item 6); We welcome customized requests for measurement under more than one spectrum. Total illumination area: 70 x 70 cm 2 ; Acceptable sample height: 10 mm; Spectrum: IEC Class A; Nominal light intensity: 1000 W/m 2 ±2%; Irradiance homogeneity: ±5%; Temporal instability: ±5% over 24 hours; Stage temperature control range: 25-60 C (±2 C); IEC 60904-1 IEC 60904-7 IEC 60904-9 Price as of 1 Nov 2018 (US Dollars) 1st cell: $350; 2nd cell onwards: - $210 (with SR for every cell) or - $80 (SR only for 1st cell, spectral mismatch correction based on 1st cell) $300 per batch (up to 16 x 6 wafers) for 24 hours LED based light soaking also available, please inquire. We welcome customized requests for light-induced degradation studies. 6 Area measurement of cell High-precision topology measurement tool. Measuring range: (i) 300 mm (x-axis), (ii) 200 mm (y-axis), (iii) 200 mm (z-axis); Accuracy (@20 C ± 1 C): 3 + 4L/1000 m (xy-axis) $120 per sample 2

Standard Measurement Services and Prices Reference 7 8 9 Determination of temperature coefficient - T dependent I-V - With spectral mismatch correction Single point, solar cell active area external quantum efficiency / total reflectance Total reflectance / transmittance Measured using Xenon lamp based I-V tester (Item 3); Temperature dependent I-V characterization (at 15, 25, 30, 40, 50, 60 C); Spectral mismatch correction using 0.3-sun biased spectral response (Item 1) at Option (i) 25, or (ii) respective temperatures of I-V characterization. Bentham/IVT PVE300 spectral response system; Measurement of external quantum efficiency (EQE) and total reflectance (R) at small localized area; Measurement wavelength range: 300-1700 nm; Motorized X-Y stage with 200 x 200 mm travel; Small typical beam size ~ 1 x 9 mm; For solar cell metal finger pitch > 1.5 mm, beam lies completely within active area of solar cell between fingers; Excellent repeatability of < 0.2% in integrated I sc. Agilent Cary 7000 UMS; Measurement wavelength range: 200-2500 nm; White reflectance standard; Automatic wavelength calibration; Wavelength accuracy: (i) UV-VIS (200-900nm): ± 0.08 nm (ii) NIR (760-2500nm): ± 0.4 nm Price as of 1 Nov 2018 (US Dollars) $700 per sample for Option (i) $1400 per sample for Option (ii) 1st cell: $220 (EQE or R only), $300 (EQE and R); 2nd cell onwards: $100 (EQE or R only), $150 (EQE and R) Mapping option at $50 per additional point (EQE or R), $80 (EQE and R) 1st sample: $150; 2nd sample onwards: $80 3

10 11 12 13 14 Angular resolved reflectance PCD point measurement / Corona voltage measurement / Surface photovoltage (SPV) sheet resistance Four point probe Agilent Cary 7000 UMS; Measurement wavelength range: 200-2500 nm; Automatic wavelength calibration; Wavelength accuracy: (i) UV-VIS (200-900nm): ± 0.08 nm (ii) NIR (760-2500nm): ± 0.4 nm Semilab PV-2000; Measures injection-dependent differential lifetime in Si by measuring the rate of change in carrier density with step changes in illumination conditions. Semilab PV-2000; Employs incremental corona charging of dielectrics and subsequent measuring of the surface potential with a vibrating capacitive electrode (Kelvin probe), to achieve non-contact /measurement of (i) Surface barrier height (V sb ) (range: -800 to 800 mv, resolution: 1 mv), (ii) Flat band voltage (V fb ) (range: -60 to 60 V, resolution: 0.001 V), (iii) Dielectric total charge (Q tot ) (range: 5 x 10 9 to 5 x 10 13 cm -2, resolution: 5 x 10 9 /cm 2 ) (iv) Interface trap density (D it ) (10 10 to 10 13 cm -2, resolution: 10 10 cm -2 ) Suitable for square wafers up to 156 x 156 mm 2. Semilab PV-2000; SPV-based technique for of sheet resistance. AIT Instruments CMT-SR2000-PV with Jandel probes; Allows / checking of spatial uniformity of square wafers up to 160 mm x 160 mm and round wafers up to 230 mm diameter, with maximum thickness of 6mm; Measuring range: 1 mω/sq 2 MΩ/sq (sheet resistance) or 10.0 mω.cm - 200.0 kω.cm (resistivity) 4

15 16 17 Fourier transform infrared (FTIR) Raman 3D profile microscope 18 Stylus profiling Thermo Scientific Nicolet is50 FT-IR; FTIR over spectral range of 400 4000 cm -1 ; Total / diffused reflectance and transmittance using integrating sphere with MCT detector accessory; Surface analysis of materials using single bounce Ge attenuated total reflection (ATR) accessory; High wavenumber resolution of ~0.1 cm -1. Renishaw invia Reflex; 514 nm Ar ion excitation laser (50 mw); Measures Raman spectrum from 100 cm -1 to 4000 cm -1 ; Raman peak positions allow material and phase identification (e.g. amorphous vs crystalline silicon); Raman relative peak intensities and peak shifts provide further information on material and strain; Research grade Leica microscope (5x, 20x, 50x objectives) with binocular head and color video camera. Zeta Instruments Zeta-300; Non-contact optical profiler; High sensitivity for low reflectance surfaces such as anti-reflection coated, rough surfaces; Optically image large areas and provide accurate 3D topography information; Enables measurement of roughness parameters, lateral dimensions, step heights, wall angles, etc; Z resolution: <10 nm; 5x, 20x, 50x, 100x, 150x objective; Motorized XY stage with 200 x 200 mm travel and automated Z stage. Veeco Dektak 150 Surface Profiler; Measures surface steps, variation and roughness as a function of position by monitoring the displacement of a stylus moved in contact on the sample surface; Vertical resolution: 1Å max; Vertical range: 524 mm; Scan length range: 55 mm 5

19 Scanning electron microscope (SEM) Zeiss Auriga field emission scanning electron microscope (FESEM); Characterization of sample's surface topography, structure and electrical properties; Schottky type field emission system; Resolution: 1.0 nm at 15 kv and 1.9 nm at 1 kv; Accelerating voltage: 100V to 30 kv ; Beam current: up to 20 na 20 21 22 23 24 Electron beam induced current (SEM-EBIC) Electron backscattered diffraction (SEM- EBSD) Electron dispersive X-ray (SEM-EDX) Electrochemical capacitance voltage (ECV) profiling Solar cell metal line and contact resistance measurement Kammrath & Weiss EBIC capability; Extension to Zeiss Auriga FESEM; Allows study of electronic quality of p-n junctions with SEM resolution. Bruker e-flash1000 attachment to Zeiss Auriga FESEM; Mapping of crystal orientation of crystalline semiconductor films; Native resolution: 640 x 480 pixels Oxford Instruments, Aztec Energy Advancd (plus IE350) with X-Max N 80; Resolution better than 127 ev with 80mm 2 Silicon Drift Detector (SDD) (liquid N 2 free, Peltier cooling); Elemental detection and from beryllium (Be) to californium (Cf). WEP Wafer Profiler CPV21; Measurement of concentration of active dopants in semiconductors; E.g. Bulk doping density or doping profile of Si, Ge, GaAs, InP, GaN, etc; Concentration resolution: < 10 12 cm -3 to > 10 21 cm -3 ; Depth resolution (depending on material): up to 1 nm Custom built tool Measurement of metal-semiconductor contact resistance via transmission line method (TLM); Measurement of metallization grid resistance via busbar-to-busbar resistance and line resistance techniques. 6

25 26 27 28 29 Photoconductance based Si wafer lifetime measurement Temperature & injection dependent lifetime PL imaging of raw Si wafers PL/EL of cells with R s and efficiency maps Time-resolved fluorescence Sinton Instruments WCT-120; Measures effective lifetime of Si (e.g. in quasi-steady state or transient modes); Measures implied V oc and emitter saturation current density J 0 ; Sensor area: 40 mm diameter; Lifetime measurement range: 1 s to 10 ms; Typical calibrated injection range: 10 13 to 10 16 cm -3 ; Sample size diameter: 40 to 210 mm Sinton Instruments WCT-120TS with temperature controlled chuck; Similar to Item 25 but with temperature range from room temperature to 200 C. BT Imaging LIS-R2; PL based method of defect distribution (e.g. handling marks, material defects, process quality & homogeneity, iron concentration, etc) High power 915 nm infrared laser with illumination intensity up to 3.6 suns Si back illuminated deep depletion CCD camera (high sensitivity over wavelength 800 to 1100 nm) Image size: up to 1024 x 1024 pixels; Wafer size: up to 160 x 160 mm 2 BT Imaging LIS-R2; Combination of luminescence images at different operating points of a finished solar cell to construct maps of R s and efficiency Advanced solar cell analysis options are available (please enquire). PicoQuant FluoTime 300; Measures (1) fluorescence/photoluminescence spectrum, and (2) fluorescence/photoluminescence time decay of luminescence samples. Time-correlated single photon counting (TCSPC) or multi-channel scaling (MCS) is employed. 7