Research & Development in Delaware. Delaware. Olivier Letessier, VP R&D Air Liquide Henri Chevrel, VP R&D Americas Air Liquide THIS DOCUMENT IS PUBLIC

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Research & Development in Delaware Olivier Letessier, VP R&D Air Liquide Henri Chevrel, VP R&D Americas Air Liquide THIS DOCUMENT IS PUBLIC I AIR LIQUIDE, LE LEADER MONDIAL DES GAZ, TECHNOLOGIES ET SERVICES POUR L INDUSTRIE ET LA SANTE Delaware Research & Technology Center, Date Nom & Fonction Direction 22 March 2017 Presentation of Air Liquide R&D

Global Research & Development Role & Responsibilities 2

Scientific Territory of Essential Small Molecules to Life to Matter to Energy 3

Wide Range of Skills Process Engineering Material Sciences Combustion Life Science Applied Mathematics Analytical Sciences Fine Chemical Synthesis and Surface Science Design & Manufacturing 4

Global R&D Network GERMANY FRTC (Frankfurt) AMERICAS - US DRTC (Delaware) Schülke GROUP R&D R&D SUBSIDIARIES 1,100 researchers 9 R&D sites 3 continents 41 nationalities FRANCE Paris-Saclay Research Center SEPPIC Air Liquide Medical Systems ASIA SRTC (China) ALL (Japan) ALLK (South Korea) 5

R&D 2016 Figures 217 Industrial & Academic partners 288 Millions Innovation Expenses 1,100 Researchers 296 Patents 6

Corporate R&D Mission Partnering with our stakeholders, we bring value to Air Liquide customers through innovation, based on sound scientific competencies, broadening of our collaborative ecosystems and flawless execution.

Collaborative Innovation WBLs, WBUs, ab&t HUBS & CLUSTERS Market and customer facing entities States the problem + sell the solution OPERATIONS CUSTOMERS GROUP R&D Develop the solution for today and tomorrow customer s needs Public Bodies/ Administrations Set legal frameworks and constraints Financially support solutions finding PUBLIC AFFAIRS POLICY MARKETS FUNDINGS AGENCIES (BPI, ANR, EEC, DOE) Owner of needs: functions, performance, costs User of the solutions SUPPLIERS ACADEMICS START-UPS, SMEs External partners Provide building blocks for the solution 8

R&D Activity Segmentation Exploratory Key Projects New techno, new competency development, Long term Support to Operations Technical assistance and expertise for operations Solutions for short/medium internal and external customer needs 9

Research & Development in the Americas 10

Delaware Research and Technology Center Mission Statement Air Liquide innovation driver in the Americas, capitalizing on North America s scientific & creative strengths for the Group Ensure technological and innovation support to Air Liquide s Americas operations, markets and customers 11

Example: Unconventional Oil and Gas Improve productivity and reduce the environmental impact of unconventional oil and natural gas recovery Optimize industrial gas-based foam fluids for hydrocarbon recovery Improve mobility control in EOR Reduce water usage by -70/85% Target 2x well productivity increase Place proppant further into fractures Develop understanding of foam/particle interactions Nitrogen and carbon dioxyde sales SG Ø: 1 inch Water: sand bed SG Ø: 1 inch Foam: sand suspended 12

Example: Calibration Gases Identify appropriate gases, molecular and isotopic concentrations, and validate stability Stable isotope references gases used in multiple industries: Forensic in Food & Beverage: honey, olive oil, beef etc. Oil & gas exploration: Origin of well (biogenic vs. thermogenic), connectivity through a well Environment: pollutant migration Specialty gases sales Example: olive oil origin Multiple geographies Proof of origin thanks to AL technology 13

Example: Energy Efficiency & Emission Reduction via Oxy-Combustion Improve energy efficiency and reduce emissions of customers plants Support wide range of industrial furnace: glass, aluminum, steel, copper, kiln, lead, cupola, etc. Integrate with customer process such as waste heat recovery, fuel preheating Furnace audit, production boost, custom burners, process tuning Oxygen sales Example: glass manufacturing Burner, Heat exchanger, control logic Burners work seamlessly in hot and cold 8-10 % fuel savings demonstrated Up to 16% CO 2 reduction from air to HeatOx Maintained same glass color, quality 14

Example: Deposition and Etching Solutions for Semiconductors (1/2) Electronics manufacturers (Apple, Samsung, Dell): increase performance (speed, memory capacity, bandwidth) for computers, cell phones, Big Data, Internet of Things and Artificial Intelligence Semiconductor manufacturers (Intel, TSMC, Micron) continuously: Compete on: Performance (bits, Memory capacity) of their chips Lower energy consumption Need for: New materials (different properties) New methods to deposit or process them More complex architectures to be manufactured R&D contribution to Air Liquide Advanced Materials 15

Example: Deposition and Etching Solutions for Semi-conductors (2/2) Customer (Semicon Mfg.) needs New Materials New Processes Semicon. Manu. R&D R&D Molecules Discovery: Design Synthesis Characterization Electronics Tool Maker R&D OK ed for production Molecules Screening for solution : Deposition Etching Metrology 16

Air Liquide R&D - Airgas Interactions Cost Synergies CYLINDER OPERATIONS BULK OPERATIONS PROCESS & PROCUREMENT Currently implemented Cylinder production: asset optimization Cylinder logistics: leveraging operational research capabilities Bulk production: asset optimization Bulk logistics: leveraging operational research capabilities Share Air Liquide and Airgas innovation culture Specialty gases manufacturing support 17

Air Liquide R&D - Airgas Interactions Revenue Synergies REVENUE SYNERGIES Currently implemented Gas applications: increased involvement of R&D teams in large bulk gas markets Combustion CO 2 Applications development E-biz and digital: combine Airgas and R&D digital expertise New offering development leveraging Airgas market channel Stable isotopes for O&G/Environment/Forensic Engine emissions testing Extension of foam applications in O&G recovery 18

Conclusion Sound and expert Air Liquide R&D supporting new offers development and operations efficiencies to leverage on Airgas national unmatched footprint 19

Delaware Research & Technology Center, 22 March 2017 R&D Americas 22 March 2017