"Anthraquinone Pulping: A TAPPI PRESS Anthology of Published Papers" Edited by, Gopal C. Goyal
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1 1997, 600 pages Item Number: 0101R269 ISBN: This new anthology contains 93 technical papers covering all aspects of the use of anthraquinone (A) in different pulping processes. In this unique collection of papers, the editor has compiled information on the use of anthraquinone in soda, kraft, and sulfite processes to reduce active alkali charge, H-factor and to achieve lower Kappa (extended delignification) pulp. The book is divided into five sections: Kraft/Soda and Anthraquinone Pulping Polysulfide and Anthraquinone Pulping Combination of Anthraquinone with Neutral and Alkaline Sulfite Processes Mechanism of Anthraquinone Reaction Analytical Methods for Anthraquinone Chapter 1 Page 1 of 9 TABLE OF CONTENTS Low Kappa Pulping Without Capital Investment - Use of Anthraquione for Low Kappa Pulping / 3 Sturgeoff, L.G. and Pitl, Y., TAPPI 1993 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p Extending the Digester Delignification with Anthraquione / 10 Rajan, P.S., Griffin, C.W., Jameel, H., and Gratzl, J.S., TAPPI 1992 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p Tearing Resistance in Soda-AQ and Kraft Pulps / 30 Nelson, P.J. and Irvine, G.M., Tappi J., 75(1):163 (1992). Low Sufidity and Additive Cooking by Modified Batch (MB) Cooking / 34 Watson, P.A., Andrews, E.K., Gustafson, R.R. and McKean, W.T., Tappi 1992 Pulping Conference Proceedings, TAPPI PRESS, Atlant, p.847. Anthraquinone - A Simple Approach for Extended Delignification in Conventional Kraft Pulping / 42 Goyal, G.C., Powers, J. and Cronlund, M., TAPPI 1992 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p Oxidative Pretreatment of Loblolly Pine with Alkaline Hydrogen Peroxide and Soda- AQ Pulping / 49 Parthasarathy, V.R. and Gratzl, J.S., TAPPI 1990 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p. 605.
2 Soda-AQ Pulping and the Tear Strength Problem / 84 Nelson, P.J., and Irvine, G.M., TAPPI 1989 International Symposium on Wood and Pulping Chemistry Proceedings, TAPPI PRESS, Atlanta, p.515. The Effects of Anthraquinone on the Reaction Rate of Kraft Pulping of Northeastern White Pine / 89 Malachowski, P.S., Poniatowski, S.E., and Walkinshaw, J.W., Tappi J., 72(6): 207(1989). Kraft Anthraquinone Pulping of Sawdust / 93 MacLeod, J.M. and Kingsland, K.A., TAPPI 1988 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.677. Digester Operating Conditions and Pulp Quality in a Soda-AQ Pulp Mill / 100 Sherban, C., Tappi J., 71(11): 50(1988). Studies on Kraft and Soda-Anthraquinone Pulping of Indian Mixed Hardwoods / 104 Haldar, R. and Bhattacharya, P.K., Tappi J., 70(6): 129(1987). Influence of Sulfite on the Effectiveness of Anthraquinone in Soda Pulping / 108 He, P. and Lai, Y.Z., Tappi J., 69(12): 89(1986). Comparisons of As-AQ Pulping of Mixed Hardwoods and Pulping by the Conventional Kraft Process / 110 Miller, M.L. and Gounder, R., Tappi J., 69(11): 118(1986). Substituting AQ for AA in Kraft Pulping / 113 Mortimer, R.D. and Fleming, B.I., Tappi J., 68(10): 111(1985). Soda Anthraquinone Pulping of Douglas Fir / 116 Eckert, R.C., Pfeiffer, G.O., Gupta, M.K., and Lowers, C.R., Tappi J., 67(4): 120(1984). The Interrelationship of Residual and Initial Alkali Concentrations for Kraft and Soda Pulping at Constant Hfactor / 121 Mortimer, R.D. and Fleming, B.I., Tappi J., 67(4): 120(1984). The Carbohydrate Composition of Soda-Additive Pulps / 12 MacLeod, J.M., Iwase,H., and Bolker, H.I., Tappi J. 67(5) Delignification Rates of Alkaline-AQ Processes / 127 MacLeod, J.M. and Fleming, B.I., Tappi J., 66(12): 81(1983). The Influence of Low-Lignin Pulping Conditions on Bleachability: Effects of Anthraquinone and Effective Alkali Charge / 129 McDonough, T.J. and Herro, J.L., Tappi J., 65(9): 117(1982). Kinetics of Soda-Anthraquinone Delignification / 134 Abbot, J., and Bolker, H.I., Tappi J., 65(9): 127(1982. Page 2 of 9
3 The Interaction of Anthraquinone with Tall Oil Components / 137 Dimmel, D.R., Thireault, D.D., Curti, P.D., and Seefeldt, R.G., Tappi J., 64(6): 64(1981). New Opportunities for In-Plant Reduction of Pollutants Through Process Changes / 139 Renard, J.J., Phillips, R.B., Jameel, H., and Rudie, A.W., Tappi J., 64(8): 51(1981). Would Anthraquinone be Economical in Your Pulp Mill? / 143 Virkola, N.E., Tappi J., 64(6): 51(1981). Effect of Sulfidity in Alkaline Pulping of White Spruce with Anthraquinone / 146 Van Allen, N.J., Hatton, J.V., and Gee, W.Y., Tappi J., 64(6): 64(1981). Anthraquinone in Kraft Pulping / 149 Goel, K., Ayroud, A.M., and Branch, B., Tappi J., 63(8): 83(1980). The Influence of Sulfidity on the Bleachability and Strength Properties of Alkaline- Anthraquinone Softwood Pulps / 152 Blain, T.J., Tappi J., 63(5): 125(1980). Kraft and Soda Pulping of Decayed Western Hemlock Using Anthraquinone / 156 Leu, J.D., Hunt, K., and Hatton, J.V., Tappi J., 63(1): 82(1980). The Strengths of Kraft-AQ (Anthraquinone) and Soda-AQ Pulps / 158 MacLeod, J.M., Fleming, B.I., Kubes, G.J., and Bolker, H.I., Tappi J., 63(1): 57(1980). Soda-Anthraquinone Pulping of Hardwoods - Process Models / 162 Ghosh, K.L., Venkatesh, V., and Gratzl, J.S., Tappi J., 61(8): 57(1978). Kraft Pulping with Anthraquinone: Laboratory and Full-Scale Mill Trials / 165 Holton, H.H. and Chapman, F.L., Tappi J., 60(11): 121(1977). Quinone Additives in Soda Pulping of Hardwoods / 170 Ghosh, K.L., Venkatesh, V., Chin, W.J., and Gratzl, J.S., Tappi J., 60(11): 127(1977). Defining AQ Pulping Activity: Part 1- AQ vs. Sulfidity / 175 Kutney, G.W., TAPPI 1984 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.65 A Review of New Alkaline-AQ Processes / 184 MacLeod, J.M., TAPPI 1983 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.89 Low-Sulfidity Kraft-Anthraquinone Pulping of Hardwood/Softwood Mixtures / 187 Kent, W.R., and Hatton, J.V., TAPPI 1983 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.69 Page 3 of 9
4 Mill Experience with Kraft/Quinone Additive Pulping of Eucalyptus in Batch Digester / 196 Furuya, J., TAPPI 1983 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.549. Improved Kraft Pulping of White Spruce Bark/Wood Mixtures with Anthraquinone / 203 Kotani, E.K., Hatton, J.V., Hunt, K., and Gee, W.Y., TAPPI 1982 International Pulp Bleaching Conference Proceedings, TAPPI PRESS, Atlanta, p. 69 Low-Lignin Pulping to Replace or Enhance Oxygen Bleaching / 208 McDonough, T.J., and Van Drunen, V.J., TAPPI 1982 International Pulp Bleaching Conference Proceedings, TAPPI PRESS, Atlanta, p. 59 Evaluation of Kraft / AQ Pulping at Gardiner Mill (of International Paper Co.) / 220 Shaw, J.S. and Renard, J.J., TAPPI 1980 Pulping Confernce Proceedings, TAPPI PRESS, Atlanta, p.472 Anthraquinone Pulping: Fifteen Years After / 227 Blain, T.J., TAPPI 1992 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.1005 Chapter 2 Use of AQ/PS Pulping Additives for the Production of Linerboard Pulp / 239 Prasad, D.Y., Jameel, H., Gratzl, J., and Tu, X., TAPPI 1996 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.59 Anthraquinone and Polysulfide - Applicability foe Use in Pulp Mill Operations / 253 Deal, H., TAPPI 1996 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p. 73 Sulfide Profiling for Increased Kraft Pulping Selectivity / 261 Jiang, J.E. and Herschmiller, D.W., TAPPI 1996 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.311 Anthraquinone and Anthraquinone Polysulfide Pulping for Extended Digester Delignification / 269 Katz, G., TAPPI 1993 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.323 Extended Delignification of Southern Pine with Polysulfide and Anthraquinone / 278 Jiang, J.E., TAPPI 1993 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p. 313 Operating Experiences with the Moxy Process and Quinoid Compounds / 287 Yamaguchi, A., TAPPI 1983 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.544. The Use of Quinone Additives in Kraft and Polysulfide Pulping / 292 Green, R.P. and Smith, G.C., TAPPI 1983 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p. 79 Page 4 of 9
5 Applications of Anthraquinone to Kraft and Polysulfide Pulping / 298 Brown, G.W., and Knowles, S.E., TAPPI 1980 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.109 Application of Anthraquinone in Extending the Delignification of Kraft and Polysulfide Pulps. Part 1: Pulping and Bleaching of Mixed Hardwoods / 304 Parthasarathy, V.R., Smith, G.C., Rudie, G.F., Detty, A.E., and Steffy, J.J., Tappi J., 78(2): 113(1995). Extending Delignification with AQ/Polysulfide / 317 Jameel, H., Gratzl, J., Prasad, D.Y., and Chivukula, S., TAPPI 1994 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p. 781 Chapter 3 Can Sulphite Pulp Challenge the Predominance of Kraft Pulp Successfully? / 337 Wong, A., Chiu, C., anf Krzywanski, R., TAPPI 1993 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.135. A Novel Sulphite Pulping and Chemical Recovery System for Small-and Medium- Scale Pulp Mills / 334 Wong, A., and Derdall, G., TAPPI 1989 International Sulfite Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.105 Manufacture of Bleached Aspen Market Pulp Without the Use of Chlorine or Chlorine Dioxide / 348 Ng, D., Tichy, J., and Wong, A., TAPPI 1989 International Sulfite Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p. 7 The Characteristics of MSS-AQ Pulping: A New Pulping Process / 352 Dahlbom, J., Olm, L., and Teder, A., TAPPI 1989 International Sulfite Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.1 Sulfite-Quinone and Sulfite-Oxygen Delignification / 358 Ohi, H., Fukagawa, N., Meshitsuka, G., and Ishizu, A., TAPPI 1989 International Symposium on Wood and Pulping Chemistry, TAPPI PRESS, Atlanta, p.497 The Role of Anthraquinone in Sulphite-Anthraquinone Pulping / 363 Suckling, I.D., TAPPI 1989 International Symposium on Wood and Pulping Chemistry, TAPPI PRESS, Atlanta, p.503 Ultra High Yield Pulps From Black Spruce by Acid Bisulphite, Neutral Sulphite and Neutral Sulphite SAQ Pulping / 371 Nye, J.W., Fitkowski, T.C., and Tay, C.H., TAPPI 1988 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.725 Page 5 of 9
6 A New Cooking Method for Producing Wood Sugars and Specialty Pulps / 376 Tikka, P.O., Virkola, N.E., and Laine, J.E., TAPPI 1988 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.255 Alkaline Sulfite-Anthraquinone Pulp From Aspen / 382 MacLeod, J.M., Tappi J., 69(8): 106(1986) An Evaluation of the Sulfite-AQ Pulping Process / 386 Sanborn, I.B., and Schweiger, K.D., Tappi J., 68(8): 102(1986) A Neutral-Sulfite/SAQ Chemimechanical Pulp for Newsprint / 390 Tay, C.H., Fairchild, R.S., and Imada, S.E.,Tappi J., 64(5): 103(1981) A Case Study - Converting a Kraft Mill into a NSAQ (Neutral Sulfite Anthraquinone) Mill / 396 Kettunen, J., Reilama, I., and Ruhanan, M., Tappi J., 65(10): 63(1982) Neutral Sulfite AQ Pulping as an Alternative to Kraft Pulping / 401 Virkola, N.E., Pusa, R., and Kettunen, J., Tappi J., 64(5): 103(1981) An Evaluation of SAQ (Sulfite-Anthraquinone) Pulp / 406 Sanborn, I.B., and Schweiger, K.D., TAPPI 1985 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.487 Sulfite-Anthraquinone Pulping of Southern Pine for Linerboard / 414 McDonough, T.J., and Paulson, T.W., TAPPI 1985 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.471 Alkaline Sulfite Anthraquinone Pulping: A Brief Review of its Nature Development and Present Status / 431 Ingruber, O.V., TAPPI 1985 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.461. Chemimechanical Pulp From Neutral (ph 7.5) Sulphite/SAQ (Soluble Anthraquinone) Pulping for Newsprint Manufacture /431 Tay, C.H., Fairchild, R.S., and Imada, S.E., TAPPI 1984 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.319 NSSC/AQ Pulping of P. Radiata - Laboratory and Mill Experience / 437 Evans, R. Farrington, A. Kettunen, J., Nelson, P.F., and Vanderhoek, N., TAPPI Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.53. Neutral Sulfite AQ Pulping and Bleaching of the Pulps / 443 Tikka, P. and Tulppala, J., TAPPI 1982 International Sulfite Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.47 Page 6 of 9
7 A Case Study to Convert Kraft Mill into a NSAQ (Neutral Sulfite-Anthraquinone) Mill / 454 Kettunen, J., Reilama, I., and Ruhanen, M., TAPPI 1982 International Sulfite Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.47 Some Results of Mill Trials with AQ as a Pulping Additive in Finland / 462 Virkola, N.E., TAPPI 1980 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.479 NS (Neutral Sulfite) or SAS (SemiAlkaline Sulfite) AQ Pulping as an Alternative to Kraft Pulping / 465 Kettunen, J., Pusa, R., and Virkola, N.E., TAPPI 1980 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.425 Chapter 4 Pulping with Anthraquinone: Fundamental Chemistry / 479 Dimmel, D.R., TAPPI 1996 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.53 A Comparative Study of the Delignification Efficiencies of Alkaline Pulping Systems / 485 Brogdon, B.N., and Dimmel, D.R., TAPPI 1994 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.1209 Mass Transfer Limitations in Sulfite-AQ Pulping. Part 1: Three Dimensional Digital Simulation for the Impregnation Stage / 492 Morin, F., and Kubes G.J., TAPPI 1993 Pulping Conference Proceedings, TAPPI PRESS, Atlanta, p.253. Kinetic Studies on Soda-Anthraquinone Pulping of Indian Mixed Hardwood / 500 Bhattacharya, P.K., De, S., Haldar, R., and Thakur, R., Tappi J., 75(8): 123(1992) Lignin Functionalization and the Alkaline Delignification Rate / 505 Evstigneyev, E., Maiyorova, H., and Platonov, A., Tappi J., 75(7): 177(1992) Soda-AQ Delignification of Hardwoods: Reactions, Mechanism, and Dissolved Lignin Characteristics / 511 Venica, A.D., Chen, C.L., and Gratzl, J.S., TAPPI 1989 International Symposium on Wood and Pulping Chemistry, TAPPI PRESS, Atlanta, p.263 Sulfide and Anthraquinone-like Catalysts Delignify Wood via Different Chemical Mechanisms in Alkaline Pulping / 518 Wethemann, D.P., Tappi J., 65(7): 98(1982) AQ Radicals in Alkaline Pulping / 522 Mattar, S.M., and Fleming, B.I., Tappi J., 64(4): 136(1981) Page 7 of 9
8 Effect of Quiones and Amines on Cleavage Rate of Beta 0-4 Ethers in Lignin During Alkaline Pulping / 524 Obst, J.R., and Sanyer, N., Tappi J., 63(7): 111(1980) Quinones in Alkaline Pulping: Characterization of an Anthrahydroquinone - Quinone Methide Intermediate / 528 Landucci, L.L., Tappi J., 63(7): 95(1980) The Effect of Reducing Agents on Anthraquinone Pulping / 533 Simard, G.L., Genco, J.M., and Hendricksson, K.E., Jr., Tappi J., 62(5): 91(1979). Quinones in Alkaline Pulping: Beta-Ether Cleavage of Free Phenolic Units in Lignin / 535 Obst, J.R., Landucci, L.L., and Sanyer, N., Tappi J., 62(1): 55(1979). Improved Stabilization of Carbohydrates by the Oxygen-Quinone System / 540 Rucho, K. and Sjostrom, E., Tappi J., 61(7): 87(1978). Soda Pulping with Anthraquinone: A Mechanism / 542 Fleming, B.I., Kubes, G.J., MacLeod, J.M., and Bolker, H.I., Tappi J., 61(6): 43(1978). Carbohydrate Stabilization During Soda Pulping with Addition of Anthraquinone / 546 Lowendahl, L., and Samuelson, O., Tappi J., 61(2): 19(1978). Soda-Anthraquinone Pulping: Advantages of Using Oxygen-Free Conditions / 549 Fullerton, T.J., Tappi J.,62(8): 55(1979). The Analysis of Anthraquinone in Pulping Liquors and Pulp Products by HPLC (High Performance Liquid Chromatography) and TLC / 555 Mortimer, R.D., and Fleming, B.I., Tappi J., 64(11): 114(1981). Pulping Catalysts from Lignin / 558 Dimmel D.R., and Bozell, J.J., Tappi J., 74(5): 239(1991). Liquid Chromatographic Determination of Anthraquinone in Soda and Kraft Pulping Liquor, Pulp, Air Filters, and Wastewater / 561 Armentrout, D.N., Tappi J., 64(9): 165(1981). Determining Anthraquinone Content: Analysis of Pulp- and Paper-Type Materials and Pulping and Pulping Liquors by Gas Chromatography / Mass Spectrometry / 566 Currah, J.,E., Tappi J., 62(8): 73(1979). Reduction Products of Anthraquinone: Soda-Anthraquinone Pulping of Norway Spruce / 570 Gourang, I., Cassidy, R., and Dence, C.W., Tappi J., 62(7): 43(1979). Page 8 of 9
9 Polargraphic Analysis of Soda-Anthraquinone Pulping Liquor / 575 Fleming, B.I., Kubes, G.J., MacLeod, J.M., Bolker, H.I., Tappi J., 62(7): 55(1979). Chapter 6 Patent Literature on Anthraquinone / 581 Page 9 of 9
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