NEW SUSTAINABLE CHEMISTRY

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NEW SUSTAINABLE CHEMISTRY Bicomponent spunbond nonwovens Thierry LE BLAN, TECHNICAL MANAGER CETI 1

THE «MAGIC BOX» Key Words Polymers :Advantage Technology : Simple Product : Unique 2

POLYMERS PLA: Enviromentally Friendly Sustainable.. Biopolymer Etc 3

POLYMER FUNCTIONALITY Materials List: Ingeo Grade 6202D 6752D 6302D 6100HP 6252D 6362D RV 3.0-3.2 3.2-3.4 2.9-3.1 3.0-3.2 2.4-2.6 2.3-2.7 %D 1.5-2.5 3.7-4.6 9.5-10.2 0-0.5 1.2-1.6 10.5-13.5 4

WELCOME TO THE BICO-WORLD PLA PET PE PP PA6 PBT 5

BICOMPONENT FIBERS In the Bicomponent world, we look at the polymers in a different way. We look at what one polymer brings to the table when combine with another polymer to make a fiber. We look for something different, unique; an advantage over the rest either in cost, processability or functionality. 6

ROUND SIDE BY SIDE 7

TRILOBAL SIDE BY SIDE 8

TIP TRILOBAL 9

HOLLOW 10

ECCENTRIC CORE 11

MIX SHAPES 12

THE «MAGIC BOX» Key Words Polymers :Advantage Technology : Simple Product : Unique 13

NONWOVENS TECHNOLOGIES NonWoven Fabrics: Fabrics which are neither woven nor Knitted] Carding (staple fibers) Air Lay (staple fibers) Spun Laid /Spunbond (filaments) Melt blow (filaments) Others 14

SPUNLAID (SPUNBOND) PROCESS Fibers are spun and then directly dispersed into a web. This technique leads to faster belt speeds, and cheaper costs. Simple process: Directly from the polymer(s) into a fabric. Spunlaid (as well as carded) nonwovens would have no mechanical strength by themselves, without the bonding (mechanical, chemical or thermal) step. 15

TRADITIONAL SB => FLAT MATERIAL Usage in Diaper, Hygiene and Medical applications 16

BICOMPONENT SPUNBOND PROCESS Polymer Hopper A C Extruder Pump Filte r Pack Spinbeam Quench Air B Forming Belt Height Adjustable Aspirator Compaction Roll Winder Tension Roll Guide Roll Calender (or Needle, Hydro, Chemical, etc.) 17

MICRO-DENIER (SEGMENT PIE) Uses: Wipes Absorbants Filtration and Other highsurface area apps Polymers:Mostly PET/PA6 18

MICRO-DENIER (ISLANDS) Uses: Filtration Synthetic leather High-tenacity filament Polymers: PA6 or PET islands, PLA, EVOH, ESPET sea 19

NONWOVEN OPPORTUNITIES EASTONE, PLA, EVOH, ect. PA, PET, PLA, PTT, PPS, PBT, PVDF, ect. HI PRESSURE EQUAL RESIDENCE TEMPERATURE SEPERATION PRINTED CIRCUIT STYLE PACKS BICO FIBER OPEN SYSTEMS SLOT DRAW UNIT NANO & BICO MELTBLOWN TEXTILE PROCESSING NEEDLE PUNCHING HYDROEN- TANGLEMENT 20

PRODUCT WHAT S NEW??? 21

THE «MAGIC BOX» Key Words Polymers : Advantage Technology : Simple Product : Unique 22

THE FUTURE OF NONWOVENS When talking of tridimensional Nonwovens, Carding process has been the dominant technology.but what if a lofty material can be made in very simple process just by selecting the right polymer combination in the right fiber configuration to make a web 23

LOFTY SPUNBOND/SPUNLAID MATERIAL SPUNLAID MATERIAL IS NOT A 2D STRUCTURE ANYMORE 24

ONE SIMPLE PROCESS 25

HIGH LOFT > 80MM 26

CONTINUOUS PRODUCTION 27

WHAT IS BEHIND THIS Develop spiral fibers during the Spunlaid process to create loftiness in the material. Change polymer ratio and /or fiber structure to optimize the characteristics in the material. Interlocking of the fibers under fiber activation to improve strength in the material. 28

SPIRAL FIBER 29

FIBER STRUCTURE AND RATIOS 80 % PLA 20 % PP 60% PLA 40 % PP 50 % PLA - 50 % PP 10 % PLA 90 % PP PLA IS SUSTAINABLE, BIOPOLYMER, ETC PP IS THE MOST AVAILABLE PLASTIC

MATERIAL DENSITY AS A FUNCTION OF POLYMER RATIO 31

PRODUCT DIVERSIFICATION Samples photographed at the CETI headquarters, 32

UNIQUE PRODUCT Multicomponent Continuous Filament Spunlaid Process -> Simple Process No Thermal nor Mechanical Bonding Tremendous Product Functionality & Flexibility Suitable for downstream: Cross Lapping, Needled Punch, Thermal Bonding, Hydroentangle, Patent Pending 33

PRODUCT CHARACTERISTICS Main Feature: Enhance Functionality just by changing polymers ratio and/or fiber structure Loftiness Resilience Stretchiness Strength - Inner bonding Wettability Memory, Shape, etc.. 34

HYGIENE MARKET Light Weight Loftiness Softness Resilience Strength Stretching Wettability Sustainability..

OTHER APPLICATIONS Thermal Insulation K value = 0.229, <5 Kg/m3 Acoustic Insulation Filtration Acquisition/Distribution layer Textile Application Medical 36

THE FUTURE OF NONWOVENS PLA, EVOH, ETC PA, PET, PLA, PTT, PPS, PBT, PVDF, ect. BICO FIBER OPEN SYSTEMS SLOT DRAW UNIT TEXTILE PROCESSING

THE «MAGIC BOX» Key Words Polymers : Advantage Technology : Simple Product : Unique 38

THE RESULT Spunbond (Spunlaid) material is NOT a 2D structure any more.. Lofty Spunbond is here. 39

THANK YOU!!! CETI Hills Inc NatureWorks LLC 40