VCSELs for gas sensing

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1 Long-wavelength VCSELs for gas sensing A. Sirbu*, A.Caliman *, V.Iakovlev ", A. Mereuta *, G. Suruceanu " and E. Kapon *" * Laboratory of Physics of Nanostructures, EPFL, 1015 Lausanne, Switzerland " BeamExpress, 1015 Lausanne, Switzerland 1

2 Outline VCSEL fabrication approach; Results at 1550 nm; Results at 2000 nm; CO2 sensing results; Summary. 2

3 Tunable laser diode spectroscopy, TLDS with long- wavelength VCSELs in the nm range Gas Methane Ammonia Hydrogen sulphide Carbon Monoxide Carbon Dioxide Water Ethylene Hydrochloride Symbol CH 4 NH 3 H2S CO CO 2 H 2 O C 2 H 4 HCl Absorption line, nm , , , gas-cell sensing Typical VCSEL RIN= -130 db/hz corresponds to the shot noise of the photo-detector at ~3 µa that corresponds to 3 µw incident power; 1 mw SM output for optical path length of the order of 10 cm at specified wavelengths is OK; A cost-effective technology for building a wavelength inventory is important for large-scale applications. 3

4 4 regions on the wafer with different emission wavelengths Top mirror Cav.Eng. layer A InP active Cav.Eng. Layer B Bottom mirror - Emission at 1550 nm, 1560 nm, 1570 nm, 1580 nm - Regions with different output coupling: 20 and 17 pairs in the top DBR 4

5 10 4 Photoluminescence spectra of InAlGaAs quantum wells at different temperatures Off-set max Off-set min C step Emission wavelength: nm Wavelength, nm Gain medium: InAlGaAs 5 QWs, 1.1% compressive strain, grown by LP MOCVD 5

6 Overview of VCSELs characteristics (20 pairs top DBR) Voltage, V l nm l nm l 3 l nm 1580 nm LIV, 20 C Current, ma Similar LIV characteristics for different wavelengths Power, mw Threshold Current, ma Maximal power, mw nm 1563 nm 1571 nm 1580 nm 1554 nm 1563 nm 1571 nm 1580 nm Temperature, C Ith and Pmax variations with temperature 6

7 Spectral characteristics at 1560 nm Spectra at 2 mw output 10 db/div 3 ma 7 ma 11 ma 15 ma 19 ma 20 C Voltage, V 20 C 40 C 60 C 80 C Wavelength, nm Wavelength, nm Single-mode emission in the full operation range; At low currents optical guiding is due to lateral refractive index variation, while at higher currents is due thermal lens; Wavelength tuning: 0.4 nm/ma; 0.15 nm/ºc 7

8 Impact of output coupling pairs pairs Power, mw Current, ma 0 C P max I th DP/DI 20 pairs 6.8 mw 3.5 ma pairs 8 mw 5 ma

9 Wavelength inventory SM operation with SMSR more than 40 db 60 db/div nm/ma; 0.1 nm/ C 20 C 40 C 60 C '558 1'562 1'566 1'570 1'574 Wavelength, nm 9

10 Wavelength tuning LIV and spectral characteristics of 7 mm tj diameter device 0 C 15nm 37 ma 10 db/div 15 ma 25 ma 5 ma Wavelength, nm 15 nm tuning 10

11 1550 nm far-field field and line-width Far-field and line-width measurements performed at 2 mw output, RT FWHM=9 Frequency, MHz Lorentzian line-shape; n = 4.5 MHz Self-homodine line-width measurements performed by M.Grossenbacher, ED EPFL 11

12 Wavelength selection in the 2000 nm band 15 C V. Iakovlev, Internal report 12

13 Wavelength tuning Wavelength, nm Single mode emission in the 4-18 ma current range A. Mereuta et al. PTL 2008, IPRM-2008 Wavelength tuning range ~ 5 nm Wavelength tuning rates: λ/ I ~ 0.31 nm/ma / T ~ 0.14 nm/ C 13

14 CO 2 detection with LPN/BX VCSEL f 2f 2f 8 C 2f diode3248 wafer l070502b 1st DC 1st DC 1st DC 1st DC Idc [ma] V.Iakovlev, Internal report Dashed lines ordinary room air Solid lines 10 mbar CO2 Optical path length - 10 cm 14

15 Two-species detection: CO 2 and H 2 O CO 2 H 2 O CO 2 15 cm CO 2 H 2 O V. Iakovlev, Internal report 15

16 Summary 1.5 mm VCSELs are produced with a broad range of wavelength inventory on the same wafer of 40 nm, high SM output power of C and C with line-width of 4.5 MHz and 15 nm of tuning range with current; Capability of fabrication of 2 mm VCSELs with 0.5 mw SM output; 2003-nm VCSELs detection of carbon dioxide (CO2) and water (H2O) molecules in air is demonstrated. 16

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