SDS-338R44-A-E0 SAFETY DATA SHEET (SDS) 1. IDENTIFICATION Manufacturer's Information; Nippon Sheet Glass Co., LTD. Technical Glass Strategic Business Unit / Quality Assurance Department. Address: 4902 Komoricho Takachaya Tsu-City Mie Pref. Japan, Zip Code 514-0817 Emergency Telephone: +81-59-238-1126(8:00-17:00; Japan time), Fax +81-59-234-7676 Person in charge: Takeshi AMARI, e-mail: takeshi.amari@nsg.com Date of Preparation: May. 28, 2015 Product Name(Trade Name) MICROGLAS METASHINE GT/ ST@@@@RCJ4 (RSJ4, RYJ4, RRJ4, RBJ4 RGJ4) Recommended use of the chemical and restrictions on use Colorants for industrial use 2. HAZARDS IDENTIFICATION * The following GHS product classifications are referenced to the classification information of NITE (Japan National Institute of Technology and Evaluation), EU CLP inventory, OSHA, KOSHA and so on. If you want to refer to more detail information, please refer to the Section 15. Classification (Hazard and Category): None GHS label elements: Pictogram, Signal Word, Hazard Statement and code None Hazards Otherwise Classified If glass flake dust levels are high, measures to avoid exposure to the glass flake should be taken. (See SECTION 8) Material Name MICROGLAS METASHINE GT1/ ST-RCJ4 Page 1 of 6
3. COMPOSITION/INFORMATION ON INGREDIENTS Description: Mixture of substances listed below. Chemical name: Composition (wt%) Ingredient Titanium Tin Metal Metal Organic Product code Glass dioxide dioxide hydroxide oxide silane GT1080RSJ4 84~94 6~16 <0.1 <0.7 <0.3 <0.1 GT1080RYJ4 79~89 11~21 <0.1 <0.7 <0.3 <0.1 GT1080RRJ4 75~85 15~25 <0.1 <0.7 <0.3 <0.1 GT1080RBJ4 69~79 21~31 <0.1 <0.7 <0.3 <0.1 GT1080RGJ4 66~76 24~34 <0.1 <0.7 <0.3 <0.1 GT1040RSJ4 84~94 6~16 <0.1 <0.7 <0.3 <0.1 GT1040RYJ4 79~89 11~21 <0.1 <0.7 <0.3 <0.1 GT1040RRJ4 75~85 15~25 <0.1 <0.7 <0.3 <0.1 GT1040RBJ4 69~79 21~31 <0.1 <0.7 <0.3 <0.1 GT1040RGJ4 66~76 24~34 <0.1 <0.7 <0.3 <0.1 GT1030RSJ4 84~94 6~16 <0.1 <0.7 <0.3 <0.1 GT1030RYJ4 79~89 11~21 <0.1 <0.7 <0.3 <0.1 GT1030RRJ4 75~85 15~25 <0.1 <0.7 <0.3 <0.1 GT1030RBJ4 69~79 21~31 <0.1 <0.7 <0.3 <0.1 GT1030RGJ4 66~76 24~34 <0.1 <0.7 <0.3 <0.1 GT1020RSJ4 84~94 6~16 <0.1 <0.7 <0.3 <0.1 GT1020RYJ4 79~89 11~21 <0.1 <0.7 <0.3 <0.1 GT1020RRJ4 75~85 15~25 <0.1 <0.7 <0.3 <0.1 GT1020RBJ4 69~79 21~31 <0.1 <0.7 <0.3 <0.1 GT1020RGJ4 66~76 24~34 <0.1 <0.7 <0.3 <0.1 ST1025RSJ4 84~94 6~16 <0.1 <0.7 <0.3 <0.1 ST1025RYJ4 79~89 11~21 <0.1 <0.7 <0.3 <0.1 ST1025RRJ4 75~85 15~25 <0.1 <0.7 <0.3 <0.1 ST1025RBJ4 69~79 21~31 <0.1 <0.7 <0.3 <0.1 ST1025RGJ4 66~76 24~34 <0.1 <0.7 <0.3 <0.1 ST1018RSJ4 84~94 6~16 <0.1 <0.7 <0.3 <0.1 ST1018RYJ4 79~89 11~21 <0.1 <0.7 <0.3 <0.1 ST1018RRJ4 75~85 15~25 <0.1 <0.7 <0.3 <0.1 ST1018RBJ4 69~79 21~31 <0.1 <0.7 <0.3 <0.1 ST1018RGJ4 66~76 24~34 <0.1 <0.7 <0.3 <0.1 *GT/ST : TA-glass Structure: Glass; Amorphous anastomosis, Titanium dioxide; TiO2, Tin dioxide; SnO2 Metal hydroxide, Metal oxide, Organic silane : Trade Secret* *The Trade Secret conforms to paragraph 1910.1200(i) of US HCS 2012 (Standard 29 CFR, PART 1910). Material Name MICROGLAS METASHINE GT1/ ST-RCJ4 Page 2 of 6
Substance information: Glass Titanium Tin Metal Metal Organic dioxide dioxide hydroxide oxide silane CAS number 65997-17-3 13463-67-7 18282-10-5 Registered Registered Registered TSCA number 65997-17-3 13463-67-7 18282-10-5 Registered Registered Registered EINECS number 266-046-0 236-675-5 242-159-0 Registered Registered Registered UN Classification/number 4. FIRST AID MEASURES Inhalation: Rinse out your mouth with water about 10 times. Also, blow your nose lightly. If itching or pain persists in your nose or throat, consult physician. Skin contact: Do not rub. Rinse contacted areas with room temperature to cool water, then wash gently with mild soap. Taking a bath is effective for removing. Eye contact: Flush with clear water for at least 15 minutes - seek medical attention for prolonged pain. Swallowing: First induce vomiting to get rid of it up. Then, rinse your mouth with water. If you fail to vomit it up, consult physician. This product is intended for industrial applications; in the unlikely event that this product is swallowed, consult a physician if any adverse medical conditions occur. 5. FIRE FIGHTING MEASURES Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. Protective equipment: No special measures required. Others: MICROGLAS METASHINE itself is not flammable. 6. ACCIDENTAL RELEASE MEASURES Person-related safety precautions: required. Measures for environmental protection: No special measures required. Measures for cleaning/collecting: Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. 7. HANDLING AND STORAGE Handling: Information for safe handling: Prevent formation of dust. Wear the protective gloves, glasses (preferably goggle type) and dust respirator (officially approved replacement of disposable type) Information about fire - and explosion protection: No special measures required. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: required Further information about storage conditions: Store in its original packaging in a clean, dray area, away from direct sunlight, high temperature or high humidity. Material Name MICROGLAS METASHINE GT1/ ST-RCJ4 Page 3 of 6
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Limits: Glass flake dust ACGIH (2003) TLV 10mg/M 3 (Inhalable Particulate) 3mg/M 3 (Respirable Particulate) OSHA (2000) PEL (8-hr TWA) None established (5mg/M 3 ; respirable nuisance dust) Titanium dioxide ACGIH (2009) TLV-TWA 10mg/M 3 OSHA (2000) 15mg/M 3 (total dust) Tin dioxide ACGIH (2003) TLV 2mg/M 3 NIOSH REL-TWA 2mg/M 3 Respiratory protection: If glass flake dust levels are high, respiratory protection for nuisance dust should be provided. Ventilation: Mechanical, general, or local exhaust may be required in some operations. Eye protection: Wear safety glasses with side shields if necessary. Protective gloves: Wear protective gloves such as leather ones. May reduce skin irritation in some operations. Protective clothing: Use of long sleeved shirts, buttoned to fit at the neck and wrists, long pants, and good personnel hygiene will maximize comfort. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Solid (Flake particle) Odour: No specific odor. ph: Melting point: No data for the mixture. Ref) Approx. 880 deg C [TA glass] (Softening point) Initial boiling point and boiling range: Flash point: Upper/lower flammability or explosive limits: Vapor pressure: Relative density: Approx. 2.5 ~ 3.2 (bulk) Ref) TA glass; 2.6, titanium dioxide; 4.26 Solubility in water: Nil Partition coefficient: n-octanol/water: Auto-ignition temperature: Decomposition temperature: No data 10. STABILITY AND REACTIVITY Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications. Dangerous reactions: No dangerous reactions known Dangerous decomposition products: No dangerous decomposition products known. Material Name MICROGLAS METASHINE GT1/ ST-RCJ4 Page 4 of 6
11. TOXICOLOGICAL INFORMATION Acute toxicity (Oral): Out of category for the mixture. Ref) TiO2: rat LD50 > 10000mg/kg [IUCLID (2000)], SnO2: rat LD50 > 20000mg/kg, mouse: LD50 > 20000mg/kg Acute toxicity (Dermal): Out of category for the mixture. Ref) TiO2: rabbit LD50 > 10000mg/kg [IUCLID (2000)], SnO2: rat LD50 > 6600mg/kg, mouse: LD50 > 6600mg/kg Acute toxicity (Inhalation): None known Skin corrosion/irritation: Out of category for the mixture. Eye damage/irritation: Out of category for the mixture. Sensitization - Respiratory: Cannot be categorized for the mixture. Sensitization - Skin: Out of category for the mixture. Germ cell mutagenicity: Out of category for the mixture. Ref) TiO2: negative on a mouse micronucleus examination and mouse chromosome aberration examination [NTP DB (2005)] Carcinogenicity: Out of category*. Ref) Continuous glass fibre; IARC: Group 3, ACGIH: A4 TiO2; IARC: Group 2B (10~50nm), ACGIH: A4 * TiO2 of 10~50nm particle size is categorized 2B by IARC but this series TiO2 is not within these range. Toxic to reproduction: None known Specific target toxicity (single exposure): Out of category for the mixture. Specific target toxicity (repeated exposure): Out of category for the mixture. Aspiration hazard: None known. Additional toxicological information: Glass is stable and any free silicic acid has not been detected in glass by the existing analysis method. 12. ECOLOGICAL INFORMATION Hazardous to the aquatic environment (acute): classified due to lack of data for the mixture. Hazardous to the aquatic environment acute (chronic): classified due to lack of data for the mixture. Hazardous to the ozone layer: Out of category for the mixture. 13. DISPOSAL CONSIDERATIONS Disposal procedures for solid waste: in accordance with local, state, and federal regulations. 14. TRANSPORT INFORMATION These products are not classified as dangerous goods according to international transport regulations. Avoid wetting or other careless handling to maintain product quality. 15. REGULATORY INFORMATION < Classifications for the product > As described above, the product(s) is not classified for the mixture ( Out of category or Can not be categorized for the mixture.), for example, U.S. under regulation U.S. HCS 2012 (29 CFR PART 1910), Material Name MICROGLAS METASHINE GT1/ ST-RCJ4 Page 5 of 6
China under regulation GB13690-2009, Republic of Korea under ISHA and CCA, EU* under CLP regulation (REGULATION (EC) No 1272/2008) and so on. * REACH registration number - (glass; exempted according to Annex V, other components; less than 1t/y at present) < Other regulations > - U.S. Federal and State Regulations - TSCA 8(b) inventory: All substances are listed. - U.S. OSHA: Listed in 1910.1000 TABLE Z-1 - Limits for Air Contaminants - Titanium dioxide - Illinois toxic substances disclosure to employee act, Rhode Island RTK hazardous substances, Pennsylvania RTK, Minnesota, Massachusetts RTK, New Jersey - Titanium dioxide - Canadian Regulations - Canada WHMIS: D2A [* TiO2 of 10~50nm particle size is categorized 2B by IARC but this series TiO2 is not within these range.] - Titanium dioxide 16. OTHER INFORMATION This information is based on our current level of knowledge, related to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee particular properties. Material Name MICROGLAS METASHINE GT1/ ST-RCJ4 Page 6 of 6