Tel: +27 (0) 11 923 0800 Fax: +27 (0) 11 392 4715 web: www.amis.co.za 11 Gewel Street (off Hulley Road), D1 Isando Business Park, Kempton Park, 1609 P.O. Box 856, Isando, 1600, Gauteng, South Africa AMIS0409 Certified Reference Material Cu Silver Concentrate Boseto Copper Mine, Botswana Certificate of Analysis Recommended Concentrations and Limits 1. (at two Standard Deviations) Certified Concentrations 2. Cu M/ICP 33.74 ± 1.06 % Cu Titration 34.39 ± 0.42 % Au Pb Collection 0.75 ± 0.08 g/t Ag M/ICP 544 ± 29 g/t Fe M/ICP 3.68 ± 0.30 % Specific Gravity 3.57 ± 0.16 Indicated Means Cl Leach 1549 ppm F ISE 433 ppm 1. Manufacturers recommended limits for use of the material as control samples, based on two standard deviations, calculated using Between Laboratory statistics for treatment of the data for trivial, non-trivial and technically invalid results. See sections 1, 9 and 12. 2. There is additional certified major element data presented on p2 and uncertified trace element data presented as an appendix. Directors: GJ Horsfield (CEO), MD Evers (CFO)(British), A Buddingh, K Gerber, SJ Ingram M McWha, N Robinson, V Singh, MH Snelling, D Steenkamp (alt), J Vassiloudis
Major Element Recommended Concentrations and Limits (at two Standard Deviations) Certified Concentrations (Mixed XRF and ICP data) Al 2 O 3 5.88 ± 0.36 % CaO 3.39 ± 0.10 % Fe 2 O 3 5.32 ± 0.42 % K 2 O 1.22 ± 0.10 % MgO 1.64 ± 0.10 % MnO 0.16 ± 0.01 % Na 2 O 1.28 ± 0.12 % S Comb/LECO 8.48 ± 0.30 % Indicated Means Cr 2 O 3 0.27 % TiO 2 0.51 % 1. Intended Use: AMIS0409 can be used to check analysis of samples of copper-silver concentrates with a similar grade and matrix. It is a matrix matched Certified Reference Material (CRM) fit for use as control samples in routine assay laboratory quality control when inserted within runs of samples and measured in parallel to the unknown. Its purpose is to monitor inter-laboratory or instrument bias and within lab precision. It can be used, indirectly, to establish the traceability of results to an SI system of units. The recommended concentrations and limits for this material are property values based on a measurement campaign (round robin) and reflect consensus results from the laboratories that participated in the round robin. Slight variations in analytical procedures between laboratories will reflect as slight biases to the recommended concentrations (see 19). Good laboratories will report results within the two standard deviation levels with a failure rate of <10 %. The material can also be used for method development and for the calibration of equipment. 2. Origin of Material: The concentrate material for AMIS0409 was supplied by Discovery Metals and is from their Boseto Copper Project, located in north western Botswana, 75 kilometres south west of Maun. 3. Mineral and Chemical Composition: The Kalahari Copperbelt sedimenthosted mineralisation of the Boseto copper project is similar in style to the well-known and large deposits of the Central African Copperbelt of Zambia and the Democratic Republic of the Congo. The mine is part of the Ghanzi-Chobe fold belt, which is a 140km-wide zone of deformation within the late Proterozoic Pan African Mobile Belt. Copper and silver mineralisation occured along a stratigraphic redox boundary, between continental sedimentary hosted red beds and overlying marine siliciclastic s, which was then hydrothermally remobilized into extensive networks of bedding-parallel and discordant quartz-carbonate (Cu-Fe-sulphide) veins. The copper mineralisation is mainly in the form of chalcocite. Minor amounts of bornite and other copper sulphides are also found. (ref Wesley S. Hall, 2012 (?) Geology and paragenesis of the Boseto Copper Deposits, Kalahari Copperbelt, Northwest Botswana. MSc Thesis submitted to the Colorado School of Mines. http://digitool.library.colostate.edu///exlibris/dtl/d3_1/apache_media/l2v4bglicmlzl2r0bc9km18xl 2FwYWNoZV9tZWRpYS8yMDc4MzI=.pdf) 2
4. Appearance: The material is a very fine powder. It is colored Dark Grey 5. Handling instructions: The material is packaged in Laboratory Packs and Explorer Packs that must be shaken or otherwise agitated before use. Normal safety precautions for handling fine particulate matter are suggested, such as the use of safety glasses, breathing protection, gloves and a laboratory coat. 6. Method of Preparation: The material was crushed, dry-milled and air-classified to <54um. Wet sieve particle size analysis of random samples confirmed the material was 98.5% <54um. It was then homogenized in a double cone blender, systematically divided and sealed into 1kg Laboratory Packs. Explorer Packs are subdivided from the Laboratory packs as required. Samples were randomly selected for homogeneity testing and third party analysis. Statistical analysis of both homogeneity and consensus test results were carried out by an independent statistician. 7. Methods of Analysis requested: 1. Au Pb collection AAS or ICP-OES. 2. Ag AAS. 3. Multi acid digest, ICP-OES multi element scan. 4. Cu Titration. 5. S combustion IR. 6. F by ISE. 7. Fusion XRF -Majors (Cl, F, Al 2 O 3, CaO, Cr 2 O 3, Fe 2 O 3, K 2 O, MgO, MnO, Na 2 O, SiO 2, TiO 2. LOI. ). 8. SG. Gas pycnometer. 8. Information requested: 1. State and provide brief description of analytical techniques used. 2. State aliquots used for all determinations. 3. Results for individual analyses to be reported. 4. All results for base metals to be reported in ppm. 5. Report all QC data, to include replicates, blanks and certified reference materials used. 9. Method of Certification: Twenty five laboratories were each given eight packages, comprising eight samples scientifically selected from throughout the batch. Nineteen laboratories reported results in time for certification Final limits were calculated after first determining if all data was compatible within a spread normally expected for similar analytical methods done by reputable laboratories. Data from any one laboratory was then removed from further calculations when the mean of all analyses from that laboratory failed a t test of the global means of the other laboratories. The means and standard deviations were then re-calculated using all remaining data. Any analysis that fell outside of the new two standard deviations was removed from the ensuing data base. The mean and standard deviations were again calculated using the remaining data. The between-laboratory standard deviation is used in the calculation to eliminate technically and statistically invalid data. Upper and lower limits are based on the standard deviation of the remaining data, which reflect individual analyses and can be used to monitor accuracy in routine laboratory quality control. This is different to limits based on standard deviations derived from grouped set of analyses (see 12), which provide important measures for precision and trueness, but which are less useful for routine QC. Standards with an RSD of near or less than 5 % are termed Certified, RSD s of between near 5 % and 15 % are termed Provisional, and RSD s over 15 % are termed Informational. 3
10. Participating Laboratories: The 19 out of 25 laboratories that provided results timeously were (not in same order as in the table of assays): 1. Acme Analytical Laboratories Chile 2. ACME Analytical Laboratories Ltd CA 3. Activation Laboratories Pty Ltd (ActLabs) CA 4. ALS Ammtec (Australia) 5. ALS Chemex Laboratory Group Johannesburg SA 6. ALS Chemex Laboratory Group Perth WA 7. ALS Chemex Laboratory Group Vancouver CA 8. ALS OMAC (Ireland) 9. Genalysis Laboratory Services (W Australia P) 10. Namibia Custom Smelters 11. Set Point Laboratories (Isando) SA 12. Set Point Laboratories Botswana 13. SGS Australia Pty Ltd (Newburn) WA 14. SGS Geosol Laboratories Ltda (Brazil) 15. SGS Mineral Services Callao (Peru) 16. SGS Mineral Services Lakefield (Canada) 17. SGS Prominent Hill Australia (AU) 18. SGS Vancouver (Canada) 19. Ultra Trace (Pty) Ltd WA 11. Assay Data: Data as received from the laboratories for the important certified elements listed on p1 is set out below. Lab Au Ag Cu Cu F Fe Cl Al 2 O 3 CaO Cr 2 O 3 Fe 2 O 3 K 2 O MgO MnO Na 2 O TiO 2 S SG Code Pb Coll M/ICP M/ICP Titration ISE M/ICP Leach XRF XRF XRF XRF XRF XRF XRF XRF XRF Comb/LECO pyc g/t ppm % % ppm % ppm % % % % % % % % % % A 0.73 532 34.6 34.3 500 3.78 2000 6.03 3.42 0.32 5.42 1.24 1.70 0.16 1.32 0.62 3.63 A 0.76 538 34.2 34.3 500 3.80 2000 6.05 3.40 0.32 5.42 1.23 1.69 0.16 1.31 0.62 3.67 A 0.72 531 34.1 34.3 500 3.76 2000 6.05 3.41 0.32 5.40 1.24 1.69 0.16 1.29 0.62 3.64 A 0.72 531 34.0 34.3 500 3.75 2000 6.05 3.42 0.32 5.42 1.24 1.70 0.16 1.29 0.62 3.60 A 0.72 527 34.1 34.3 500 3.82 2000 6.04 3.41 0.32 5.41 1.24 1.71 0.16 1.29 0.62 3.62 A 0.71 527 34.6 34.3 500 3.80 2000 6.03 3.40 0.32 5.41 1.24 1.70 0.15 1.32 0.62 3.67 A 0.77 528 34.0 34.3 500 3.78 2000 6.04 3.42 0.32 5.40 1.24 1.70 0.16 1.31 0.62 3.65 A 0.72 535 34.2 34.2 500 3.80 2000 6.03 3.39 0.32 5.38 1.23 1.70 0.16 1.31 0.62 3.61 B 0.77 566 38.8 3.68 5.75 3.54 0.27 5.25 1.71 0.16 1.21 3.44 B 0.69 564 33.0 3.47 5.63 3.38 0.28 4.96 1.61 0.16 1.24 3.37 B 0.79 562 38.8 3.69 5.73 3.49 0.26 5.27 1.71 0.16 1.21 3.31 B 0.75 548 33.4 3.51 5.65 3.40 0.25 5.02 1.62 0.16 1.20 3.36 B 0.79 553 33.3 3.47 5.59 3.37 0.29 4.96 1.60 0.16 1.22 3.33 B 0.22 550 33.1 3.52 5.62 3.41 0.25 5.03 1.62 0.16 1.21 3.35 B 0.74 553 33.2 3.45 5.54 3.36 0.25 4.94 1.60 0.16 1.23 3.30 B 0.70 553 40.0 3.72 5.77 3.56 0.25 5.31 1.72 0.16 1.21 3.28 C 0.80 547 31.1 34.4 300 3.97 5.33 3.46 0.23 5.68 1.25 1.62 0.17 1.31 8.36 3.50 C 0.83 548 31.0 34.3 300 3.90 5.39 3.41 0.23 5.58 1.23 1.61 0.17 1.28 8.23 3.48 C 0.83 544 30.0 34.5 400 3.93 5.61 3.40 0.22 5.62 1.24 1.62 0.17 1.29 8.56 3.49 C 0.74 543 31.4 34.8 400 3.90 5.74 3.44 0.23 5.58 1.24 1.62 0.17 1.29 8.34 3.48 C 0.81 545 30.8 34.4 400 3.91 5.48 3.39 0.23 5.59 1.24 1.61 0.17 1.28 8.42 3.50 C 0.79 549 30.3 34.7 300 3.90 5.54 3.40 0.23 5.58 1.24 1.61 0.17 1.29 7.95 3.48 C 0.80 544 31.5 34.4 300 3.95 5.80 3.46 0.23 5.65 1.25 1.64 0.17 1.31 8.22 3.49 C 0.79 541 31.3 34.3 300 3.96 5.90 3.47 0.23 5.66 1.25 1.64 0.17 1.31 8.35 3.48 D 0.82 555 35.2 415 3.58 880 D 0.72 585 35.5 440 3.63 895 D 0.75 591 35.3 455 3.55 890 D 0.72 573 35.3 435 3.63 890 D 0.77 593 35.4 425 3.60 895 D 0.73 586 35.1 440 3.53 880 D 0.71 610 35.2 430 3.67 910 D 0.72 584 35.0 455 3.50 895 E 0.83 529 34.8 35.0 410 3.70 1050 8.60 E 0.82 525 34.0 35.1 450 3.66 1080 8.53 E 0.82 519 33.7 34.9 400 3.54 960 8.47 E 0.80 528 34.0 34.9 390 3.62 1020 8.47 E 0.82 529 34.3 34.7 450 3.74 970 8.61 E 0.82 517 33.9 34.8 410 3.64 1050 8.46 E 0.83 529 34.3 34.8 430 3.71 1100 8.34 E 0.80 522 34.2 34.9 390 3.60 1070 8.45 F 0.74 565 34.6 34.3 460 8.51 3.61 F 0.76 562 33.6 34.4 470 8.29 3.69 F 0.71 564 33.3 34.5 450 8.42 3.56 F 0.72 563 33.8 34.4 460 8.44 3.65 F 0.69 566 33.3 34.4 460 8.49 3.49 F 0.76 560 34.6 34.4 450 8.39 3.64 F 0.76 564 34.0 34.3 460 8.60 3.64 F 0.78 556 33.8 34.3 460 8.36 3.58 H 0.78 549 34.3 3.72 9.07 H 0.79 556 34.4 3.70 9.07 H 0.77 546 34.3 3.74 8.81 H 0.75 545 34.3 3.81 8.97 H 0.77 543 34.3 3.75 8.71 H 0.75 551 34.3 3.71 8.97 H 0.75 544 34.3 3.73 9.09 H 0.78 547 34.3 3.72 8.86 4
Assay data Lab Au Ag Cu Cu F Fe Cl Al 2O 3 CaO Cr 2O 3 Fe 2O 3 K 2O MgO MnO Na 2O TiO 2 S SG Code Pb Coll M/ICP M/ICP Titration ISE M/ICP Leach XRF XRF XRF XRF XRF XRF XRF XRF XRF Comb/LECO pyc g/t ppm % % ppm % ppm % % % % % % % % % % I 567 34.5 1594 I 577 34.5 1648 I 586 34.6 1646 I 567 34.4 1624 I 602 34.7 1585 I 609 34.6 1517 I 571 34.6 1588 I 576 34.7 1593 K 0.76 546 32.5 3.35 8.38 3.67 K 0.73 524 32.2 3.52 8.39 3.66 K 0.72 544 34.3 3.49 8.33 3.63 K 0.75 551 32.1 3.43 8.42 3.64 K 0.75 555 32.9 3.46 8.41 3.65 K 0.75 542 32.0 3.31 8.41 3.64 K 0.74 543 32.3 3.32 8.43 3.65 K 0.74 555 32.9 3.44 8.42 3.62 L 0.69 519 33.9 3.06 2200 5.83 3.44 5.30 1.20 1.61 0.16 1.24 0.62 8.53 3.61 L 0.66 519 34.0 3.08 2000 6.00 3.40 5.28 1.21 1.61 0.16 1.23 0.61 8.58 3.61 L 0.70 517 33.9 3.20 2300 5.88 3.42 5.26 1.20 1.61 0.16 1.22 0.63 8.38 3.63 L 0.69 515 34.2 3.19 2400 6.00 3.42 5.22 1.19 1.61 0.16 1.22 0.62 8.40 3.63 L 0.67 519 34.2 3.17 2200 6.05 3.46 5.39 1.21 1.62 0.16 1.23 0.63 8.51 3.62 L 0.67 522 34.1 3.19 2600 5.86 3.43 5.25 1.20 1.57 0.16 1.22 0.61 8.35 3.62 L 0.68 529 34.0 2.99 2400 6.12 3.47 5.36 1.21 1.63 0.16 1.24 0.62 8.73 3.63 L 0.71 526 34.1 2.99 2700 6.07 3.49 5.36 1.21 1.63 0.16 1.23 0.63 8.37 3.65 O 0.73 596 34.6 308 3.60 5.74 3.34 5.15 1.65 0.15 8.85 3.45 O 0.73 608 34.2 361 3.46 5.59 3.26 4.95 1.58 0.15 8.86 3.43 O 0.73 594 34.2 325 3.69 5.82 3.36 5.28 1.67 0.16 8.73 3.46 O 0.73 596 34.3 363 3.45 5.52 3.23 4.93 1.57 0.15 8.74 3.43 O 0.73 612 34.6 312 3.62 5.74 3.32 5.18 1.61 0.16 8.78 3.45 O 0.72 598 34.2 365 3.17 5.10 2.95 4.53 1.42 0.14 8.73 3.44 O 0.73 615 34.3 314 3.58 5.74 3.33 5.12 1.61 0.15 8.71 3.43 O 0.74 600 34.4 314 3.61 5.78 3.37 5.16 1.64 0.16 8.67 3.45 P 530 34.3 5.96 3.37 0.31 5.44 1.21 1.64 0.16 1.36 0.63 8.64 3.58 P 530 34.3 6.00 3.37 0.32 5.46 1.22 1.63 0.16 1.36 0.62 8.10 3.63 P 525 34.5 6.01 3.39 0.31 5.46 1.22 1.61 0.17 1.33 0.63 8.36 3.56 P 520 34.5 6.01 3.39 0.32 5.46 1.21 1.62 0.17 1.39 0.62 8.76 3.63 P 530 34.4 5.99 3.37 0.32 5.47 1.22 1.63 0.16 1.33 0.61 8.28 3.56 P 540 34.4 5.98 3.38 0.31 5.47 1.21 1.62 0.17 1.30 0.61 8.68 3.65 P 535 34.4 5.97 3.39 0.32 5.49 1.22 1.60 0.17 1.36 0.61 8.70 3.57 P 520 34.4 5.94 3.38 0.31 5.47 1.22 1.60 0.17 1.37 0.61 8.70 3.65 Q 532 34.1 3.12 0.23 1.08 1.21 8.43 3.46 Q 530 34.1 3.17 0.23 1.16 1.29 8.49 3.45 Q 540 34.2 3.11 0.22 1.12 1.21 8.50 3.46 Q 535 34.4 3.26 0.22 1.14 1.27 8.56 3.46 Q 532 34.1 3.13 0.23 1.12 1.24 8.50 3.45 Q 533 34.1 3.16 0.23 1.12 1.24 8.44 3.43 Q 536 34.1 3.19 0.23 1.16 1.25 8.49 3.43 Q 540 34.0 3.19 0.23 1.12 1.27 8.59 3.45 R 554 34.0 8.40 3.56 R 564 33.9 8.42 3.54 R 549 33.5 8.47 3.59 R 559 32.9 8.60 3.55 R 559 33.0 8.47 3.52 R 546 32.9 8.44 3.55 R 550 33.3 8.53 3.59 R 554 33.2 8.55 3.55 S 485 34.2 505 1688 6.94 S 483 33.3 504 1646 7.30 S 445 33.2 501 1601 7.35 S 460 33.8 504 1498 6.93 S 447 32.6 504 1482 7.04 S 443 33.0 500 1542 6.82 S 450 32.3 502 1504 6.88 S 474 33.2 502 1506 7.06 T 0.72 557 34.0 452 3.83 6.05 3.36 0.29 5.48 1.34 1.71 0.17 1.35 0.30 8.49 3.63 T 0.71 567 34.0 474 3.84 6.18 3.37 0.30 5.49 1.35 1.76 0.17 1.35 0.29 8.49 3.58 T 0.66 564 34.3 451 3.89 6.03 3.39 0.29 5.56 1.31 1.71 0.17 1.36 0.30 8.50 3.64 T 0.69 553 33.9 452 3.88 6.08 3.36 0.31 5.55 1.33 1.66 0.17 1.35 0.35 8.48 3.58 T 0.71 550 34.0 474 3.85 6.01 3.36 0.30 5.50 1.30 1.71 0.16 1.35 0.37 8.45 3.57 T 0.75 555 34.0 550 3.81 6.01 3.37 0.30 5.45 1.30 1.69 0.16 1.36 0.36 8.52 3.63 T 0.72 559 34.0 429 3.85 5.97 3.34 0.30 5.50 1.30 1.71 0.16 1.35 0.31 8.52 3.62 T 0.68 559 34.0 524 3.83 5.95 3.37 0.30 5.48 1.28 1.69 0.16 1.35 0.36 8.50 3.61 V 0.68 547 33.6 3.79 8.78 V 0.71 553 33.7 3.81 8.68 V 0.76 546 33.4 3.77 8.75 V 0.77 545 33.5 3.78 8.69 V 0.72 546 33.6 3.78 8.74 V 0.70 556 34.1 3.85 8.66 V 0.71 550 33.8 3.81 8.67 V 0.79 547 33.6 3.78 8.67 X 3.53 5.93 3.19 0.21 5.05 1.18 1.53 0.15 1.20 0.33 8.36 3.56 X 3.56 5.91 3.30 0.23 5.09 1.17 1.53 0.15 1.20 0.33 8.29 3.58 X 3.63 6.07 3.40 0.23 5.19 1.23 1.56 0.15 1.24 0.35 8.24 3.58 X 3.57 5.93 3.32 0.24 5.10 1.19 1.53 0.15 1.20 0.33 8.28 3.57 X 3.53 5.84 3.12 0.20 5.05 1.16 1.48 0.15 1.15 0.32 8.24 3.57 X 3.52 5.86 3.32 0.21 5.03 1.20 1.59 0.15 1.25 0.35 8.41 3.60 X 3.56 5.91 3.36 0.21 5.09 1.29 1.62 0.15 1.27 0.35 8.29 3.57 X 3.46 5.73 3.26 0.21 4.95 1.19 1.58 0.15 1.21 0.33 8.23 3.58 Y 0.79 540 34.6 620 8.21 Y 0.78 541 34.6 610 8.27 Y 0.78 551 34.5 490 8.17 Y 0.80 542 34.7 470 8.31 Y 0.77 541 34.6 610 8.26 Y 0.73 542 34.5 660 8.35 Y 0.76 538 34.5 620 8.39 Y 0.78 539 34.5 630 8.32 5
12. Measurement of Uncertainty :(ref Dr Hugh Bartlett, Hugh Bartlett Consulting CC.) The samples used in this certification process have been selected in such a way as to represent the entire batch of material and were taken from the final packaged units; therefore all possible sources of uncertainty (sample uncertainty and measurement uncertainty) are included in the final combined standard uncertainty determination. The uncertainty measurement takes into consideration the between lab and the within lab variances and is calculated from the square roots of the variances of these components using the formula: Combined standard uncertainty=sqrt((between lab.var/no of labs) + (mean square within lab.var /no of assays)) These uncertainty measurements may be used, by laboratories, as a component for calculating the total uncertainty for method validation according to the relevant ISO guidelines. Analyte Method Unit S ' σl ² SW ³ CSU ⁴ Au Pb Coll g/t 0.040 0.025 0.025 0.007 Ag M/ICP ppm 14.55 10.06 5.34 2.64 Cu M/ICP % 0.5 0.38 0.38 0.14 Cu Titration % 0.2 0.18 0.11 0.05 F ISE ppm 68.0 66.2 27.0 23.6 Fe M/ICP % 0.2 0.12 0.06 0.04 Cl Leach ppm 499 608 84.5 249 Al 2 O 3 XRF % 0.175 0.155 0.091 0.056 CaO XRF % 0.049 0.038 0.031 0.014 Cr 2 O 3 XRF % 0.042 0.047 0.009 0.018 Fe 2 O 3 XRF % 0.211 0.206 0.080 0.073 K 2 O XRF % 0.048 0.049 0.019 0.019 MgO XRF % 0.050 0.043 0.029 0.016 MnO XRF % 0.006 0.006 0.003 0.002 Na 2 O XRF % 0.055 0.055 0.019 0.019 TiO 2 XRF % 0.143 0.198 0.016 0.089 S Comb LECO % 0.152 0.099 0.089 0.029 SG pyc 0.076 0.063 0.028 0.019 1. S - Std Dev for use on control charts. 2. σ L - Betw Lab Std Dev, for use to calculate a measure of accuracy. 3. S W - Within Lab Stc Dev, for use to calculate a measure of precision. 4. CSU - Combined Standard Uncertainty, a component for use to calculate the total uncertainty in method validation. 13. Certified values: The Certified, Provisional and Informational values listed on p1 and p2 of this certificate fulfill the AMIS statistical criteria regarding agreement for certification and have been independently validated by Dr Barry Smee. 14. Metrological Traceability: The values quoted herein are based on the consensus values derived from statistical analysis of the data from an inter laboratory measurement program. Traceability to SI units is via the standards used by the individual laboratories, the majority of which are accredited, who have maintained measurement traceability during the analytical process. 15. Certification: AMIS0409 is a new material. 16. Period of validity: The certified values are valid for this product, while still sealed in its original packaging, until notification to the contrary. The stability of the material will be subject to continuous testing for the duration of the inventory. Should product stability become an issue, all customers will be notified and notification to that effect will be placed on the www.amis.co.za website. 6
17. Minimum sample size: The majority of laboratories reporting used a 0.5g sample size for the ICP. This is the recommended minimum sample size for the use of this material. 18. Availability: This product is available in Laboratory Packs containing 1kg of material and Explorer Packs containing custom weights (from 50g to 250g) of material. The Laboratory Packs are sealed bottles delivered in sealed foil pouches. The Explorer Packs contain material in standard geochem envelopes, vacuum sealed in foil pouches. 19. Recommended use: The data used to characterize this CRM has been scrutinized using outlier treatment techniques. This, together with the number of participating laboratories, should overcome any inter-laboratory issues and should lead to a very accurate measure for the given methods, notwithstanding the underlying assumption that what the good inter-laboratory labs reported was accurate. However an amount of bad data might have had an effect, resulting in limits which in some situations might be too broad for the effective monitoring of a single analytical method, laboratory or production process. Users should set their own limits based on their own data quality objectives and control measurements, after determining the performance characteristics of their own particular method, using a minimum of 20 analyses using this CRM. User set limits should normally be within the limits recommended on p1 and 2 of this certificate. 20. Legal Notice: This certificate and the reference material described in it have been prepared with due care and attention. However AMIS, Set Point Technology (Pty) Ltd, Mike McWha, Dr Barry Smee and Smee and Associates Ltd; accept no liability for any decisions or actions taken following the use of the reference material. 28 October 2013 Certifying Officers: African Mineral Standards: Mike McWha BSc (Hons), FGSSA, MAusIMM, Pr.Sci.Nat Geochemist: Barry W. Smee BSc, PhD, P.Geo, (B.C.) 7
Appendix - Uncertified trace element statistics Analyte Method Unit Mean 2SD RSD% n Al M/ICP % 3.0 0.27 4.5 60 As M/ICP ppm 15.3 8.9 29.2 32 Ba M/ICP ppm 271 315 58.2 56 Be M/ICP ppm 1.3 1.1 40.0 40 Bi M/ICP ppm 10.6 0.88 4.2 31 Ca M/ICP % 2.4 0.19 4.1 59 Cd M/ICP ppm 0.50 0.18 18.5 37 Ce M/ICP ppm 76.7 5.7 3.7 30 Co M/ICP ppm 20.3 10.9 26.8 64 Cr M/ICP ppm 1805 540 15.0 56 Cs M/ICP ppm 2.0 0.38 9.4 16 Dy M/ICP ppm 4.5 0.13 1.5 8 Er M/ICP ppm 2.3 0.14 2.9 8 Eu M/ICP ppm 1.1 0.05 2.0 8 Ga M/ICP ppm 8.3 7.8 46.9 32 Gd M/ICP ppm 5.7 0.30 2.7 8 Ge M/ICP ppm 0.5 0.11 11.9 8 Hf M/ICP ppm 2.6 0.47 9.2 24 Ho M/ICP ppm 1.0 0.05 2.7 8 In M/ICP ppm 0.06 0.02 18.2 30 K M/ICP % 1.0 0.13 6.2 52 La M/ICP ppm 36.4 5.5 7.6 32 Li M/ICP ppm 21.5 2.9 6.8 48 LOI % 5.7 6.0 53.2 24 Lu M/ICP ppm 0.31 0.04 7.2 24 Mg M/ICP % 1.0 0.13 7.0 63 Mn M/ICP ppm 1203 144 6.0 59 Mo M/ICP ppm 356 75.2 10.6 64 Na M/ICP % 0.95 0.09 4.6 63 Nb M/ICP ppm 5.2 4.9 47.6 24 Nd M/ICP ppm 36.1 0.72 1.0 8 Ni M/ICP ppm 57.0 11.0 9.7 76 P M/ICP ppm 277 86.1 15.6 40 Pb M/ICP ppm 899 133 7.4 68 Pr M/ICP ppm 9.2 0.09 0.5 8 Rb M/ICP ppm 48.1 36.7 38.1 32 S M/ICP % 7.6 2.1 13.6 40 Sb M/ICP ppm 3.8 5.3 69.8 28 Sc M/ICP ppm 5.4 4.2 38.3 32 Se M/ICP ppm 17.0 11.0 32.3 24 Si M/ICP % 13.5 0.47 1.7 8 SiO 2 XRF % 29.0 0.24 0.42 22 Sm M/ICP ppm 7.1 0.14 1.0 8 Sn M/ICP ppm 2.4 1.5 29.9 24 Sr M/ICP ppm 100 12.4 6.2 63 Ta M/ICP ppm 0.49 0.17 17.8 24 Tb M/ICP ppm 0.77 0.07 4.4 23 Te M/ICP ppm 3.9 14.0 179 31 Th M/ICP ppm 8.3 0.5 3.1 31 Ti M/ICP % 0.23 0.17 36.1 32 Tl M/ICP ppm 0.47 0.18 18.8 40 Tm M/ICP ppm 0.46 0.03 2.8 8 U M/ICP ppm 4.8 0.32 3.4 29 V M/ICP ppm 117 15.3 6.5 42 W M/ICP ppm 1.7 0.47 14.0 24 Y M/ICP ppm 18.8 14.0 37.3 37 Yb M/ICP ppm 2.1 0.31 7.3 23 Zn M/ICP ppm 264 44.0 8.3 80 Zr M/ICP ppm 90.8 9.4 5.2 47 8