High Speed pin Photodetector with Ultra-Wide Spectral Responses

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High Speed pin Photodetector with Ultra-Wide Spectral Responses C. Tam, C-J Chiang, M. Cao, M. Chen, M. Wong, A. Vazquez, J. Poon, K. Aihara, A. Chen, J. Frei, C. D. Johns, Ibrahim Kimukin, Achyut K. Dutta a and M. Saif Islam Dept of Electrical and Computer Engineering, University of California, 3139 Kemper Hall, Davis, CA 95616-5294, Fax: (53)-752-8428, saif@ece.ucdavis.edu a Banpil Photonics, Inc., 2953 Bunker Hill Lane, Santa Clara, CA 9554 ABSTRACT We report the design and fabrication of a high speed surface illuminated pin photodetector with a wide spectral response. An based detector was grown lattice matched to and the device was fabricated using a novel technique to facilitate the direct absorption of incoming photons in the layer without being absorbed by any other wider bandgap material. The absorption of a wide spectrum of wavelengths was achieved by recess etching almost all of the contact layer above the absorption layer of a pin photodiode subsequent to ohmic contacts formation. Theoretical simulation shows responsivities above.6 A/W between 9 and 16 nm and a linear reduction to.3 A/W at 65 nm. This makes the detector operational in both visible and near-infrared spectrum. The responsivities are.5,.77, and.67 A/W for 84, 131 and 155 nm respectively. These values confirm the potential of the device to be effective in all of the optical fiber communication wavelengths. Our calculations also show that the device can operate above 1 GHz throughout the spectrum. Keywords: high-speed photodetector, pin photodiode, wide spectrum of wavelengths. 1. INTRODUCTION Broad spectral image sensors are required for various ground-based, air-borne, space-borne military applications, including the atmospheric properties measurement, surface topography and remote sensing. To date, several sensors covering different spectral ranges are used for this purpose. Next generation instruments require single sensor (or its array) that covers multiple spectral bands (.3 to 2.5 µm of wavelengths) and could be used for different applications. Solid-state image sensors with higher resolution are used in many commercial applications and also for other light imaging uses. Such imaging sensors typically comprise of CCD (charge coupled device) or CMOS (complimentary metal oxide semiconductor) image sensors with associated switching elements, and address (scan) and read out (data) lines [1]. Both CCD and CMOS image sensors are used in silicon technology which is so matured that nowadays millions of pixels and surrounding circuitry can be fabricated. As today s CCD and CMOS image sensors technology are based on Si-technology, the detectable spectral ranges are limited to the wavelengths below 1 µm where Si exhibits absorption. Besides, CCD and CMOS image sensors have also other shortcomings such as low frequency response combined with low quantum efficiency over broad spectral response. Absorption coefficient of various semiconductors used in the optoelectronic devices are shown in Figure 1. It is seen that In.53 Ga.47 As () and Ge are two materials whose absorption spectrum covers both the visible and the near infrared spectrum. Ge can not be used to get heterostructure photodetectors. Any pin type photodetector based on Ge will have significant amount of absortion in either p+ or n+ layer, which will lower the responsivity and the speed of the photodetector. based detector on substrate is used for detecting the light with wavelength range from.9 to 1.7 µm which is widely used in the optical communication [2]-[6]. Photodiodes especially of pin type have been studied extensively over the last decade for its application in optical communication. Now a day, the photodetector speed as high as 4 Gb/s [6], and quantum efficiency close to 1% [5] are available for optical communication. material is usually used as absorption material, and the diode is fabricated on the wafer. For detection of radiation having shorter wavelengths (3 nm to 98 nm), Si based photodiodes are used and that has been also extensively studied. None of the current solution can provide broad spectral detection capability ranges from.3 to 2.5 614-36 V. 2 (p.1 of 6) / Color: No / Format: Letter / Date: 9/7/25 1:48:3 AM

µm of wavelengths. It is highly desirable to design the photodetector (array) having broader spectral detection ranges (.3 to 2.5 µm) for various military s applications including remote sensing, surface topography etc. 1 6 1 5 α (cm -1 ) 1 4 1 3 Si GaAs Ge 1 2 4 Figure 1. Absorption coefficient of various semiconductors used in optoelectronic devices. [8] For covering broad spectral ranges especially from.3 to 1.6 µm, conventionally two photodiodes fabricated from Si and technology, discretely integrated [7], are usually used. Although wafer bonding can be used to bond Si and to cover longer wavelengths, the reliability of wafer bonding over wide range of temperature is still an unsolved issue and a high-speed operation is not feasible with a wafer bonding approach. It is highly desirable to design a monolithic photodiode array, which could offer high bandwidth (GHz and above) combined with high quantum efficiency over a broad spectral ranges (.3 to 2.5 µm), and the possibility to rapidly and randomly address any pixel. 2. DESIGN We designed an based pin type photodetector with a 1µm intrinsic layer lattice matched to. The layer thickness was chosen to be 1µm in order to get high responsivity through out the spectral range of operation. The layer structure of the grown wafer is shown at Table 1. The structure was grown on semi-insulating substrate. Initially highly Si doped layers were grown. The dopant concentration was grades as the thickness increased to prevent the dopant migration to the intrinsic layer. The n+ layers also has a thin undoped layer which is used as the etch stop layer. After the n+ layers, intrinsic layer was grown. This layer was not doped. But the background doping is n-type in the order of 1 15. Then the top p+ layers were grown with a similar dopant profile; starting from 5 1 17 to 1 2 at the topmost layer. This layer is used to get ohmic contacts with lower resistance. It is etched away after the fabrication to prevent loss of the optical power. 614-36 V. 2 (p.2 of 6) / Color: No / Format: Letter / Date: 9/7/25 1:48:3 AM

Table 1. Epitaxial layer of the grown wafer. Type of Layer Material Thickness (nm) Dopant Concentration (cm -3 ) p+ 6 Zn 1 1 2 p+ 3 Zn 1 1 2 p+ 1 Zn 5 1 18 p+ 1 Zn 5 1 17 i 1 Undoped n+ 2 Si 1 1 18 n+ 5 Si 5 1 18 6 Undoped n+ 25 Si 5 1 18 Semi Insulating Substrate = 5 nm = 25 nm 7 6 7 6 5 5 4 3 2 4 3 2 1 1 (a) (b) = 1 nm = 5 nm 7 6 7 6 5 5 4 3 2 4 3 2 1 1 (c) (d) Figure 2. Absorption in the p+ ( ) and intrinsic ( ) layers for the detector structure with 5nm (a), 25nm (b), 1nm (c), and 5nm (d) p+ layers. 614-36 V. 2 (p.3 of 6) / Color: No / Format: Letter / Date: 9/7/25 1:48:3 AM

Optical properties of the photodetector were obtained with a transfer matrix method (TMM) based calculations. We calculated the reflected power and the absorbed optical power in the p+ and intrinsic layers. Without the anti-reflection coating, 3% of the optical power is reflected from the top semiconductor layer. Figure 2 shows the absorbed optical power in the p+ layers and layer after the topmost layer was etched away. Here we can see the effect of the layer thickness on the optical power absorbed in the layer. Around 92 nm, the optical power absorbed in the layer drastically decreases with 5 nm p+ layer as shown in Figure 2(a). Above 92 nm, the absorbed power decreases gradually due to decrease of the absorption coefficient of the. As the top p+ layer is etched away and become thinner, the absorption in the layer increases below 92 nm, while it is almost same above this wavelength. The absorption in the p+ and intrinsic layers were calculated for p+ layer thicknesses of 25, 1, and 5 nm and shown in Figure 2(b), (c), and (d) respectively. The absorption in the active layer can be increased by depositing anti-reflection coating, which increases the power coupled to the photodetector layers. After etching the layer to desired thickness, single or multi-layer antireflection coatings are deposited on the active area. As the number of layers used in the coating increases, the spectral range which the reflection is minimized increases. But adding more layers increases the complexity. We calculated the reflected power and the power absorbed in the p+ and intrinsic layers for different coating layer thicknesses. We have chosen silicon nitride layer with a refractive index of 1.85. With this dielectric coating, zero reflection can be achieved for a semiconductor with refractive index of 3.42. Figure 3(a) and (b) shows the reflection, absorption in p+ layer and intrinsic layers as a function of wavelength for 18nm and 149nm thick coatings respectively. 9 8 Reflection p+ absorption absorption 9 8 Reflection p+ absorption absorption Absorption or Reflection(%) 7 6 5 4 3 2 1 Absorption or Reflection(%) 7 6 5 4 3 2 1 (a) (b) Figure 3. Reflection (-), absorption in the p+ ( ) and intrinsic ( ) layers for the detector structure with 1 nm top p+ layer with 18 nm (a) and 149nm (b) thickness anti-reflection coating. After calculating the spectral absorption in the photodetector layers, we can calculate the responsivity (or quantum efficiency) of the photodetector. The intrinsic layer is thin enough to collect all the photogenerated carriers. We know that each absorbed photon will generate one electron hole pair which contributes to the photocurrent. So above 92nm wavelength, the quantum efficiency will be equal to the absorbance of the intrinsic layer. Below 92nm wavelength, photogenerated carriers will be present in the heavily doped layers. Electrons within the diffusion length of the p+ layer will diffuse slowly to the intrinsic layer, which finally contributes to the photocurrent. This extra current must be included during the calculation of the quantum efficiency (or responsivity). 614-36 V. 2 (p.4 of 6) / Color: No / Format: Letter / Date: 9/7/25 1:48:3 AM

.8.8.7.7.6.6 Resposivity (A/W).5.4.3.2 Resposivity (A/W).5.4.3.2.1.1.. (a) (b) Figure 4. Responsivity calculation of the photodetector when the diffusion of electrons from p layer was included ( ) and not included ( ) for the detector with 18 nm (a) and 149nm (b) thickness anti-reflection coating. We calculated the responsivity of the photodetector for two anti-reflection coating layers mentioned in Figure 3. Figure 4 shows the results of these calculations. We show the responsivity when the diffusion current included and not included in the calculations, which gives the upper and lower limit. As we have absorption in the layer above 92nm wavelength, the results for both cases are identical. Below 92nm, we see a significant difference. Based on these results, this photodetector can be used between 5nm and 17nm spectral range, which covers the most of the visible and near-infrared spectrum. 25 2 3-dB Bandwidth (GHz) 15 1 5 25 5 75 1 125 15 175 2 Area (µm 2 ) Figure 5. Calculated 3-dB bandwidth of the photodetector with the load resistance of 5Ω and for serial resistance of Ω (solid line), 5Ω (dashed line), and 1Ω (dotted line). 614-36 V. 2 (p.5 of 6) / Color: No / Format: Letter / Date: 9/7/25 1:48:3 AM

Other important property of a photodetector is the speed. In our detector, the speed will depend on different factors in different wavelength range. Below 92nm, the diffusion from the heavily doped layers will affect the speed of the photodetectors, while above 92nm, the speed will depend on the transit time of the photo-generated charges and the RC constant of the photodetector. When a reverse bias of 1 V is applied, the electric filed in the intrinsic layer is 1 5 V/cm. At this electric field, the velocity of electrons and holes are 9.5 1 6 and 6 1 6 respectively. The time it takes all the photo-generated carriers in the intrinsic layer to reach the highly doped layers is around 1.5 psec and 16.7 psec for electrons and holes respectively. Our calculations show that small area photodetectors have transit time limited 3-dB bandwidth of 23 GHz. As the area increases, the capacitance of the photodetector increases and starts to limit the bandwidth of the photodetector. Figure 5 shows the calculated 3-dB bandwidth of the photodetector with the load resistance of 5Ω and for serial resistance of Ω, 5Ω, and 1Ω. Below 92nm wavelength, the diffusion current will degrade the 3-dB bandwidth significantly. 3. FABRICATION The fabrication of the photodetectors starts with the p+ ohmic contact formation. Sample is patterned with photoresist and Ti/Pt/Au metals are deposited on the p+ layer. After cleaning the sample, lithography is done for the n+ ohmic etch. All the layers down to the etch stop layer inside the n+ layers are etched with wet etch solutions. H 3 PO 4 :H 2 O 2 :H 2 O solution is used to etch, HCl:H 2 O solution is used to etch. After the desired depth is reached, Ge/Ni/Au metals are deposited. After the lift-off and the cleaning, the sample is processed at high temperatures to decrease the resistance of the contacts. Then, all the layers outside the mesa of the photodectors are etched down to the semi-insulating layer to isolate the photodetectors electrically from each other. The detectors are ready to the tests and post processing steps. The active area of the photodetector is patterned and etched gradually to see the effect of the thickness of the p+ layer on the responsivity and the speed of the photodetectors. Finally antireflection coating is deposited for the optimized structure. 4. CONCLUSION The calculations show that the photodetector is capable of operating between the 5nm and 17nm wavelength range, which covers the most of the visible and near-infrared spectrum. Also the photodetector has 3-dB bandwidth of 23 GHz for optical signals in the 92 nm to 17 nm range. The bandwidth is lower below 92nm, but the expected bandwidth is above 1 GHz. With these properties, the photodetector shows high speed and wide bandwidth properties. REFERENCES 1. B. Ackland and A.Dickinson, Camera on a chip, ISSCC Dig. Tech. Papers, pp. 22-25, 1996. 2. G. Lucovsky, R. F. Schwarz, and R. B. Emmons, Transit-time consideration in p-i-n diodes. J. Appl. Phys., 35, pp.622-628, 1964. 3. R. G. Smith and S. D. Personick, Receiver design for optical communication systems, in Semiconductor Devices for Optical Communication, 2nd ed., pp.89-16, H.Kressel-Springer-Verlag, New York, 1982. 4. T. Mikawa, S. Kagawa, and T. Kaneda, / PIN photodiodes in the 1 µm wavelength regio. Fujitsu Sci. Tech. J., 2, pp. 21-218, 1984. 5. M. K. Emsley, O. Dosunmu, and M. S. Ünlü, Silicon substrates with buried distributed Bragg reflectors for resonant cavity-enhanced optoelectronics, IEEE J. Selected Topics in Quantum Electron., 8(4), pp. 948-955, 22. 6. A. K. Dutta, M. Takechi, R. S. Virk, M. Kobayashi, K. Araki, K. Sato, M. Gentrup, and R. Ragle, 4 Gb/s Postamplifier and PIN/preamplifier Receiver Moduled for Next Generation Optical Front-end System, IEEE J. Lightwave Technology, 2, pp. 2229-2238, 22. 7. Hamamatsu, Optoelectronics Catalog, 23. 8. Edward D. Palik, Handbook of Optical Constants of Solids, Academic Press, Orlando, 1998, Vol. 1. 614-36 V. 2 (p.6 of 6) / Color: No / Format: Letter / Date: 9/7/25 1:48:3 AM