INFRARED REFLECTANCE INSPECTION

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Infrared Reflectance Imaging for Corrosion Inspection Through Organic Coatings (WP-0407) Mr. Jack Benfer Principal Investigator NAVAIR Jacksonville, FL Tel: (904) 542-4516, x153 Email: john.benfer@navy.mil (Senior Corrosion Engineer) Mr. John Weir, P. E. Northrop Grumman Corp. Bethpage, NY Tel: (516) 575-5422 Email: john.weir@ngc.com

Report Documentation Page Form Approved OMB No. 0704-0188 Public reporting burden for the collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden, to Washington Headquarters Services, Directorate for Information Operations and Reports, 1215 Jefferson Davis Highway, Suite 1204, Arlington VA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to a penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. 1. REPORT DATE SEP 2009 2. REPORT TYPE 3. DATES COVERED 00-00-2009 to 00-00-2009 4. TITLE AND SUBTITLE Infrared Reflectance Imaging for Corrosion Inspection Through Organic Coatings (WP-0407) 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Naval Air Station Jacksonville,Jacksonville,FL,32212 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSOR/MONITOR S ACRONYM(S) 12. DISTRIBUTION/AVAILABILITY STATEMENT Approved for public release; distribution unlimited 11. SPONSOR/MONITOR S REPORT NUMBER(S) 13. SUPPLEMENTARY NOTES ASETSDefense 2009: Sustainable Surface Engineering for Aerospace and Defense Workshop, August 31 - September 3, 2009, Westminster, CO. Sponsored by SERDP/ESTCP. 14. ABSTRACT 15. SUBJECT TERMS 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT a. REPORT unclassified b. ABSTRACT unclassified c. THIS PAGE unclassified Same as Report (SAR) 18. NUMBER OF PAGES 31 19a. NAME OF RESPONSIBLE PERSON Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39-18

TECHNICAL CONCEPT

TECHNICAL CONCEPT U.S. Patent: 7,193,215 (0.4um 0.75um) (3um 5um MW) IR cameras tuned to a transparent spectral window can image through standard paint systems. Reflectance differences between regions appears as image contrast. Result is real time imaging of substrate surfaces for video or digital capture.

Reflectance of Corroded and Uncorroded Regions of Painted Aluminum Coupons Reflectance 0.2 0.15 0.1 0.05 Gloss White Topcoat/PRC 23377 Primer Alodined Uncorroded Area Corroded Area IMAGE CONTRAST Reflectance Gloss Gray Topcoat/Korflex Sealer/PRC 23377 Primer Alodined 0.1 0.09 0.08 0.07 0.06 0.05 0.04 Uncorroded Area Corroded Area 0 3 3.5 4 4.5 5 5.5 6 Wavelength, μm 0.03 3 3.5 4 4.5 5 5.5 6 Wavelength, μm Modern IR cameras tuned to this spectral window can see through the paint, and reflectance differences between regions appears as image contrast

OPTIMAL TRANSMISSION BAND 70.0000 60.0000 Deft 44-GN-7 Primer: MIL-PRF-85582 Hentzen Color # 16440 Topcoat: MIL-PRF-85285 Deft Primer + Hentzen Topcoat Finish Scheme 50.0000 % Transmission 40.0000 30.0000 20.0000 10.0000 0.0000-10.0000 Area of Interest 2.0000 3.0000 4.0000 5.0000 6.0000 Wavelength (micrometers) COTS Camera Note: Coatings are standard mil-spec thicknesses.

TECHNICAL CONCEPT

2 ND GENERATION PROTOTYPE SYSTEM 2 Operators Optimized Filter Improved Display Remote Data Capture

TARGET STANDARD ANALYSIS Visible Image Visible Painted Image IR Painted Image Laboratory validation standard in support of image optimization. Field operational check standard to verify camera functionality. Note: This standard is painted MIL-PRF-85582 epoxy primer and MIL- PRF-85285 polyurethane topcoat. (NAVAIR Standard Paint Scheme).

IR IMAGING OPTIMIZATION

FILTER EVALUATION Optimized Filter Results 3-5 μm: STANDARD FILTER 3.75-5 μm: OPTIMIZED FILTER **Received new Merlin IR camera with internal 3.75-5 micron filter.

CHEMICAL AGENT RESISTANT COATINGS Visible Infrared Visible Infrared 35 30 25 46168 green 3.3 mil 53039 green 6 mil 64159 black 5.6 mil FTIR Transmission % Transmission 20 15 10 Hentzen P3 2x2 mil 5 0 0 1 2 3 4 5 6 7 Wavelength

TECHNICAL CONCEPT Infrared Imaging

TECHNICAL APPROACH Dem/Val NADEP Jacksonville, FL IRRIT Results (Painted) vs. Visible Results (Stripped)

NADEP JACKSONVILLE Dem/Val Started Official Dem/Val (2of 3) P-3 BU# 162772, SEQ 311

IR Inspection of Painted A/C Fastener Heads Spot Welds Corrosion Part Numbers

HILL AFB: A-10 CORROSION SURVEY Fuel Cell Machine Marks on Fastener Head Visible IR Image Visible IR Image Filiform Corrosion

DETAIL OF E2-C HAWKEYE PANELS Metal Rework Markings

KC-135 OC-ALC Dem/Val

Results 1. The IR method directly images corrosion by-product through the paint system due to reflectance contrast differences of the substrate. 2. The visual method relies upon the identification of paint surface irregularities/blistering (i.e., paint degradation) as a result of substrate volume changes associated with corrosion formation.

DEPLOYMENT - PRODUCTION MAINTENANCE & OVERHAUL Wing Spar Inspection Engineering evaluation of incoming material condition following visual ID of Corrosion.

DEPLOYMENT IR PHOTOS

DEPLOYMENT RESEARCH & DEVELOPMENT Outdoor Exposure Testing Evaluation of NAVAIR exposure coupons located at Cape Canaveral, FL Exposure Coupons Exposure Test Facility

DEPLOYMENT IR PHOTOS Outdoor Exposure Testing Evaluation of NAVAIR exposure coupons located at Cape Canaveral, FL Scribe Line Corrosion Fastener Panel Anomalies

DEPLOYMENT ENGINEERING INVESTIGATION Avionics Receiver/Transmitter Evaluation of corrosion damage for root cause assessment. Visual Photograph IR Photograph

DEPLOYMENT RESEARCH & DEVELOPMENT ASTM B117 corrosion investigation in support of cadmium alternative brush electroplating repair of AISI 4130 substrate. Visual Photograph IR Photograph

TECHNOLOGY IMPROVEMENT MWIR cameras are required to be smaller, lighter and more portable then prototype system. Require integrated data capture and storage. 3.75-5.0 um band pass filter. Detector Resolution: (320 x 240 min). Auto focus, zoom with interchangeable lenses.

TECHNOLOGY IMPROVEMENT FLIR GF309 3.9 um narrow bandpass cold filter specifically designed for imaging through flames. FLIR is replacing the current cold filter with a broadband 3 5 um filter and offering it as a standard MWIR camera.

QUESTIONS

USCG HU-25 INSPECTION Paint Thickness in this Zone = ~6.5 mils USCG NDI Program Manager Mr. Rusty Waldrop Visible Image - Painted IR Image - Painted Note: Several corroded areas were found while checking the scan rate on this region, all corroded areas found via the IRRIT were confirmed by chemically stripping.

B-52 Demonstration Results Surveyed Bomb Bay Longerons of (2) B-52 Aircraft at OC-ALC. Right and left sides inspected, each 15-16 feet in length. 8 corrosion sites located via IR Inspection that were not identified through visible or eddy current inspection. All corrosion sites were confirmed following chemical spot stripping. 100% correlation achieved.

IR IMAGES Blackbody Effect US Patent 7,164,146 Emissive Surface T = 95.7 F IR source = 0W Equilibrium Surface T = 95.6 F IR source = 4.35W Reflective Surface T = 95.0 F IR source = 7.70W Corrosion Product White No Corrosion Product Observed Corrosion Product Black