S1 TITAN 600-800 Alloy LE Calibrations () Low Alloy Si P S Ti V Cr Mn Fe Co Ni Cu Nb Mo W Pb Analysis range, % LLD-2 LLD-0.15 LLD-0.3 LLD - 0.1 0.05-1.8 LLD - 9 0.1-2.0 75-100 LLD - 8 LLD - 5 LLD - 5 LLD- 0.3 LLD - 8 LLD - 6 LLD-0.3 LLD (Fe pure) 186 169 61 28/47 21/85 18/50 53 N.A. 27 60/80 48 28 32 80 121 SEC % 0.95 0.013 0.04 0.005 0.01 0.04 0.02 0.5 0.03 0.06 0.02 0.002 0.01 0.01 0.009 Typical accuracy: ±% 0.02 0.02 0.04 0.04 0.5 0.03 0.06 0.03 0.01 0.04 0.03 Phase 2 2 2 2/1 2/1 2/1 1 1 1 1 1 1 1 1 1 Tool Steel Al Si P S Ti V Cr Mn Fe Co Ni Cu Zr Nb Mo Sn W Pb Analysis range, % LLD-1.5 LLD-2 LLD-0.2 LLD-0.3 LLD - 0.3 LLD - 2 LLD - 5 0.1-2.0 69-98 LLD - 8 LLD - 2 LLD - 2 LLD-0.04 LLD- 0.15 LLD - 9 LLD-0.05 LLD - 19 LLD-0.3 LLD (Fe pure) 190 300 66 10 17/74 21/90 16/54 73 N.A. 120 100 44 24 27 32 51 175 105 SEC % 0.3 0.2 0.02 0.05 0.07 0.05 0.04 0.04 0.7 0.09 0.01 0.02 0.001 0.003 0.03 0.007 0.03 0.008 Typical accuracy: ±% 0.03 0.02 0.04 0.05 0.5 0.2 0.02 0.03 0.005 0.01 0.04 0.04 Phase 2 2 2 2 2/1 2/1 2/1 1 1 1 1 1 1 1 1 1 1 1 Stainless Steels Al Si P S Ti V Cr Mn Fe Co Ni Cu Zr Nb Mo Ta W Analysis range, % LLD-1.5 LLD-4 LLD-0.1 LLD-0.5 0.05-2 0.05-9 0.02-26 0.01-20 30-95 LLD - 18 0.05-50 0.01-5 LLD-0.05 LLD - 4.5 0.01-10 LLD-0.6 LLD - 15 LLD (Fe pure) 190 232 66 48 21/120 81 48 60 N.A. 26 82 57 32 32 34 93 96 SEC % 0.3 0.09 0.02 0.05 0.0 0.04 0.2 0.08 0.1 0.08 0.08 0.02 0.003 0.02 0.06 0.02 0.01 Typical accuracy: ±% 0.0 0.02 0.03 0.05 0.4 0.03 0.08 0.03 0.02 0.05 Phase 2 2 2 2 2/1 1 1 1 1 1 1 1 1 1 1 1 1 Nickels Al Si P Ti V Cr Mn Fe Co Ni Cu Zr Nb Mo Hf Ta W Re Analysis range, % LLD-2 LLD-1.5 LLD-0.1 0.05-3.5 0.05-0.5 0.02-30 0.02-2 0.02-66 0.1-20 32-100 0.1-35 LLD-0.6 LLD - 5.5 LLD - 28 LLD - 2 0.05-7 0.1-15 LLD-3 LLD (pure Ni) 480 171 37 20/51 26 24/141 41 44 64 N.A. 43 27 35 45 187 109 138 106 SEC % 0.3 0.06 0.02 0.05 0.05 0.3 0.16 0.67 0.08 0.7 0.11 0.005 0.01 0.05 0.02 0.016 0.05 0.02 Typical accuracy: ±% 0.03 0.05 0.3 0.05 0.4 0.05 0.1 0.1 0.02 0.04 Phase 2 2 2 2/1 2 2/1 1 1 1 1 1 1 1 1 1 1 1 1 Cobalts Al Si P S Ti V Cr Mn Fe Co Ni Cu Nb Mo W Pb Analysis range, % LLD-1.5 LLD-1.5 LLD-0.1 LLD-0.1 LLD-3.5 LLD-0.05 0.05-35 LLD - 1.8 0.1-55 15-100 0.1-58 LLD-0.25 LLD- 4.0 LLD - 10 0.1-15.1 LLD-0.4 LLD (pure Co) 694 240 10 10 22/108 25 28/75 68 69 N.A. 33 4 54 34 295 90 SEC % 0.18 0.11 0.005 0.004 0.03 0.009 0.5 0.06 0.15 0.46 0.09 0.045 0.006 0.04 0.1 0.009 Typical accuracy: ±% 0.03 0.02 0.05 0.05 0.1 0.3 0.1 0.01 0.04 0.1 Phase 2 2 2 2 2/1 2 2/1 1 1 1 1 1 1 1 1 1 Zincs Al Ti Fe Cu Zn Pb Bi Analysis range, % LLD-30 LLD-0.15 LLD-0.5 LLD-2.5 65-100 LLD-0.15 LLD-0.1 LLD (pure Zn) 547 12/105 85 75 N.A. 112 80 SEC % 0.4 0.003 0.004 0.02 0.4 0.005 0.005 Typical accuracy: ±% 0.6 0.006 0.01 0.04 0.6 Phase 2 2/1 1 1 1 1 1 Coppers Al Si P S Ti Cr Mn Fe Co Ni Cu Zn As (KB1) Zr Ag Sn Pb (LB1) Bi Analysis range, % LLD-1.5 LLD-5 LLD-0.5 LLD-0.2 LLD-0.25 LLD - 2.5 LLD - 5.5 LLD- 5 LLD-0.5 LLD- 30 40-100 0.1-40 LLD - 0.3 LLD- 0.5 LLD - 3.0 0.1-10 0.1-10 LLD-0.05 LLD (pure Cu) 983 257 101 25 23/132 20/150 35 29 18 62 N.A. 27 35 44 185 275 122 107 SEC % 0.4 0.09 0.01 0.01 0.005 0.08 0.04 0.07 0.01 0.07 1 0.15 0.01 0.01 0.01 0.08 0.13 0.01 Typical accuracy: ±% 0.01 0.02 0.03 0.06 0.02 0.06 1 0.2 0.03 0.02 0.02 0.1 0.2 0.03 Phase 2 2 2 2 2/1 2/1 1 1 1 1 1 1 1 1 1 1 1 1 Bruker Elemental - August 27, 2014
S1 TITAN 600-800 Alloy LE Calibrations () Al, Si Bronzes Al Si P S Ti Cr Mn Fe Co Ni Cu Zn As (KB1) Zr Ag Sn Pb (LB1) Bi Analysis range, % LLD - 12 LLD - 5 LLD-0.5 LLD-0.2 LLD-0.25 LLD - 2.5 LLD - 5.5 LLD- 5 LLD-0.5 LLD- 30 40-100 0.1-40 LLD - 0.3 LLD- 0.5 LLD - 3.0 0.1-10 0.1-10 LLD-0.05 LLD (pure Cu) 983 257 101 25 23/132 20/150 35 29 18 62 N.A. 27 35 44 185 275 122 107 SEC % 0.4 0.09 0.01 0.01 0.005 0.08 0.04 0.07 0.01 0.07 1 0.15 0.01 0.01 0.01 0.08 0.13 0.01 Typical accuracy: ±% 0.01 0.02 0.03 0.06 0.02 0.06 1 0.2 0.03 0.02 0.02 0.1 0.2 0.03 Phase 2 2 2 2 2/1 2/1 1 1 1 1 1 1 1 1 1 1 1 1 Light Alloys - Titaniums Al Si Ti V Cr Mn Fe Cu Zr Nb Mo Pd Sn Ta W Analysis range, % 0-15 0-1 68-100 LLD -16 LLD -15.0 LLD - 1.5 LLD - 2 LLD - 4 LLD - 5.5 LLD - 2.0 LLD -16 LLD -0.15 LLD -2 LLD-1 LLD-0.5 LLD (pure Ti) 1220 265 N.A. 181 290 106 60 32 18 20 32 85 158 60 48 SEC % 0.3 0.09 0.9 0.08 0.04 0.01 0.09 0.01 0.02 0.02 0.04 0.006 0.04 0.01 0.01 Typical accuracy: ±% 1.1 0.15 0.1 0.1 0.1 0.04 0.1 0.02 0.1 0.01 0.1 0.02 0.04 Phase 2 2 2/1 2 2 1 1 1 1 1 1 1 1 1 1 Light Alloys - Al/Mg Mg Al Si Ti V Cr Mn Fe Co (KB1) Ni Cu Zn Zr Sn Pb Bi Analysis range, % LLD-100% LLD-100% LLD-18 LLD -0.1 LLD -0.1 LLD -0.3 LLD-2 LLD-1.5 0.02-0.45 LLD - 2.5 LLD - 5 LLD -7 LLD-0.2 LLD-0.1 LLD -0.1 LLD-0.1 LLD (1100 or pure Mg) 957 484 125 96 95 48 34 22 140 15 10 7 6 78 10 11 SEC % 0.17 1.9 0.2 0.008 0.004 0.009 0.005 0.01 0.01 0.01 0.02 0.02 0.001 0.005 0.002 0.003 Typical accuracy: ±% 0.03 0.015 0.02 0.015 0.04 0.03 0.02 0.05 0.05 0.01 0.02 0.02 0.01 Phase 2 2 2 1 1 1 1 1 1 1 1 1 1 1 1 1 Full MultiMatrix FP Mg Al Si P S Ti V Cr Mn Fe Co Ni Cu Zn As Se Y Zr Nb Analysis range, % LLD-100% LLD-100% LLD-100% LLD-5% LLD-5% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% SEC % 0.4 0.7 0.8 0.3 0.3 0.1 0.03 0.3 0.15 0.5 0.3 0.4 0.4 0.1 0.2 0.2 0.01 0.02 0.05 Mo Ru Rh Pd Ag Cd In Sn Sb Hf Ta W Re Ir Pt Au Pb Bi Analysis range, % LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% LLD-100% SEC % 0.05 0.08 0.04 0.04 70.00% 0.1 0.1 0.2 0.07 0.1 0.1 0.4 0.1 0.3 0.2 0.4 0.2 0.1 Calibration: FP based (with empirical corrections), with normalization based on BRUKER Intensity scaling when sample is smaller than mask Analysis range: Concentration range covered by reference samples in the calibration of the application. Can be extened by 15% with FP based calibrations. Empirical calibrations should only be used within the range. Lower Limit of Detection (LLD): The smallest concentration which can be detected. a) In this document LLD is specified for a given matrix in three sigma 99.7% confidence level (3 sigma); 60 second phase 1 analysis time, 180 second phase 2 analysis time b) Individual elemental LLD's improve as a function of the square root of the analysis time. Actual lower limit of detection range depends on several factors such as matrix interferences, overlapping elements, level of statistical confidence and testing time. Measurement of concentration close to the low analysis range requires typically long measurement time > 60s Standard Error of Calibration (SEC): Average error (deviation) between certified and XRF value of the samples used for the calibration expressed as an absolute value in weight %. Typical accuracy: Typical average error within the analysis range when large set of reference samples are measured. Notice that error of the individual sample may differ significantly from this value. Measurement time: 30s (2) or less than 10 sec (1) Phase: Number indicates on which measurement phase the listed LLD was determined Bruker Elemental - August 27, 2014
S1 TITAN 600-800 Alloy Calibration: Multimatrix FP V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Low Alloy V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Tool Steel V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Stainless Steels V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Nickels V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Cobalts V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Zincs V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Coppers V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Al Si Bronzes V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Light Alloys- Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
S1 TITAN 600-800 Alloy Calibration: Light Alloys Al/Mg V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr