AX460, AX466 and AX416 Single and dual input analyzers for ph/redox (ORP)

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Data sheet DS/AX4PH EN Rev. K AX460, AX466 and AX416 More processing power, higher performance Cost effective select one or two ph/redox (ORP) inputs or combine ph/ Redox (ORP) and conductivity in one analyzer Reduced installation cost easy access terminations; reduced panel space High functionality at minimum cost three alarms and two fully isolated current outputs integral Water/Chemical sensor cleaner control integral PID controller (AX460) Expanded monitoring and control add-on option board provides a total of five alarm relays and four current outputs service log-book providing historical data On line assurance of reliability comprehensive sensor and instrument self-checking Energy saving high visibility backlit display with auto switch-off function Reduced yearly maintenance costs 12 to 30V DC option negates the need for costly safety tests Wide range of applicability water and wastewater treatment power, pure water semiconductors chemicals pharmaceuticals pulp & paper

The AX400 Series AX400 analyzers incorporate the latest technology to provide highly reliable, flexible, feature-packed devices that satisfy a diverse range of process monitoring and control applications. The complete range encompasses solutions for ph/redox (ORP), conductivity and dissolved oxygen. AX46x analyzers enable continuous measurements of one or two ph or Redox (ORP) points with simultaneous local display and retransmission. AX46x is used with glass, enamel and antimony ph electrodes and metal Redox sensors, providing measurements with exceptional accuracy and performance. AX400 Series analyzers are available for either wall-/pipe- or panel-mounting and are rated to IP65. High Functionality as Standard All versions are supplied with two, fully isolated current outputs as standard, that can be assigned to the measured parameter, sample temperature or any appropriate calculated variables. Three programmable relay set points are available that can also be assigned as required. Innovative features such as power-saving display and a diagnostic current output option all contribute to a low cost of ownership. Plug-and-Produce Expanded Control An advanced function card provides an additional two current outputs and two further alarm relays that can be assigned to either measured values or sample temperature. ABB Plug-and-Produce software automatically reconfigures the analyzer if an option board is added later. No user programming is necessary. A real-time clock and logbook are also included making the full-facility versions extremely powerful and versatile. 7.00 7.00 ph ph Monitoring ph 3 Standard Relay s Significantly Reduced Maintenance Costs The AX400 analyzers are supplied as standard for 85 to 265V AC operation. There are no inner switches to set. They can also be provided for 24V AC or 12 to 30V DC supply and recognize automatically which of the two supplies is being used. 24V DC operation reduces maintenance costs significantly by negating the need for costly, yearly safety tests to ensure compliance with safety procedures. Energy Saving Display The backlit display has been designed to operate in all types of environments and shows both the measured parameter(s) and, on a separate 16-character display line, diagnostic and computed information. On dual-input analyzers both measured parameters are displayed simultaneously. For conservation of energy, the backlight can be set to switch off automatically after 60s of inactivity. Backlight Can Be Set to Switch-off When Inactive Easy-Access Installation Terminals Easy access to the terminations ensures rapid and cost-effective installation. The wall-/pipe-mount version has been designed to ensure that cable connection is simple and convenient. Ingress protection of the electronics section is retained even when the terminal compartment cover is opened. 7.00 ph 7.00 ph Monitoring ph 2 Additional Relay s 2 Standard Current s 2 Additional Current s AX400 s AX400 Termination Chamber Makes Access Easy 2 DS/AX4PH EN Rev. K

Dual Input Measurement for Critical Duties The AX400 enables two continuous measurements with simultaneous local display and retransmission. This capability provides an on-line validation of the process measurement. Making two simultaneous measurements and configuring one of the set points as a difference alarm provides continuous on-line checking and early warning of an invalid measurement. ph Sensor A ph Sensor B AX466 Dual Input ph + ph Analyzer PV1 PV2 Difference Alarm Waste Treatment ph & Redox (ORP) ph and Redox (ORP) are essential control parameters when removing toxic chromium ions from waste water in metal-finishing applications. Dual ph and Redox analyzers and integral control simplifies installation and reduces investment costs. Acid Chrome Waste Bisulphite ph On/Off ORP On/Off ph AX466 ph/orp ORP Caustic ph Proportional AX460 ph ph Reduction Neutralization Dual-input Comparator for Critical Measurements Detecting breakthrough of ammonia in a chiller unit is made possible with dual measurement. Comparison before and after the chiller ensures extremely rapid leakage detection, preventing damage to the system. Waste Treatment ph and Redox (ORP) Just-in-Time Maintenance One of the most vulnerable times for a ph electrode is during reintroduction into the line. If used with a solution earth rod, AX46x analyzers with advanced diagnostic facilities can detect sensor breakages as they occur. In addition, they can detect sensors out-of-process and several reference faults for fault diagnosis and reduced downtime. Process or Waste Water Outlet Tubular Heat Exchanger Process or Waste Water Inlet 'Cable Broken/ Disconnected' Ammonia Leakage Detection in a Chiller Unit 'Glass Cracked or Broken' 'Reference Fault' 'Electrode Out of Sample' Just-in-Time Maintenance DS/AX4PH EN Rev. K 3

Reduced Maintenance Through In-line Cleaning Many installed ph sensors benefit from regular cleaning. When carried out manually, this can be laborious and costly so is often ignored. Advanced AX400 ph analyzers make it possible to automate sensor cleaning by using a programmable wash-timer contact to activate a cleaning agent valve or pump. Pulsed water-wash and jet-wash chemical clean actions are standard, user-selectable functions. The frequency and duration of the wash can be tuned to meet the requirements of the application. For chemical cleaning a 60 liter (13 gallon) sensor cleaning station can be supplied (model no. AA0010), complete with delivery pump and low level alarm. Chemical cleaning has proved particularly successful on potable drinking water plants where manganese and iron in the sample can create unacceptably high levels of maintenance. Effective cleaning reduces cost of ownership. AX460 Integral P, PI and PID Control The single input AX460 analyzers incorporate three-term PID Control, offering three modes of sophisticated control: analog, pulse length (time proportional) and pulse frequency. These are supplied as standard and can be operated in direct- or reverse-acting mode, dependent upon the application. Auto/Manual and Bumpless Transfer An auto/manual feature is incorporated for rapid manual access to the control functions. The controller facilitates bumpless transfer between manual and auto modes, providing the measured variable is within the proportional band and some integral action time has been programmed. AX460 ph Analyzer AX46x Analyzer/Wash Controller Sensor Cables Pump Control Signal Reagent Tank Current Power Supply Power Supply Contact Cleaning Agent Tubes 1 or 2 Sensor Systems Reagent Pump Stroke Position Adjusted Automatically by Controller Sample Sample Stirrer Electrode System Sample AA010 Sensor Cleaning Station AX460 Integral P, PI, and PID Control Efficient Auto-cleaning Control for One or Two Sensor Systems Combined Conductivity and ph The AX416 version measures conductivity and ph with the same analyzer. The option board provides the capability to retransmit ph, conductivity and both sample temperatures. Five programmable alarms can be assigned to suit the needs of the application, enabling even the most demanding requirements to be met. Current Proportional Control In this case, the control signal is provided by the 4 to 20mA output of the AX460 analyzers rather than using the alarm/control contacts. The magnitude of the current output changes in proportion to the deviation from set point. This method is used generally with motorized valves or when controlling the speed of dosing pumps with a 4 to 20mA proportional input. 20 Current (ma) 4 Time Simultaneous Conductivity and ph Measurement Current Acting Control 4 DS/AX4PH EN Rev. K

Time Proportioning Control (Pulse Length) With time proportioning control, the AX460 analyzerõs control signal output is in pulses, the duration of which changes in proportion to the system error. The pulses are delivered by varying the length of time that the alarm/control contact is activated. Time Proportioning Control is used generally to control dosing by low-cost solenoid valves or metering pumps and is also known as pulse-length proportional or Mark Space control. Energized De-energized Energized De-energized Energized De-energized 2.5 seconds Time Proportioning Control Permanently De-energized 5 seconds 7.5 seconds 7.5 seconds 5 seconds Cycle time = 10 seconds 2.5 seconds = 0% = 25% = 50% = 75% Bi-directional Control As well as single set point control for both acid and base addition, the AX460 analyzer can be configured with independent controllers. To avoid control overlap, a minimum of 0.5pH difference (or deadband) between the set points is essential. The difference between the set points varies depending upon the application. Control of each set point can be configured independently as either P or PI control in this mode. The setting of proportional band or integral action can also be different for each set point. Pulse-frequency Proportional Control Impulse pumps dosing chemical reagents are controlled easily by the AX460 analyzerõs pulse-frequency proportional control output. In this case, the pulse length of the alarm/control contact is fixed and the frequency of the delivered pulses increases in proportion to the system error, as set by the proportional band. Diaphragm metering pumps must have a remote pulse input capability in order to utilize this function. Pulse-frequency control in the AX460 analyzer operates by pulsing a relay on for 300ms and off for a period of time determined by the pulse frequency. The pulse frequency (PFr) is adjustable between 1 and 120 pulses per minute. The greater the difference between the measured variable and the set point the greater the pulse frequency. Example If the pulse frequency is set at 120 pulses per minute and the percentage output is 100% then the pulse rate is 2 pulses per second. If the percentage output is reduced to 50%, the pulse rate falls to one pulse per second. = 0% Energized = 50% De-energized Energized = 100% De-energized Pulse-frequency Proportional Control Permanently De-energized 0.3s 0.7ms 0.3s 0.2s 0.3s 0.2s Pulse Frequency = 120 pulses per minute 100% Control Low Set Point High Set Point Power Failure Recovery In the event of a power failure the user can configure the control mode to be Auto, Manual or Last. This optimizes control conditions on power-up to ensure rapid recovery of process control. 0% 0 ph 14 Bi-directional Control DS/AX4PH EN Rev. K 5

Specification ph/redox (ORP) AX460 and AX466 Inputs One or two* ph or mv inputs and solution earth One or two* temperature sensors Enables connection to glass or enamel ph and reference sensors and Redox (ORP) sensors *AX466 only Input resistance Glass >1 x 10 13 Reference 1 x 10 13 Range 2 to 16pH or 1200 to +1200mV Minimum span Any 2pH span or 100mV Resolution 0.01pH Accuracy 0.01pH Temperature compensation modes Automatic or manual Nernstian compensation Range 10 to 200 C (14 to 392 F) Process solution compensation with configurable coefficient Range 10 to 200 C (14 to 392 F) adjustable 0.05 to +0.02%/ C ( 0.02 to +0.009%/ F) Temperature sensor Programmable Pt100, Pt1000 or Balco 3k Calibration Ranges Check value (zero point) 0 to 14pH Slope Between 40 and 105% (low limit user-configurable) Electrode Calibration Modes Calibration with auto-stability checking Automatic 1 or 2 point calibration selectable from: ABB DIN Merck NIST US Tech 2 x user-defined buffer tables for manual entry, 2-point calibration or single-point process calibration Conductivity AX416 Only Range Programmable 0 to 0.5 to 0 to 10,000µS/cm (with various cell constants) Minimum span 10 x cell constant Maximum span 10,000 x cell constant Units of measure µs/cm, µs/m, ms/cm, ms/m, M -cm and TDS Accuracy Better than ±0.01% of span (0 to 100µS/cm) Better than ±1% of reading (10,1000µS/cm) Operating temperature range 10 to 200 C (14 to 392 F) Temperature compensation 10 to 200 C (14 to 392 F) Temperature coefficient Programmable 0 to 5%/ C and fixed temperature compensation curves (programmable) for acids, neutral salts and ammonia Temperature sensor Programmable Pt100 or Pt1000 Reference Temperature 25 C (77 F) Display Type Dual 5-digit, 7-segment backlit LCD Information 16-character, single line dot-matrix Energy-saving function Backlit LCD configurable as ON or Auto-Off after 60s Logbook* Electronic record of major process events and calibration data Real-time clock* Records time for logbook and auto-manual functions *Available if option board is fitted 6 DS/AX4PH EN Rev. K

Relay s On/Off Number of relays Three supplied as standard or five with option board fitted Number of set points Three supplied as standard or five with option board fitted Set point adjustment Configurable as normal or failsafe high/low or diagnostic alert Hysteresis of reading Programmable 0 to 5% in 0.1% increments Delay Programmable 0 to 60s in 1s intervals Relay contacts Single-pole changeover Rating 5A, 115/230V AC, 5A DC Insulation 2kV RMS contacts to earth/ground Analog s Number of current outputs (fully isolated) Two supplied as standard or four with option board fitted ranges 0 to 10mA, 0 to 20mA or 4 to 20mA Analog output programmable to any value between 0 and 22mA to indicate system failure Accuracy ±0.25% FSD, ±0.5% of reading (whichever is the greater) Resolution 0.1% at 10mA, 0.05% at 20mA Maximum load resistance 750 at 20mA Configuration Can be assigned to either measured variable or either sample temperature Digital Communications Communications Profibus DP (with option board fitted) Control Function AX460 Only Controller Type P, PI, PID (configurable) Control s Can be assigned a maximum of two relays, two analog outputs, or one of each Analog Current output control (0 to 100%) Time proportioning cycle time 1.0 to 300.0s, programmable in increments of 0.1s Pulse frequency 1 to 120 pulses per minute, programmable in increments of 1 pulse per minute Controller action Reverse, direct or bi-directional (programmable) Proportional band 0.1 to 999.9%, programmable in increments of 0.1% Integral action time (Integral reset) 1 to 7200s, programmable in increments of 1s (0 = Off) Derivative 0.1 to 999.9s programmable in increments of 0.1s, available only for single set point control Auto/Manual User-programmable Access to Functions Direct keypad access Measurement, maintenance, configuration, diagnostics and service functions Performed without external equipment or internal jumpers Sensor Cleaning Function Configurable cleaning action relay contact Continuous Pulse in 1s on and off times Frequency 5 minutes to 24 hours, programmable in 15 minute increments up to 1 hour then in 1 hour increments for 1 to 24 hours Duration 15s to 10 minutes, programmable in 15s increments up to 1 minute then in 1 minute increments up to 10 minutes Recovery period 30s to 5 minutes, programmable in 30s increments DS/AX4PH EN Rev. K 7

Mechanical Data Wall-/Pipe-mount versions IP65 (not evaluated under UL certification) Dimensions 192mm high x 230mm wide x 94mm deep (7.56 in. high x 9.06 in. wide x 3.7 in. deep) Weight 1kg (2.2 lb) Panel-mount versions IP65 (front only) Dimensions 96mm x 96mm x 162mm deep (3.78 in. x 3.78 in. x 6.38 in. deep) Weight 0.6kg (1.32 lb) Cable Entry Types Standard North American 5 or 7 x M20 cable glands 7 x knockouts suitable for 1 /2 in. Hubble gland Power Supply Voltage requirements 100 to 240V AC 50/60 Hz (90 V Min. to 264 V Max. AC) 12 to 30V DC Power consumption 10 W Insulation Mains to earth (line to ground) 2kV RMS Environmental Data Operating temperature limits 20 to 55 C ( 4 to 131 F) Storage temperature limits 25 to 75 C ( 13 to 167 F) Operating humidity limits Up to 95%RH non condensing EMC Emissions and immunity Meets requirements of: EN61326 (for an industrial environment) EN50081-2 EN50082-2 Approvals, Certification and Safety Safety approval UL CE Mark Covers EMC & LV Directives (including latest version EN 61010) General safety EN61010-1 Overvoltage Class II on inputs and outputs Pollution category 2 Languages Languages configurable: English French German Italian Spanish 8 DS/AX4PH EN Rev. K

Overall Dimensions Dimensions in mm (in.) R10 (0.4) 210 (8.27) 192 (7.56) 96 (3.78) 61mm (2 3 /8 in.) OD Vertical or Horizontal Post 150 (5.9) 175 (6.9) 192 (7.56) Ø6.50 (0.26) 25 (1) 23 (0.9) 25 (1) 94 (3.7) Pipe-mount Detail 22.5 22.5 (0.88) (0.88) 45 (1.77) 45 (1.77) 67.5 (2.66) 67.5 (2.66) Wall-/Pipe-mount Version Dimensions in mm (in.) 91.60 (3.60) 137.50 (5.41) 25 (1) 96 (3.77) 91.60 (3.60) 96 (3.77) 5.40 (0.21) Panel-mount Version DS/AX4PH EN Rev. K 9

Electrical Connections Wall-/Pipe-mount Version Panel-mount Version Terminal Block A Terminal Block C (Analog Option Board) Terminal Block C (Analog Option Board) Terminal Block B Common Third Lead Temperature Compensator Earth (Ground) Stud Terminal block A L Live N Neutral E Earth A4 C A5 NC Relay 1 A6 NO A7 C A8 NC Relay 2 A9 NO A10 C A11 NC Relay 3 A12 NO A13 + Analog output 1 A14 A15 + Analog output 2 A16 Terminal Block A Terminal Block B Terminal Block C (Analog Option Board) C1 Not used C2 Not used C3 Profibus DP A C4 Profibus DP B C5 Profibus Earth C6 Not used C7 C C8 NC Relay 4 C9 NO C10 C C11 NC Relay 5 C12 NO C13 + Analog output 3 C14 C15 + Analog output 4 C16 Terminal Block B (see table below) B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 B13 B14 B15 B16 Terminal Block B Sensor B Sensor A 1 9 ph/redox (ORP) without Solution Earth Temperature Compensator common* Link 1 & 2 / 9 & 10** ph/redox (ORP) with Solution Earth Temperature Compensator common* Link 1 & 2 / 9 & 10** Conductivity Temperature Compensator common Link 1 & 2 / 9 & 10** 2 10 Temperature Compensator third lead* Temperature Compensator third lead* Temperature Compensator third lead 3 11 Temperature Compensator* Temperature Compensator* Temperature Compensator 4 12 Not applicable Reference Electrode Screen 5 13 Not used Not used Cell (Cell Electrode) 6 14 Reference Electrode Solution Earth Cell (Earth Electrode) 7 15 Screen* Screen* Not used 8 16 Glass/Metal Electrode Glass/Metal Electrode Not used *If fitted. **When a 2-wire Pt100, Pt1000 or BALCO temperature compensator is fitted. Solution Earth also referred to as Ground Rod. 10 DS/AX4PH EN Rev. K

Ordering Information Single and Dual Input Analyzers for ph/redox (ORP) and Conductivity Models AX460, AX466 & AX416 AX4 X X X X X 0 X First Process Variable (PV1) Conductivity 0 to 10,000µS cm 1 for 2-electrode sensors Conductivity 0 to 1,999mS cm 1 for 4 electrode sensors Conductivity USP<645> for 2-electrode sensors ph/redox (ORP) Dissolved Oxygen Second Process Variable (PV2)* No second process variable select for PID control of PV1 Conductivity 0 to 10,000µS cm 1 for 2-electrode sensors Conductivity 0 to 1,999mS cm 1 for 4-electrode sensors** Conductivity USP<645> for 2-electrode sensors ph/redox (ORP) Dissolved Oxygen Enclosure Types Wall-mount IP65, General Wall-mount cable glands fitted Pipe-mount Wall-mount IP65, North American Wall-mount Pipe-mount Panel-mount, Universal Panel-mount** 5 Advanced Functions & Communications Basic (2 current outputs + 3 relays) Advanced (4 current outputs + 5 relays + logbook) Profibus DP, basic (2 current outputs + 3 relays)** Profibus DP, advanced (4 current outputs + 5 relays + logbook)** Power Supply 100 to 240V AC 50 to 60Hz 12 to 30V DC Reserved 0 Manual English French Italian German Spanish * When ordering units with a second process variable (PV2) the code digit for PV2 in the order code number must be equal to, or greater than, the code digit for PV1, e.g. AX416 permissible, AX461 not permissible. ** Profibus DP not available in panel-mount housing when 0 to 1,999mS/cm is selected as Second Process Variable (PV2). 1 3 5 6 8 0 1 3 5 6 8 1 2 6 7 0 1 2 3 0 1 1 2 3 4 5 DS/AX4PH EN Rev. K 11

Contact us ABB Limited Process Automation Oldends Lane Stonehouse Gloucestershire GL10 3TA UK Tel: +44 1453 826 661 Fax: +44 1453 829 671 ABB Inc. Process Automation 125 E. County Line Road Warminster PA 18974 USA Tel: +1 215 674 6000 Fax: +1 215 674 7183 Note We reserve the right to make technical changes or modify the contents of this document without prior notice. With regard to purchase orders, the agreed particulars shall prevail. ABB does not accept any responsibility whatsoever for potential errors or possible lack of information in this document. We reserve all rights in this document and in the subject matter and illustrations contained therein. Any reproduction, disclosure to third parties or utilization of its contents in whole or in parts is forbidden without prior written consent of ABB. Copyright 2011 ABB All rights reserved 3KXA162401R1001 DS/AX4PH EN Rev. K 03.2011 www.abb.com