C10 - Cold rolled steels for conventional enamelling

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1 C10 - Cold rolled steels for conventional enamelling Enamelled steel is eminently suitable for use in the sanitary ware industry, which has very rigorous requirements with regard to hygiene and bacteriological resistance.

2 C10 Properties After drawing, cold rolled steels for conventional enamelling are used for: Ground-coat enamelling one coat / one fire Conventional enamelling two coats / two fires Grades DC01EK, DC04EK, DC05EK and DC06EK comply with EN Grade DC05EK was developed for the manufacture of bathtubs. Grade DC07EK AM FCE is intended for very deep drawing applications. It is worth noting that the DC06EK EN 10209:2013 and DC07EK AM FCE grades are also compatible with the twocoat / one-fire enamelling process. C10 Advantages These grades are suitable for light and deep drawing and two-side enamelling adapted to the client's process (wet or dry enamelling). They also offer excellent resistance to "fish scale" defects. We can guarantee a minimum TH of 100, in accordance with EN for grades DC01EK, DC03EK AM FCE, DC04EK and DC05EK.

3 C10 Applications These steels have many applications: Domestic appliances (cooking, laundry) Sanitary ware (bathtubs, shower trays, sinks), in particular grade DC05EK EN 10209, which has improved mechanical properties for the manufacture of bathtubs Architectural panels (building interiors and exteriors, transport and infrastructure), signage Industry

4 C10 Recommendations for use Forming The different grades are adapted to the difficulty of enamelling the given parts. Grades DC01EK EN and DC03EK AM FCE are intended for easy forming by bending or moderate drawing. Grade DC04EK EN is intended for more difficult deep drawing operations. Grade DC05EK EN 10209, which has superior mechanical properties compared with DC04EK EN 10209, is especially intended for forming bathtubs. Grades DC06EK EN and DC07EK AM FCE, interstitial free steel (IFS) with low carbon content and excellent rheological and mechanical properties, can be used for forming very complex parts. Joining Grades DC01EK EN 10209, DC03EK AM FCE, DC04EK EN 10209, DC05EK EN 10209, DC06EK EN and DC07EK AM FCE can be welded without any difficulty, whatever the welding process may be. Other joining processes (clinching, crimping) may also be used. Enamelling Surface preparation: If an additive-free ground-coat enamel is used (e.g. without adhesion oxides), light pickling is recommended after meticulous degreasing (targeting an iron loss of 5 g/m 2 per side), especially for grades DC06EK EN and DC07EK AM FCE, which have a lower surface reactivity. In this case, surface reactivity can be improved by a nickel flash Pickling can be avoided by using a ground-coat enamel with the addition of adhesion oxides (nickel or cobalt oxides) Application of the enamel and firing: Grades DC01EK EN 10209, DC03EK AM FCE, DC04EK EN 10209, DC05EK EN 10209, DC06EK EN and DC07EK AM FCE are compatible with all the common enamelling processes: wet spraying, wet or dry electrostatic deposition These grades have a very good level of internal purity (few inclusions) and consistency. The risk of the appearance of defects such as black dots, lines or bubbles is minimal. A good resistance to "fish scale" defects is obtained through tight control of manufacturing conditions Finally, firing is performed at a temperature of about 830 C.

5 C10 Brand correspondence EN 10209:2013 NFA DIN 1623/3 UNI 5866 BS 1449/1 ASTM 424 JIS Old brand names DC01EK EN DC01EK EME EK2 FeP02S CR3VE SPCD DC03EK AM FCE DC04EK EN DC04EK EMES EK4 FeP04S CR1VE Type 2 DC05EK EN DC05EK FeK4 B/DC04EK+ DC06EK EN DC06EK Type 3 DC07EK AM FCE Grades in italics: not included in the standard C10 Dimensions Thickness (mm) Min width DC01EK EN 10209, DC03EK AM FCE, DC04EK EN DC05EK EN DC06EK EN 10209, DC07EK AM FCE Max width Max width Max width 0.50 th < th < th < th < For thicknesses below 0.5 mm, please contact us.

6 C10 Mechanical properties Direction Thickness (mm) R e (MPa) R m (MPa) A 80 (%) r 90 r average n DC01EK EN T DC03EK AM FCE T DC04EK EN T DC05EK EN T DC06EK EN T DC07EK AM FCE T Grades in italics: not included in the standard

7 C10 Chemical composition C (%) Mn (%) P (%) S (%) Ti (%) DC01EK EN DC03EK AM FCE DC04EK EN DC05EK EN DC06EK EN DC07EK AM FCE Grades in italics: not included in the standard Any questions? Ask them via our contact form on All details provided in the ArcelorMittal Flat Carbon Europe S.A. catalogue are for information purposes only. ArcelorMittal Flat Carbon Europe S.A. reserves the right to change its product range at any time without prior notice.

8 C20 - Solfer : decarburised cold rolled steel range for white and coloured enamelling processes The use of Solfer decarburised cold rolled steel grades for white and coloured enamelling processes produces an excellent surface finish after enamel firing.

9 C20 Properties Solfer grades are obtained by decarburisation. Two decarburisation processes are used: Decarburisation during open-coil annealing process Solfer and Solfer + grades: these grades are particularly suitable for the direct-on white or coloured enamelling process after degreasing, pickling and deposition of a nickel layer. However, they can also be used for two-coat / one-fire or for ground enamelling processes using groundcoat enamel specially designed for the low intrinsic reactivity of these grades (e.g. enamelling of self-cleaning pyrolytic oven cavities). Surface decarburisation during continuous annealing process Solfer CA grade: this patented steel grade has been developed for the two-coat / one-fire enamelling process. Nevertheless, it can also be used for ground or conventional enamelling processes. C20 Advantages Solfer and Solfer + grades are suitable for the manufacture of complex parts (medium to deep drawing) and are compatible with all existing enamelling processes (direct-on white or coloured enamelling after degreasing, pickling and coating with nickel, two-coat / one-fire or ground enamelling after degreasing), with enamel layers being applied as either a liquid or a powder. These grades offer excellent resistance to "fish scale" defects. A minimum TH of 100 is guaranteed, in accordance with EN 10209:2013. Solfer CA grade is suitable for light to medium drawing and is compatible, after degreasing, with the two-coat / onefire enamelling process using the wet/dry or dry/dry method. This grade can also be used for the ground enamelling process. It offers excellent resistance to "fish scale" defects. A minimum TH of 100 is guaranteed, in accordance with EN 10209:2013. For the whole Solfer range, surface appearance after enamelling is excellent: no pinholes or black spots. This is linked to the ultra-low carbon content of these grades (throughout for Solfer and Solfer + grades and on the surface for Solfer CA grade). Moreover, for Solfer and Solfer + grades, deformation at high temperature (e.g. sagging, during pyrolytic cycles) is limited.

10 C20 Applications Solfer grades are particularly suitable for the manufacture of casing panels for domestic appliances (hobs, covers, control panels, side panels etc) and for kitchen utensils (pots and pans). They can also be used for architectural applications, thanks to their excellent resistance to deformation during enamel firing.

11 C20 Recommendations for use Forming Solfer grades can be formed by bending, profiling or deep drawing. Joining Solfer grades can easily be welded, whatever the welding process may be. Other joining processes (clinching, crimping) may also be used. Direct-on enamelling process: Solfer and Solfer + grades Surface preparation: Surface preparation before enamelling must be performed with the greatest care (degreasing, pickling and coating with nickel). This is essential to achieve a good surface appearance of the part after enamelling and good adhesion of the enamel. The level of iron loss after pickling and the quantity of nickel deposited must therefore be monitored very precisely. Application of the enamel and firing: The thickness of the enamel layer deposited is generally about 130 microns. Moreover, Solfer and Solfer + grades are compatible with all the common enamelling processes: wet spraying, electrostatic liquid or powder deposition. Taking into account its limited Al content, the Solfer grade is particularly suitable for the ETE application process. Where wet application is used, it is imperative to dry the enamel layer before firing. Finally, firing is performed at a temperature of about 830 C. Two-coat / one-fire enamelling process: Solfer CA, Solfer and Solfer + grades Surface preparation: Very meticulous degreasing before enamel application is essential Enamel application and firing:

12 Solfer grades are compatible with all the common enamelling processes: wet spraying, electrostatic liquid or powder deposition. It is essential that the following requirements are met: Use of ground-coat enamel containing a high level of metallic adhesion oxides The thickness of the ground-coat enamel should not be less than 35 microns or more than 45 microns The thickness of the cover-coat enamel should be about 100 microns Where wet application is used, it is imperative to dry the enamel layer before firing Finally, firing is performed at a temperature of about 830 C C20 Brand correspondence EN 10209:2013 DIN 1623/3 ASTM A424 JIS Solfer DC03ED ED3 Type 1 CS SPP Solfer + DC04ED ED4 Type 1 DS SPP Solfer CA

13 C20 Dimensions Thickness (mm) Min width Solfer, Solfer + Max width Solfer CA Max width 0.40 th < th < th < th < th <

14 C20 Mechanical properties Direction Thickness (mm) R e (MPa) R m (MPa) A 80 (%) Solfer Solfer + T T Solfer CA T Mechanical properties as delivered Solfer CA: mechanical properties as well as fish scale resistance comply with EN 10209:

15 C20 Chemical composition Notes C (%) Mn (%) P (%) S (%) Si (%) Al (%) Solfer Solfer Solfer CA C (%): heat analysis The manufacturing conditions guarantee very good resistance to "fish scale defects (TH > 100 in accordance with EN 10209:2013). Any questions? Ask them via our contact form on All details provided in the ArcelorMittal Flat Carbon Europe S.A. catalogue are for information purposes only. ArcelorMittal Flat Carbon Europe S.A. reserves the right to change its product range at any time without prior notice.

16 C30 - HC300EK: structural cold rolled steel for enamelling with guaranteed minimum yield strength after enamel firing One of our clients key objectives is to lower the cost of enamelled parts. Reducing the thickness of the steel used can contribute to this aim, leading to substantial savings. However, enamel firing at high temperature causes deformation of parts, which becomes more significant as steel thickness decreases. The use of cold rolled steel for enamelling with guaranteed minimum yield strength after enamel firing eliminates this problem.

17 C30 Properties HC300EK is a cold rolled enamelling steel grade with guaranteed minimum yield strength that retains its mechanical properties after deformation and enamel firing. This grade can be used for both one-side and two-side enamelling. C30 Advantages The use of HC300EK grade enables steel thicknesses to be reduced whilst avoiding deformation of the parts after enamel firing. This grade can replace hot rolled steel in the manufacture of water heater tanks. After manufacture, parts like these are generally subjected to a cyclic fatigue test under pressure, during which they must not be deformed. The use of HC300EK grade thus makes it possible to reduce thicknesses to a lower level than is possible with hot rolled steel. C30 Applications HC300EK grade is particularly suitable for the manufacture of water heater tanks. It can also be used for flat parts for household items (dripping pans, baking trays) and shower trays or for manufacturing architectural panels for building interiors or exteriors.

18 C30 Recommendations for use Forming HC300EK grade can be formed by bending, profiling or light drawing. Joining HC300EK grade can easily be welded, whatever the welding process may be. Other joining processes (clinching, crimping) may also be used. Enamelling Surface treatment: The parts must be degreased before enamelling. When enamel containing a low level of adhesion oxides is used (e.g. water heater tank using Ni-free enamel), sand blasting or pickling may be necessary. Enamel application and firing: HC300EK grade is compatible with all the common enamelling processes: wet spraying, electrostatic liquid or powder enamelling. Both ground and conventional enamelling processes are feasible. Where wet application is used, it is imperative to dry the enamel layer before firing. Enamel firing is carried out at 830 C.

19 C30 Brand correspondence HC300EK C30 Dimensions Thickness (mm) 0.50 th < 0.80 Min width HC300EK Max width th < th <

20 C30 Mechanical properties Mechanical properties as delivered. R e (MPa) R m (MPa) E (%) HC300EK 280/ /480 > 20 The guaranteed minimum yield strength after 5% deformation and enamel firing is 300 MPa. C30 Chemical composition C (%) Mn (%) P (%) S (%) Si (%) N (%) HC300EK The manufacturing conditions guarantee very good resistance to fish scale defects (TH > 100 in accordance with EN 10209). Any questions? Ask them via our contact form on All details provided in the ArcelorMittal Flat Carbon Europe S.A. catalogue are for information purposes only. ArcelorMittal Flat Carbon Europe S.A. reserves the right to change its product range at any time without prior notice.

21 C50 - Hot rolled steels for one-side enamelling Its very good resistance to chemicals and to fermentation makes hot rolled steel for one-side enamelling an excellent material for manufacturing tanks for electric water heaters.

22 C50 Properties Hot rolled steels for one-side enamelling are steels with a specific chemical composition, which can guarantee: Excellent resistance to "fish scale" defects in the enamelled parts Conservation of mechanical properties after forming and firing of the enamel Two grades are available to match the requirements of different applications: S240EK AM FCE and S300EK AM FCE, which can be supplied pickled or unpickled and oiled or unoiled. C50 Advantages Grades S240EK AM FCE and S300EK AM FCE are used to manufacture water heater tanks with very good mechanical strength and good resistance to in-service stresses. In addition, by using these grades, and S300EK AM FCE in particular, the thickness of the steel can be reduced. After enamelling, the inside wall of the tank has excellent corrosion, heat and moisture resistance.

23 C50 Applications Hot rolled steels for one-side enamelling are mainly intended for the manufacture of tanks for water heaters. They can also be used for enamelled tubes or coiled pipes. C50 Formability Forming of hot rolled grades for one-side enamelling presents no particular problems: Grade S300EK AM FCE is particularly recommended for the manufacture of cylindrical sections by rolling Grade S240EK AM FCE is preferable for deep drawn top and bottom parts All the usual welding processes can be used (TIG, MIG, seam welding, laser).

24 C50 Technical properties Surface preparation and enamelling of water heaters The surface must be treated by pickling or shot blasting. Enamel can be applied in a wet or dry process. Firing is performed at a temperature of about 830 C. Conservation of mechanical properties after enamelling The mechanical properties of hot rolled steel for one-side enamelling remain unchanged after forming and firing of the enamel. This offers the following advantages: It extends the life span of water heaters by increasing their fatigue safety margin The thickness of the steel can be reduced, thereby reducing the cost of the raw materials for the water heater. Simulation and calculation tools at your disposal in our laboratories will enable us to optimise the thickness required for the piece and arrive at the best balance between cost and technical requirements

25 C50 Brand correspondence Old brand names S240EK AM FCE Sid S235J EK/S235J EK/S235J EQ/Cock 240/ 250 S300EK AM FCE Sid S275J EK/Cock 280/ 300

26 C50 Dimensions Hot rolled steel for one-side enamelling: unpickled Thickness (mm) S240EK AM FCE S300EK AM FCE Min width Max width Min width Max width 1.50 th < th < th < th < th < th < th < th < th < th < th < th < th < th < th <

27 Hot rolled steel for one-side enamelling: pickled Thickness (mm) S240EK AM FCE S300EK AM FCE Min width Max width Min width Max width 1.50 th < th < th < th < th < th < th < th < th < th < th < th < th < th < th < th < th <

28 C50 Mechanical properties Direction Thickness (mm) R e (MPa) R m (MPa) A 80 (%) A 5.65 S o (%) S240EK AM FCE S300EK AM FCE T T (before enamelling) C50 Chemical composition C (%) Mn (%) P (%) S (%) Ti (%) B (%) S240EK AM FCE S300EK AM FCE Any questions? Ask them via our contact form on All details provided in the ArcelorMittal Flat Carbon Europe S.A. catalogue are for information purposes only. ArcelorMittal Flat Carbon Europe S.A. reserves the right to change its product range at any time without prior notice.

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